Fayalitic olivine in CV3 chondrite matrix and dark inclusions: A nebular origin

Abstract— Fayalitic olivine (Fa₃₂) is the major component of the matrices and dark inclusions of CV3 and other unequilibrated chondrites. It occurs most commonly as rims, veins and halos in and around chondrule silicates in the Allende-type (CV3_OXA) chondrites and, to a much lesser extent, in the reduced (CV3R) and Bali-type (CV3OXB) chondrites. The olivines have distinctive platy, tabular and lath- or irregular-shaped crystals, with the ratio of the two types varying widely. In CV3_OXB chondrites, matrix fayalitic olivines range up to Fag_99.9; whereas, in the other CV3 chondrites, the range is much smaller. The platy and tabular anisotropic forms of the fayalitic olivines strongly suggest growth from a vapor, and the nature of the occurrences suggests that CV3 matrices are unequilibrated mixtures of nebular materials. We argue that the parent body hydration/dehydration model has numerous inconsistencies that make this hypothesis highly unlikely. These include: (1) There is no direct evidence linking fayalitic olivine to precursor phyllosilicates. (2) Dehydration of phyllosilicates cannot explain the wide range of morphologies of the fayalitic olivines. (3) Fayalitic olivine clearly predates the formation of the hydrous phases in CV3 chondrites and is one of the phases that breaks down to form phyllosilicates (Keller et al., 1994). (4) The unequilibrated nature of the matrix, including fine-scale zoning in 10 μm sized fayalitic olivine crystals, would not survive the parent body metamorphism required in the dehydration model. (5) A dark inclusion in the Ningqiang chondrite contains fayalitic olivine rimmed by glassy and microcrystalline material (Zolensky et al., 1997), which probably formed by radiation damage. This indicates that the fayalitic olivine was exposed to solar radiation in a nebular setting. (6) Some Allende chondrules contain unaltered primary, anhydrous glassy mesostasis in contact with the host matrix (e.g., Ikeda and Kimura, 1995). Chondrule mesostases would not have survived parent body hydration without becoming hydrated and would probably not survive the metamorphic heating required in the dehydration scenario. (7) Single platy and barrel-shaped crystals of fayalitic olivine are present in accretionary rims in calcium-aluminum-rich inclusions (CAIs) (MacPherson and Davis, 1997), which developed in the nebula. (8) Matrix lumps completely encased in chondrules in ordinary chondrites contain mainly fayalitic olivine (Scott et al., 1984), which indicates a nebular origin. (9) Oxygen isotopic compositions of Allende matrix and dark inclusions strongly indicate little or no hydration for Allende and its components (Clayton, 1997). We favor a nebular vaporization/recondensation model in which vaporization of chondritic dust produced a fayalite-rich vapor, followed by formation of the fayalitic olivine by direct recondensation from the vapor, epitactic growth on surfaces of existing forsterite and enstatite in chondrules, and replacement of existing forsterite and enstatite by gas-solid exchange.     

Object-oriented data modelling for spatial databases

Data modelling is a critical stage of database design. Recent research has focused upon object-oriented data models, which appear more appropriate for certain applications than either the traditional relational model or the entity-relationship approach. The object-oriented approach has proved to be especially fruitful in application areas, such as the design of geographical information systems which have a richly structured knowledge domain and are associated with multimedia databases. This article discusses the key concepts in object-oriented modelling and demonstrates the applicability of an object-oriented design methodology to the design of geographical information systems. In order to show more clearly how this methodology may be applied, the paper considers the specific object-oriented data model IFO. Standard cartographic primitives are represented using IFO, which are then used in the modelling of some standard administrative units in the United Kingdom. The paper concludes by discussing current research issues and directions in this area.     

