Observational estimation of heat budgets on drifting ice and open water over the Arctic Ocean

It is of major scientific interests to determine the parameters of momentum, heat and vapor exchange in the planetary boundary layer in order to study the effects of ocean-ice-atmosphere interactions and their feedback mechanisms on global climate[1]. Lin…     

The geometry and petrogenesis of hydrothermal dolomites at Navan, Ireland

The dolomites at Navan, Ireland, formed in Courceyan peritidal and shallow-shelf limestones. The dolomite body has a plume-like geometry, cross-cutting both lithological boundaries and diagenetic barriers generated by sea-floor cementation and emergence. The dolomitizing fluids rose parallel to major faults to diffuse laterally through the succession, controlled by variations in permeability that reflect both facies variation on deposition and pre-dolomitization diagenesis. Cathodoluminescent zones reveal three principal stages of dolomite emplacement, separated by dissolution surfaces, with each stage reflecting several changes in the character of dolomitizing solutions. The predominance of dull zones indicates burial rather than surface conditions. The dolomites formed some time after burial in response to an areally limited hydrothermally-driven flow. Isotope values (σ¹⁸O of — 6σ6 to — 10.4%_δ and σ¹³C of — 0σ2 to +2σ5%_δ PDB), and fluid inclusion data, suggest that these fluids had compositions similar to those of Carboniferous seawater. However, these became hotter with time, with temperature increasing from 60 to 160δC. The Navan dolomites are closely associated with Europe's largest zinc-lead deposit. The distribution of the ores follows the same trend as that of the dolomites and paragenetic relationships indicate that dolomitization and mineralization were temporally and genetically related.     

The OSO-1 solar neutron experiment

BF₃ counters on OSO-1 were used to look for solar neutrons by trying to observe a diurnal variation in count rate. No effect was observed and an upper limit was placed on the solar neutron flux at the earth of J _n < 2 × 10^–3 neut/cm²/sec of 10 keV < E _n < 10 meV for the period March to May 1962. No proton-producing flares occurred during this time, so the most obvious source of solar neutrons could not be studied. The emulsion experiment of Apparao et al., flown during this period, which seemed to indicate solar neutrons has probably been misinterpreted.     

Cloud effects on air-sea interactions during the 1979 Indian summer monsoon as studied from satellite observations

Summary The Indian summer monsoon, one of the earth's most vigorous and energetic seasonally occurring weather events, influences the global atmospheric circulation. Its onset, duration, and intensity are governed by large- and meso-scale geophysical processes, such as surface solar heating and air-sea interactions. In this paper, using innovative combinations of satellite sensor data, we investigate some of these fundamental processes which are closely tied to clouds and control the monsoon system's evolution. The study, which focuses on the monsoon period of June, 1979, examines the low-frequency variability of clouds and their effects on air-sea processes through an analysis of the complex influence clouds play on the surface heat and water budgets. First, the effects of clouds on both the solar and longwave components of the surface radiation budget are assessed using a cloud radiative forcing parameter. While the effects of clouds on the long-wave irradiance act in a manner opposite to their effects on the shortwave irradiance, only a partial compensation is found to take place and the net effect results in a maximum cloud forcing of 60 Wm^–2 in the southwestern Arabian Sea. Second, employing satellite-derived precipitation and evaporation estimates, the paper analyzes the net surface fresh water budget variability around the monsoon onset. This budget is important in that fresh water affects the upper ocean density distribution and, consequently, the thermohaline circulation. Two regions are found to dominate the analysis: the western Arabian Sea, where evaporation is dominant by more than 10 mm day^–1, and the eastern Arabian Sea, where precipitation is dominant by more than 10 mm day^–1. Thus, a strong zonal gradient of fresh water at the surface is established during the monsoon. The last topic investigated is the intraseasonal variability of convection as analyzed using a cloud parameter indicative of deep convection. Cloud oscillations of 30–50 days, associated with the different phases of the monsoon, are found to propagate northward in the eastern Indian Ocean and eastward in the Bay of Bengal. Our analysis not only supports the hypothesis that the 30–50-day oscillation is driven by deep convection but also, and more importantly, suggests that the ocean thermal forcing is modulated by 30–50-day oscillations through cloud-induced surface radiative forcing. Although the results presented are limited in scope and preliminary because of the diffculty in quantifying the accuracy of the parameters examined, they do demonstrate: 1) the role of clouds in modulating the surface heat and water budgets, 2) the advantage of using combinations of multi-sensor and multi-platform satellite observations to quantify interrelated surface heat/water budget processes, and 3) the potential to examine the intraseasonal variability of air-sea interaction processes associated with the monsoon, even though these processes are not directly measurable from space.With 6 FiguresB. DiJulio passed away in September 1990.     

Tropospheric Ozone in a Global-Scale Three-Dimensional Lagrangian Model and Its Response to NOX Emission Controls

A three-dimensional Lagrangian tropospheric chemistry modelis used toinvestigate the impact of human activities on the tropospheric distributionofozone and hydroxyl radicals. The model describes the behaviour of 50 speciesincluding methane, carbon monoxide, oxides of nitrogen, sulphur dioxide andnineorganic compounds emitted from human activities and a range of other sources.Thechemical mechanism involves about 100 chemical reactions of which 16 arephotochemical reactions whose diurnal dependence is treated in full. The modelutilises a five minute chemistry time step and a three hour advection timestepfor the 50,000 air parcels. Meteorological data for the winds, temperatures,clouds and so on are taken from the UK Meteorological Office global model for1994 onwards. The impacts of a 50% reduction in European NO_Xemissions onglobal ozone concentrations are assessed. Surface ozoneconcentrations decrease in summertime and rise in wintertime, but to differentextents.     

Temperature dependence of the cation distribution in nickel aluminate (NiAl2O4) spinel: a powder XRD study

NiAl₂O₄ is a largely inverse spinel, which in detail shows increasing randomisation with temperature of Ni and Al between the octahedral and tetrahedral cation sites of the spinel structure. We have used powder XRD to determine this cation distribution in various samples of NiAl₂O₄ quenched after annealing between 700 and 1400° C. The inversion parameter (x) can be measured with a precision of ± 0.004 (one standard deviation), and a comparison of different methods of synthesis, X-ray diffraction and refinement techniques, suggests a probable accuracy of better than 0.01. The results are supported by some preliminary single crystal refinements on flux-grown samples.Below 800° C the rate of cation ordering becomes very slow, and, despite reaching an apparently steady state, it is doubtful if our samples attained complete internal equilibrium. Above 1250° C the cation redistribution becomes so fast that the quenching method becomes unreliable. Between 800 and 1250° C inclusive, the degree of inversion changes smoothly from 0.87 at 800° C to 0.79 at 1250° C, and is accompanied by linear changes in u, the oxygen parameter, from 0.2555 to 0.2563 (±0.0002), and a₀, the lattice parameter, from 8.0462 to 8.0522 Å (±0.0002 Å).