Thermal histories of IVA iron meteorites from transmission electron microscopy of the cloudy zone microstructure

Abstract— We have measured the size of the high‐Ni particles in the cloudy zone and the width of the outer taenite rim in eight low shocked and eight moderately to heavily shocked IVA irons using a transmission electron microscope (TEM). Thin sections for TEM analysis were produced by a focused ion beam instrument. Use of the TEM allowed us to avoid potential artifacts which may be introduced during specimen preparation for SEM analysis of high Ni particles <30 nm in size and to identify microchemical and microstructural changes due to the effects of shock induced reheating. No cloudy zone was observed in five of the eight moderately to highly shocked (>13 GPa) IVA irons that were examined in the TEM. Shock induced reheating has allowed for diffusion from 20 nm to 400 nm across kamacite/taenite boundaries, recrystallization of kamacite, and the formation, in Jamestown, of taenite grain boundaries. In the eleven IVA irons with cloudy zone microstructures, the size of the high‐Ni particles in the cloudy zone increases directly with increasing bulk Ni content. Our data and the inverse correlation between cooling rate and high‐Ni particle size for irons and stony‐irons show that IVA cooling rates at 350‐200 °C are inversely correlated with bulk Ni concentration and vary by a factor of about 15. This cooling rate variation is incompatible with cooling in a metallic core that was insulated with a silicate mantle, but is compatible with cooling in a metallic body of radius 150 ± 50 km. The widths of the tetrataenite regions next to the cloudy zone correlate directly with high‐Ni particle size providing another method to measure low temperature cooling rates.     

The Effects of Fe3? and Mn3? on Aluminum Silicate Phase Relations in North-Central New Mexico, U.S.A.

Aluminum silicate triple-point occurrences are common in metamorphicrocks of northern New Mexico. The three polymorphs show extensivesolid solution, with Fe and Mn substituting for Al. Mineraltextures, the spatial distribution of phases, and the systematicpartitioning of Fe and Mn indicate that the kyanite-andalusite-sillimaniteassemblages crystallized in equilibrium. The compositions ofminerals in the three-phase assemblage vary across the studyarea, recording regional variations in the pressures and temperaturesof metamorphism. The highest-pressure rocks, exposed at RioMora, contain kyanite at higher elevations and sillimanite atlower elevations. A sub-horizontal isograd separates the twominerals. Kyanite and sillimanite have nearly identical Fe contentwhich varies systematically with X_Fe2O3 in hematite or ilmenite.Andalusite occurs only along a single manganiferous layer, incrystals rich in MnAlSiO₅ and saturated in FeAlSiO₅. Triple-pointassemblages can be found wherever the folded manganiferous layercrosses the unfolded kyanite-sillimanite isograd. The TruchasRange, preserving slightly lower pressures of metamorphism,shows kyanite-andalusite-sillimanite in rocks with titaniferoushematite. Andalusite is enriched in Fe relative to kyanite andsillimanite, but no polymorphs contain Mn. Rocks with lowerX_Fe2O3 in hematite have kyanite and sillimanite without andalusite,whereas rocks with pure hematite contain only andalusite. Theshallowest erosional levels are preserved in the western PicurisRange where the three polymorphs occur as pure minerals in ilmenite-bearingrocks. Hematitic samples contain only andalusite which showsextensive solid solution of both Fe and Mn. The assemblage kyanite-andalusite-sillimanite is not invariant.Iron and manganese both add degrees of freedom. These transitionmetals have stabilized the three-phase assemblage, in apparentchemical equilibrium, across a P-T interval of 500-540 ?C, 3?8-4?6kb in rocks from New Mexico. The saturation level of FeAlSiO5in andalusite does not vary with Mn content but does vary withpressure and temperature. Calculations indicate that a 2-3 kbdecrease in pressure or a 25-50 ?C increase in temperature resultsin a 1 mole per cent increase in X_FeAlSiO5 in iron-saturatedandalusite.     