Zircon microstriators in the sand of auriferous Andean tills: fine tools and noble metals

Chemically inert and physically hard minerals, of which zircon is universally present and usually abundant, are minor but important components of glacial gold and tin placer deposits. Zircons and other much less common resistant minerals inflict major damage on light minerals, of which quartz is the dominant, chemically resistant member. Because of its sharpness inherited from a strong crystal morphology, and overall prismatic form, zircon is especially important as an abrasive mineral in glacial systems. Its chemically inert nature, its dominancc in terms of hardness over light minerals, and its abundance amongst other hard minerals makes it unique and important as a microstriator. Transported in a highly viscous glacial medium, it is capable of damaging other softer grains with aggressive crushing, chipping, striating, abrading and polishing processes. These occur in both coarse-grained gravelly sand and in fine-grained clayey silt matrices at the base of the icc. Zircon grains tend to serve many functions, initially as inclusion tools in larger feldspar grains and as 'studs' in quartzite grains. Wearing first on points, and later, following liberation, they assume a shape by honing, faceting and fracturing as tools and as grit that allows them to act as microstriators, inflicting damage on other particles in the basal ice. With a hardness of 7.5, lacking significant cleavage, and exhibiting strong crystal form. the finer-grained zircons appear to abrade and striate quartz (hardness 7.0). feldspars (hardness 6.0). garnets (hardness 6.5–7.5), and gold (hardness 2.5-3.0). A detailed study of Bolivian tills shows the dominant form of the zircon striator to be an elongate, pencil shape (euhedral polygonal prism with sharp, pyramidal terminations) that shows various degrees of abrasion, and ranges from wide grains with dull edges to narrow grains with sharp edges (typical pencil form).     

The ice-dammed lakes of Ossian Sarsfjellet (Svalbard): their geomorphology and significance

The tidewater glacier complex of Kongsvegen/Kronebreen, at the head of Kongsfjorden in north-west Spitsbergen, has advanced rapidly several times since its Neoglacial maximum. Two such advances, 1869 and 1948, are well constrained in time and space and are widely interpreted as glacier surges. During the 1869 advance an ice-dammed lake formed on the western side of Ossian Sarsfjellet. This ice-dammed lake is associated with a thrust moraine complex. Four lake levels are identified, two of which are associated with rock-cut shorelines implying a degree of lake stability. The history of this lake, the nature of the ice dam and its relationship to the thrust moraine complex are discussed. The lake history spanning 28 to 35 years is used to assess the ice-marginal dynamics of the Kongsvegen/Kronebreen glacier. It is concluded that, contrary to previous suggestions, the rapid advance of this tidewater glacier may simply be an example of a non-climatic ice-marginal fluctuation, of the type common to tidewater glacier, as opposed to a glacier surge. A second ice-dammed lake, to the east of Ossian Sarsfjellet, formed sometime after 1869 as the ice retreated, and still exists today. This largely supraglacial lake is associated with a very different geomorphological assemblage, which has a poor long-term preservation potential. The geomorphological characteristics of the two lakes on Ossian Sarsfjellet are compared and used to discuss the problems associated with the recognition of ice-dammed lakes within the Pleistocene record. On the basis of the evidence presented here, ice-dammed lakes may be more common during deglaciation than currently suggested.     

Unpairing metamorphic belts: P–T paths and a tectonic model for the Ryoke Belt, southwest Japan

