Further Characterisation of the 91500 Zircon Crystal

This paper reports the results from a second characterisation of the 91500 zircon, including data from electron probe microanalysis, laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS), secondary ion mass spectrometry (SIMS) and laser fluorination analyses. The focus of this initiative was to establish the suitability of this large single zircon crystal for calibrating in situ analyses of the rare earth elements and oxygen isotopes, as well as to provide working values for key geochemical systems. In addition to extensive testing of the chemical and structural homogeneity of this sample, the occurrence of banding in 91500 in both backscattered electron and cathodoluminescence images is described in detail. Blind intercomparison data reported by both LA-ICP-MS and SIMS laboratories indicate that only small systematic differences exist between the data sets provided by these two techniques. Furthermore, the use of NIST SRM 610 glass as the calibrant for SIMS analyses was found to introduce little or no systematic error into the results for zircon. Based on both laser fluorination and SIMS data, zircon 91500 seems to be very well suited for calibrating in situ oxygen isotopic analyses.     

A brief overview of the ACEP project: Ecosystem Processes in the KwaZulu-Natal Bight§

This introductory paper lays the basis for this supplementary issue by briefly presenting the state of knowledge on the KwaZulu-Natal (KZN) Bight at the start of this multi-disciplinary, multi-institutional, ship-based research project that ran from 2009 to 2013. The rationale and aims of the project are also described. The project was a major component of the South African Department of Science and Technology’s African Coelacanth Ecosystem Programme (ACEP), which has been prominent in supporting research on the east coast of South Africa and the wider South-West Indian Ocean. Pivotal to this was the RS Algoa, which was made available for two 30-day surveys (winter and summer) in the KZN Bight by the Department of Environmental Affairs. Although some aspects of the bight ecology are known, much of the research is dated and fragmented, and required refreshing and consolidation in order to produce a platform upon which the understanding of the region’s ecosystem functioning could be established. Much of the oceanographic knowledge is also dated, with no dedicated surveys and significant measurements undertaken since 1989. The overarching theme of the KZN Bight project was to examine the relative importance of sources of nutrients to the central KZN coast and how these are taken up and recycled in the ecosystem, and to describe aspects of the benthic biodiversity, which is poorly described in much of this region. An ambitious project, its accessibility to a ship-based research platform and the diverse scientific skills of the participating scientists allowed considerable success, as reflected in the papers that follow.     

Latitudinal changes in siphonophore assemblages across the Atlantic sector of the Southern Ocean

Siphonophores are commonly considered to be useful indicators of water masses and water-mass movement, but their employment as such across the wider Southern Ocean has not so far been attempted. We redress this here using archived samples, collected during January–February 1993 along a transect from Cape Town to the South African National Antarctic Expedition (SANAE) base in Antarctica, and compare the patterns generated with those determined from a prior analysis of whole assemblages at lower taxonomic resolution. Twenty-one species were identified from 18 of the original 53 samples collected, and two distinct assemblages were confirmed as separated by the Sub-Antarctic Front. That to the south was characterised by low diversity and high abundance and was dominated by cold-water specialists, whereas that to the north comprised a larger number of subtropical and temperate species at low abundance. Assemblage structure was strongly influenced by the mixed layer depth, sea surface salinity and chlorophyll a concentration, as well as mesozooplankton biomass. Congruence with the whole-assemblage study was high, indicating that this taxon can be suitably employed as a proxy in studies such as this. The study emphasises the value of archived plankton samples and makes a plea for better curation.     