ESTABLISHING LICHENOMETRIC AGES FOR NINETEENTH- AND TWENTIETH-CENTURY GLACIER FLUCTUATIONS ON SOUTH GEORGIA (SOUTH ATLANTIC)

Glaciers in small mountain cirques on South Georgia respond rapidly and sensitively to changes in South Atlantic climate. The timing and rate of their deglaciation can be used to examine the impact that nineteenth- and twentieth-century climate change has had on the glacial dynamics and terrestrial ecosystems of South Georgia. As part of a reconnaissance study in Prince Olav Harbour (POH), South Georgia, we measured the size of lichens ( Rhizocarpon Ram. em Th. Fr. subgenus. Rhizocarpon group) on ice-free moraine ridges around two small mountain cirques. Our aims were twofold: first, to provide age estimates for lichen colonization, and hence, deglaciation of the moraine ridges, and second, to examine the potential of applying lichenometry more widely to provide deglacial age constraints on South Georgia. In the absence of lichen age-size (dating) curves for South Georgia, we use long-term Rhizocarpon lichen growth-rates from recent studies on sub-Antarctic Islands and the western Antarctic Peninsula to calculate likely age estimates. These data suggest ice retreat from the two outermost moraines occurred between the end of the 'Little Ice Age' (post c. 1870) and the early twentieth century on South Georgia. Lichen colonization of the innermost moraines is probably related to glacier retreat during the second half of the twentieth century, which has been linked to a well-defined warming trend since c. 1950. Patterns of possible nineteenth- and twentieth-century glacial retreat identified in POH need to be tested further by establishing species- and site-specific lichen age-size (dating) curves for South Georgia, and by applying lichenometry to other mountain cirques across South Georgia.     

Pleistocene stratigraphy of Kongsfjordhallet, Spitsbergen, Svalbard

Open sections along Kongsfjodhallet, the north-western coast Kongsfjorden, Svalbard, exhibit marine and glacigenic sediments of Early to Late Plestocene age. Glaciatio, deglaciation and subsequent isostatic rebound caused the formation of three sedimentary successions (A, B and C) that comprise till grading upward into glaciomarine mud, followed by shell-bearing sand, and finally littoral sand and gravel. Six major lithostratigraphic units are recognized. Succession C comprises units 1 and 2, which were deposited during an Early Pleistocene glaciation, followed by deglaciation and subsequent beach progradation. Succession B is divisible into units 3 and 4 and reflects glaciation and eventual emergence as a result of isostatic response. The youngest succesion (A) comprises units 5 and 6, and reflects fiord glaciation followed by a regression during an Early Weichselian glaciation-deglaciation episode. Ice-free conditions may have prevailed untill the Late Weichselian, when a glaciation, confined to the fiord trough, covered parts of Kongsfjordhallet. Deglaciation and isostatic rebound are recorded by Holocene marine terraces up to ca 40 m a. s. l.
Marine and glacial events from Kongsfjordhallet are compared with stratigraphic evidence from adjacent regions and it is suggested that the Late Weichselian ice configuration was of a more restricted nature than proposed by previous authors. Glaciers. draining through the larger ford troughs reached the shelf break. while at the same time other parts of western Svalbard could have experienced restricted glaciation.     

Origin of well-rounded gravels in glacial deposits from Brøggerhalvøya, northwest Spitsbergen: potential problems caused by sediment reworking in the glacial environment

Well-rounded gravels are described from moraine-mound complexes, diamicton forefields and modern englacial thrusts at the margins of four glaciers on the northern side of Brøggerhalvøya, northwest Spitsbergen. Their shape charcteristics are compared with modern and fossil glacigenic, modern beach and Early Weichselian beach gravels from this peninsula. The best discriminators of the well-rounded gravels have been found to be the percentage-frequency roundness histograms, the roundness mid-point and roundness range diagrams and the sphericity-roundness plots. It is concluded that the gravels have been derived by englacial thrusting from Early Weichselian or last interglacial beaches in the inner parts of the fjord and in the low level cirques when sea level reached at least 50m a.s.l. and deposited the beach gravels. The discrimination between gravel in basal diamictons, proglacial outwash and modern beaches is difficult as the reworking has resulted in little particle shape change. The potential major problem caused by reworking in the glacial environment is emphasised. especially when clast shape comparisons from modern environments to older sediments are used.     