Southwest Japan is divided into Outer and Inner Zones by the Median Tectonic Line (MTL), a major transcurrent fault. The Outer Zone is composed of the Sambagawa (high-pressure intermediate or high P/T type metamorphism), Chichibu and Shimanto Belts. In the Inner Zone, the Ryoke Belt (andalusite– sillimanite or low P/T type metamorphism) was developed mainly within a Jurassic accretionary complex. This spatial relationship between high P/T type and low P/T type metamorphic belts led Miyashiro to the idea that metamorphic belts were developed as ‘paired’ systems. Textural relationships and petrogenetically significant mineral assemblages in pelites from the Ryoke Belt imply peak P–T conditions of ≈5 kbar and up to 850 °C in migmatitic garnet–cordierite rocks from the highest-grade metamorphic zone. It is likely that the thermal anomaly responsible for metamorphism of the Ryoke Belt was related to a segment of the Farallon–Izanagi Ridge as it subducted under the eastern margin of the Asian continent during the Cretaceous. The sequence of mineral assemblages developed in pelites implies a metamorphic field gradient with shallow dP/dT slope, inferred to have been generated by a nested set of hairpin-like ‘clockwise’P–T paths. These P–T paths are characterized by limited prograde thickening, minor decompression at peak-T , and near-isobaric cooling, features that may be typical of P–T paths in low P/T type metamorphic belts caused by ridge subduction. A ridge subduction model for the Ryoke Belt implies that juxtaposition of the high-P/T metamorphic rocks of the Sambagawa Belt against it was a result of terrane amalgamation. Belt-parallel ductile stretching, recorded as syn-metamorphic, predominantly constrictional strain in both Ryoke and Sambagawa Belt rocks, and substantial sinistral displacement on the MTL are consistent with left-lateral oblique convergence. Diachroneity in fast cooling of the Ryoke Belt is implied by extant thermochronological data, and is inferred to relate to progressive SW to NE docking of the Sambagawa Belt. Thus, an alternative interpretation of ‘paired’ metamorphic belts in Japan is that they represent laterally contemporaneous terranes, rather than outboard and inboard components of a trench/arc ‘paired’ system. Amalgamation of laterally contemporaneous terranes during large translations of forearcs along continental margins may explain other examples of ‘paired’ metamorphic belts in the geological record.     

Thermal and impact histories of reheated group IVA,IVB, and ungrouped iron meteorites and their parent asteroids

Abstract– The microstructures of six reheated iron meteorites—two IVA irons, Maria Elena (1935), Fuzzy Creek; one IVB iron, Ternera; and three ungrouped irons, Hammond, Babb’s Mill (Blake’s Iron), and Babb’s Mill (Troost’s Iron)—were characterized using scanning and transmission electron microscopy, electron‐probe microanalysis, and electron backscatter diffraction techniques to determine their thermal and shock history and that of their parent asteroids. Maria Elena and Hammond were heated below approximately 700–750 °C, so that kamacite was recrystallized and taenite was exsolved in kamacite and was spheroidized in plessite. Both meteorites retained a record of the original Widmanstätten pattern. The other four, which show no trace of their original microstructure, were heated above 600–700 °C and recrystallized to form 10–20 μm wide homogeneous taenite grains. On cooling, kamacite formed on taenite grain boundaries with their close‐packed planes aligned. Formation of homogeneous 20 μm wide taenite grains with diverse orientations would have required as long as approximately 800 yr at 600 °C or approximately 1 h at 1300 °C. All six irons contain approximately 5–10 μm wide taenite grains with internal microprecipitates of kamacite and nanometer‐scale M‐shaped Ni profiles that reach approximately 40% Ni indicating cooling over 100–10,000 yr. Un‐decomposed high‐Ni martensite (α₂) in taenite—the first occurrence in irons—appears to be a characteristic of strongly reheated irons. From our studies and published work, we identified four progressive stages of shock and reheating in IVA irons using these criteria: cloudy taenite, M‐shaped Ni profiles in taenite, Neumann twin lamellae, martensite, shock‐hatched kamacite, recrystallization, microprecipitates of taenite, and shock‐melted troilite. Maria Elena and Fuzzy Creek represent stages 3 and 4, respectively. Although not all reheated irons contain evidence for shock, it was probably the main cause of reheating. Cooling over years rather than hours precludes shock during the impacts that exposed the irons to cosmic rays. If the reheated irons that we studied are representative, the IVA irons may have been shocked soon after they cooled below 200 °C at 4.5 Gyr in an impact that created a rubblepile asteroid with fragments from diverse depths. The primary cooling rates of the IVA irons and the proposed early history are remarkably consistent with the Pb‐Pb ages of troilite inclusions in two IVA irons including the oldest known differentiated meteorite ( Blichert‐Toft et al. 2010 ).