Geochemical and Isotopic Evidence for Crustal Assimilation Beneath Krafla, Iceland

The Krafla volcanic system consists of a central volcano andassociated fissure swarm in the NE axial rift zone of Iceland.Lavas spanning the whole of Krafla's exposed volcanic history(estimated to be 0-> 300 ka) have been analysed and rangein composition from olivine tholeiite to rhyolite. Major-elementcompositions suggest that fractional crystallization exertsthe main control over the differentiation process. However,K₂O and the very incompatible trace elements, Rb, Th, and U,are all enriched beyond the extent expected by closed-systemfractional crystallization. Fractionation coupled with periodicreplenishment and tapping of the reservoir is unlikely to beresponsible for this enrichment, despite the geophysical evidencesuggesting a large number of inflations and deflations of ashallow magma reservoir (Tryggvason, 1986). Th- and O-isotope results confirm the work of previous authorsthat crustal assimilation is operating on a local scale beneathKrafla. A model is suggested, fitting both the Th- and O-isotopicdata, which involves the partial melting and incorporation ofa hydrothermally altered wall-rock contaminant during fractionalcrystallization (i. e., AFC processes). This process of partialmelting is likely to enhance the most highly incompatible elementconcentrations (e. g., increasing Rb/Zr) more than expectedby closed-system fractional crystallization.     

Experimental Crystallization of a High-K Arc Basalt: the Golden Pumice, Stromboli Volcano (Italy)

The near-liquidus crystallization of a high-K basalt (PST-9golden pumice, 49·4 wt % SiO₂, 1·85 wt % K₂O,7·96 wt % MgO) from the present-day activity of Stromboli(Aeolian Islands, Italy) has been experimentally investigatedbetween 1050 and 1175°C, at pressures from 50 to 400 MPa,for melt H₂O concentrations between 1·2 and 5·5wt % and NNO ranging from –0·07 to +2·32.A drop-quench device was systematically used. AuPd alloys wereused as containers in most cases, resulting in an average Feloss of 13% for the 34 charges studied. Major crystallizingphases include clinopyroxene, olivine and plagioclase. Fe–Tioxide was encountered in a few charges. Clinopyroxene is theliquidus phase at 400 MPa down to at least 200 MPa, followedby olivine and plagioclase. The compositions of all major phasesand glass vary systematically with the proportion of crystals.Ca in clinopyroxene sensitively depends on the H₂O concentrationof the coexisting melt, and clinopyroxene Mg-number shows aweak negative correlation with NNO. The experimental data allowthe liquidus surface of PST-9 to be defined. When used in combinationwith melt inclusion data, a consistent set of pre-eruptive pressures(100–270 MPa), temperatures (1140–1160°C) andmelt H₂O concentrations is obtained. Near-liquidus phase equilibriaand clinopyroxene Ca contents require melt H₂O concentrations<2·7–3·6 and 3 ± 1 wt %, respectively,overlapping with the maximum frequency of glass inclusion data(2·5–2·7 wt % H₂O). For olivine to crystallizeclose to the liquidus, pressures close to 200 MPa are needed.Redox conditions around NNO = +0·5 are inferred fromclinopyroxene compositions. The determined pre-eruptive parametersrefer to the storage region of golden pumice melts, which islocated at a depth of around 7·5 km, within the metamorphicarc crust. Golden pumice melts ascending from their storagezone along an adiabat will not experience crystallization ontheir way to the surface. KEY WORDS: basalt; pumice; experiment; phase equilibria; Stromboli     

Morphology and facies architecture of a falling sea level strandplain, Umiujaq, Hudson Bay, Canada

Coastal strandplain deposits near Umiujaq, eastern Hudson Bay, Canada, were formed under falling relative sea level conditions resulting from postglacial isostatic uplift. Ground-probing radar profiles across the strandplain reveal a lower progradational unit (LPU) discordantly overlain by an upper progradational unit (UPU), which were correlated with stratigraphic sections exposed in incised valley walls. The discordance is a wave erosion surface (WES) that separates fine shoreface sands of the LPU from coarse-sand and gravel of the UPU. Major basal downlap surfaces can be traced updip into marine terraces and define downstepping wedges. The downstepping is interpreted as representing ‘autocyclic’ morphological reconfiguration rather than a response to changes in the rate of sea level fall. The internal architecture is strongly dependent on the accommodation and thus on antecedent topography. A conceptual model for strandplain deposition under falling sea level incorporates a bipartite shallowing-upward sandy succession when sufficient accommodation is available. Where accommodation space is limited, a sharp-based bar-and-beach sandbody directly overlies muddy deeper water deposits and the WES resembles a regressive surface of erosion.     