新疆哈密香山西铜镍-钛铁矿床系同源岩浆分异演化产物——矿相学、锆石U-Pb年代学及岩石地球化学证据

香山西岩体是东天山地区发现的唯一的一个铜镍-钛铁复合型含矿岩体,前人对香山西铜镍-钛铁矿床成因认识一直存在争议。本次通过矿相学研究结合电子探针分析,在香山西铜镍矿石中发现了铜镍硫化物与钛铁氧化物共生的现象,并首次测定了香山西钛铁辉长岩的SIMS锆石U-Pb年龄为278.6±1.8Ma(MSWD=1.2),与前人测得香山中岩体角闪辉长岩的锆石U-Pb年龄基本一致,证实了香山西铜镍矿与钛铁矿为共生关系,两者空间上渐变过渡。岩石地球化学研究表明,香山岩体(包括钛铁辉长岩)为同源岩浆经结晶分异作用形成的一套镁铁-超镁铁质岩体,具有拉斑玄武质岩浆分异演化趋势,并且经历了与地壳物质的混染。与中段和东段岩石相比,香山西辉长岩类具有相对高的REE、SiO₂(平均48.99%)、K₂O+Na₂O(平均3.43%)、TiO₂(平均1.26%)和明显低的Mg^#值(平均62.4),表现出分异演化程度高于中段和东段。经反演得出香山岩体原始岩浆含MgO约10%,FeO约9%,TiO₂约1.14%,与同一成矿带内其它含铜镍矿岩体原始岩浆成份相近,应为 普通的拉斑玄武质岩浆。因此,香山西钛铁矿床的形成机制可能是由普通的拉斑玄武质岩浆,经历了较高程度的分异演化导致钛铁氧化物在残余岩浆中逐步富集,岩浆在上升侵位过程中与地壳物质的混染,不仅促使了岩浆中硫化物的饱和,同时提高了岩浆体系的氧逸度,进而促使了钛铁氧化物结晶沉淀。对香山西钛铁矿床成因研究的启示意义在于,除我国攀西地区高钛的玄武质岩浆外,普通的拉斑玄武质岩浆,在有利的分异演化条件下(如初始低氧逸度、相对高度的分异演化、后期与地壳物质混染)也有可能形成大型钛铁矿床。     

Seasonal variations of the clear-sky greenhouse effect: the role of changes in atmospheric temperatures and humidities

We present an analysis of the factors which control the seasonal variations of the clear-sky greenhouse effect, based on satellite observations and radiative transfer simulations. The satellite observations include the radiation budget at the top of the atmosphere from the Earth Radiation Budget Experiment and the total column moisture content derived from the Special Sensor Microwave/Imager. The simulations were performed with the SAMSON system described in an earlier paper, using atmospheric temperatures and humidities from operational analyses produced by the European Centre for Medium Range Weather Forecasts. At low latitudes, the magnitude of the clear-sky greenhouse effect is dominated by the strong thermodynamic link between the total column moisture content of the atmosphere and sea surface temperatures, with minimal seasonal variations. In contrast, at middle to high latitudes there are strong seasonal variations, the clear-sky greenhouse effect being largest in winter and smallest in summer. These variations cannot be explained by the seasonal cycle in the total column moisture content, as this is largest in summer and smallest in winter. The variations are controlled instead by the seasonal changes in atmospheric temperatures. The colder atmosphere in winter enhances the temperature differential between the atmosphere and the sea surface, leading to a larger greenhouse effect despite the lower moisture contents. The magnitude of the clear-sky greenhouse effect is thus controlled by atmospheric humidity at low latitudes, but by atmospheric temperature at middle and high latitudes. These controls are illustrated by results from sensitivity experiments with SAMSON and are interpreted in terms of a simple model.     