Sea level control of stacked late Quaternary coastal sequences, central Great Barrier Reef

Lithofacies analysis, pollen assemblages and radiocarbon age dates of 20 stratigraphic drill holes are used to develop an evolutionary history for late Quaternary sedimentation in two coastal embayments landward of the central Great Barrier Reef. Different physiographic settings of the embayments result in two contrasting styles of sedimentary sequence: (a) an exposed, moderate energy, beach barrier-lagoon system (Wyvuri Embayment) and (b) a protected, low energy, muddy inlet fill sequence (Mutchero Inlet). Despite sharp contrast in sequence style, similar depositional cycles occur in both embayments in response to late Quaternary sea level fluctuations including: (1) a last interglacial highstand (+2 m; c. 125 000 yr bp ) beach barrier (Wyvuri); (2) an early to mid-Holocene (8000–6100 yr bp ) transgressive beach barrier-lagoon (Wyvuri) and estuarine infill (Mutchero); and (3) mid-Holocene to present highstand beach barrier (Wyvuri) and estuarine (Mutchero) progradation. Preservation of such cycles in the stratigraphic record would produce a series of vertically stacked and offset linear barrier sands surrounded by lagoonal mud and fine grained shoreface sediment juxtaposed to muddy, estuarine infills. Sea level elevations are well recorded by the upward transition from Rhizophora-dominated intertidal mangrove mud to freshwater swamp (clearly identified by pollen analysis) and by the basal contacts of beach barrier sediments which sharply overlie the upper shoreface. Transgressive sedimentation is interrupted in both embayments by a constructional beach barrier (Wyvuri) and abbreviated progradation (Mutchero) corresponding to a — 5 m pause in relative sea level rise at c. 6800 yr bp . Sea level control of fine scale coastal sedimentation patterns is beginning to be widely recognized and provides an accurate analogue for stacked ancient sequences.     

Development of Arctic sea-ice organisms under graded snow cover

In 1988, the short-term response of sea-ice organisms to manipulated changes in snow cover (no snow cover, natural snow cover, natural snow cover + black foil) was investigated in one ice floe located in the East Greenland Current northwest of Svalbard over a period of three weeks. Autotrophic organisms (flagellates and diatoms) were concentrated in the lowermost 30 cm of the floe. In the field without snow cover, the highest diatom concentrations were observed, consisting nearly entirely of pennate forms, together with a maximum bacterial abundance. The community of larger protozoa and smaller metazoa was dominated by ciliates. Under natural conditions the flora consisted of both flagellates and diatoms, while turbellaria were the dominating animals. In the darkened field, the organism concentrations decreased with time. The results indicate that brine drainage, induced by changes in ice temperature, can reduce concentrations of ice organisms over short time scales.     

“THE END OF MODERN HISTORY”?*

ABSTRACT. The first half of the twentieth century marked both an end to confidence in human control of the earth and a prelude to the contemporary era of intense environmental concern after 1950. This conspectus of the environmental history/historical geography of the transitional years between 1900 and 1950 focuses on rising concerns over resource supplies and exploitation, particularly land settlement, timber supplies, soil erosion, and river-basin control. Conservation and the pervasiveness of ecological thinking and analogy form a strong underlying theme.     

CELEBRATING CENTRIFUGAL FORCES IN AMERICAN GEOGRAPHY

GEOGRAPHY IN AMERICA AT THE DAWN OF THE 21^ST CENTURY. Edited by GARY L. GAILE and CORT J. WILLMOTT.