Reversal of Fe-Mg Partitioning Between Garnet and Staurolite in Eclogite-facies Metapelites from the Champtoceaux Nappe (Brittany, France)

This paper concentrates on the petrology of eclogite-faciesmetapelites and, particularly, the significance of staurolitein these rocks. A natural example of staurolite-bearing eclogitic micaschistsfrom the Champtoceaux nappe (Brittany, France) is first described.The Champtoceaux metapelites present, in addition to quartz,phengite, and rutile, two successive parageneses: (1) chloritoid+staurolite+garnetcores, and (2) garnet rims+kyanite?chloritoid. Detailed microprobe analyses show that garnet and chloritoidevolve towards more magnesian compositions and that stauroliteis more Fe-rich than coexisting garnet. A comparison of thestudied rocks with other known occurrences of eclogitic metapelitesshows that whereas staurolite is always more Fe-rich than garnetin high-pressure eclogites, the reverse is true in low- to medium-pressuremicaschists. Phase relations between garnet, staurolite, chloritoid, biotite,and chlorite are analysed in the KFMASH system (with excessquartz, phengite, rutile, and H₂O). The topology of univariantreactions is depicted for a normal and a reverse Fe-Mg partitioningbetween garnet and staurolite. Mineral compositional changesare also predicted for varying bulk-rock chemistries. In the studied micaschists, the zonal arrangement of garnetinclusions and the progressive compositional changes of ferromagnesianphases record part of the prograde P–T path, before theattainment of ‘peak’ metamorphic conditions (atabout 65O–7OO?C, 18–20 kb). The retrograde path,which records the uplift of the Champtoceaux nappe, occurs underdecreasing temperatures.     

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La méthode classique de simulation d'une nappe captive consiste à résoudre le problème en régime transitoire à partir de la situation originelle. Dans cet article est présentée une méthode qui permet de déterminer directement l'état de la nappe à un instant donné si l'on peut connaître la chute piézométrique à cet instant.     

The origin and glaciodynamic significance of sandstone ridge networks from the Hirnantian glaciation of the Djado Basin (Niger)

The Djado Basin (Niger) was located beneath the inner part of the Late Ordovician ice sheet. The Felar‐Felar Formation consists mainly of glaciomarine deposits, associated with the major ice sheet recession within the glaciation, and is bounded by two glacial unconformities. Structures corresponding to sandstone ridges are found within the Felar‐Felar Formation. Sandstone ridges are several metres high, about 10 m wide and hundreds of metres long. These structures are organized in extensive anastomosed to sub‐polygonal networks. The association of sandstone ridge networks with the later glacial unconformity and with other glacial evidence suggests sub‐glacial conditions for their origin. Sandstone ridge sedimentological characteristics indicate that sandstone ridges result from the scouring of the Felar‐Felar Formation by sub‐glacial, turbulent and pressurized meltwater; then sub‐glacial cavities were infilled with sand derived from glacial abrasion. Sandstone ridge networks are comparable with tunnel channels and document unusual drainage structures of the inner part of the palaeo‐ice sheet.     

Petrological and Experimental Constraints on the Pre-eruption Conditions of Holocene Dacite from Volcan San Pedro (36{degrees}S, Chilean Andes) and the Importance of Sulphur in Silicic Subduction-related Magmas

We present an experimental and petrological study aimed at estimatingthe pre-eruptive conditions of a Holocene dacitic lava fromVolcán San Pedro (36°S, Chilean Andes). Phase-equilibriumexperiments were performed at temperatures (T) from 800 to 950°C,and mainly at 200 MPa, but also at 55, 150, and 406 MPa. Oxygenfugacity (fO₂) ranged from the Ni–NiO buffer (NNO) to3·5 log units above (NNO + 3·5), and water contentsfrom