Laser microprobe (U-Th)/He geochronology

A new analytical method had been developed to enable high-spatial-resolution (U-Th)/He dating of accessory minerals. It involves the use of a focused ArF excimer to ablate pits in a polished grain surface, with the evolved gases spiked for isotope-dilution measurement of radiogenic ⁴He. These data are converted to concentrations by precise measurement of each pit using an optical interferometric microscope. U, Th, and Sm concentration measurements are made using one of several alternative microanalytical techniques (e.g., wavelength-dispersive electron microprobe analysis or laser-ablation, inductively coupled plasma mass spectrometry). By way of illustration, we present both conventional and laser microprobe (U-Th)/He dating results for a Brazilian monazite sample. Laser microprobe data (28 measurements on two crystal fragments) yield a weighted mean (U-Th)/He date of 455.3 ± 3.7 Ma (2SE). This result is statistically indistinguishable from the mean conventional (U-Th)/He date for three separate grain fragments: 449.6 ± 9.8 Ma (2SE). The agreement of conventional and laser ablation dates should encourage a wide variety of applications of the technique, including: (1) detrital mineral dating for provenance and unroofing studies; (2) the dating of broken, included, highly zoned, or irregular grains which are not easily corrected for α-ejection; and (3) measuring ⁴He loss profiles that can be inverted to determine cooling histories.     

Turbulent mixing in a stratified estuarine tidal channel: Hikapu Reach,Pelorus Sound,New Zealand

Channel constrictions within an estuary can influence overall estuary-sea exchange of salt or suspended/dissolved material. The exchange is modulated by turbulent mixing through its effect on density stratification. Here we quantify turbulent mixing in Hikapu Reach, an estuarine channel in the Marlborough Sounds, New Zealand. The focus is on a period of relatively low freshwater input but where density stratification still persists throughout the tidal cycle, although the strength of stratification and its vertical structure vary substantially. The density stratification increases through the ebb tide, and decreases through the flood tide. During the spring tides observed here, ebb tidal flow speeds reached 0.7?m?s^?1 and the buoyancy frequency squared was in the range 10^?5 to 10^?3?s^?2. Turbulence parameters were estimated using both shear microstructure and velocimeter-derived inertial dissipation which compared favourably. The rate of dissipation of turbulent kinetic energy reached 1?×?10^?6?m²?s^?3 late in the ebb tide, and estimates of the gradient Richardson number (the ratio of stability to shear) fell as low as 0.1 (i.e. unstable) although the results show that bottom-boundary driven turbulence can dominate for periods. The implication, based on scaling, is that the mixing within the channel does not homogenise the water column within a tidal cycle. Scaling, developed to characterise the tidal advection relative to the channel length, shows how riverine-driven buoyancy fluxes can pass through the tidal channel section and the stratification can remain partially intact.     

Riverine influence determines nearshore heterogeneity of nutrient (C,N, P) content and stoichiometry in the KwaZulu-Natal Bight,South Africa

Riverine influences on nearshore oceanic habitats often have detrimental consequences leading to algal blooms and hypoxia. In oligo- to mesotrophic systems, however, nutrient delivery via rivers may stimulate production and even be a vital source of nutrients, as may nutrient supplements from upwelling. We investigated the nutrient content (C, N, P) and stoichiometry of sediment, and several pelagic, benthopelagic and benthic species in the KwaZulu-Natal (KZN) Bight, a narrow shelf area on the south-east coast of South Africa, bordering the Agulhas Current. Three suggested nutrient sources to the bight are the Thukela River in the central region of the bight, upwelling in the northern part and a semi-permanent eddy (Durban Eddy) in the southern part. Elemental content of the various groups studied showed significantly higher values for most groups at the site near the Thukela River. C:P and N:P were highest in the southern part of the bight, and lowest near the Thukela Mouth or at Richards Bay in the north, indicating the latter were the P-richer sites. Sediment organic matter showed lowest elemental content, as expected, and zooplankton stoichiometry was highest compared to all other biotic groups. Environmental heterogeneity played a greater role in organismal C, N and P content and stoichiometry compared to phylogeny, with the exception of the differences in C:P and N:P of zooplankton. From this bight-wide study, the higher elemental content and lower ratios at the Thukela Mouth site supported previous findings of the importance of coastal nutrient sources to the bight ecosystem. Reductions in river flow for water use in the catchment areas may therefore have negative consequences for the productivity of the entire ecosystem.