钱家店凹陷含铀岩系姚家组高岭土化特征及高岭石氢氧同位素的流体指示意义

钱家店凹陷姚家组高岭石的形成与铀成矿存在流体上的密切联系。通过岩心观察、孔渗测试、光谱扫描及电镜扫描等方法分析了姚家组砂岩高岭土化蚀变空间特征,并对高岭石进行H-O同位素测试,以查明形成高岭石的相关流体及其特征。研究发现:①高岭土化蚀变往往与砂岩的漂白和铀矿化关系密切,灰-灰白色砂岩渗透率明显高于红-红棕色砂岩,联井剖面反映姚家组砂岩的高岭土化与漂白程度总体呈现出沿NW-SE向逐渐减弱的趋势;②姚家组高岭石发育,含铀矿段及围岩砂岩的高岭石含量占黏土矿物的65%～90%,高岭石的δ¹⁸O_V-SMOW值为-1.03‰～8.82‰,δD_V-SMOW值为-115.87‰～-105.51‰,显示高岭石与水具有明显的O同位素分馏现象。以H-O同位素反演流体温度为切入点,从流体温度、流体性质与流向以及流体控制因素的角度探讨形成高岭石的相关流体特征,得到以下认识:①δD-δ¹⁸O特征表明形成高岭石的流体温度在40～120℃,且研究区西北部的姚家组砂岩高岭石形成的流体温度明显高于其他地区;②与高岭石形成相关的流体可能...     

云南哀牢山-红河剪切带新生代富碱侵入岩中榍石年代学和地球化学特征

榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱（Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS）与激光剥蚀系统（Laser Ablation,LA）联用,对哀牢山-红河剪切带5个富碱侵入岩体（桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体）中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce^*比值,具有较低的Eu/Eu^*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5~37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期（~35Ma）一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MC-ICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8~-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。

     

东海盆地西湖凹陷天台区始新世平湖组风暴岩的发现及其地质意义

风暴岩对于古地理和古环境具有良好的指相意义。东海盆地西湖凹陷天台区始新世平湖组发育典型的风暴岩。通过详细的岩心观察,发育的风暴沉积标志主要有冲刷-充填构造、风暴撕扯构造和丘状-洼状交错层理构造等。根据风暴岩垂向上的组合特征及沉积构造差异,识别出了近源和远源两种风暴沉积类型,分别指示了不同的沉积背景：近源风暴岩表现为不完整的风暴岩垂向沉积序列,呈风暴砾屑层段（A）+泥岩段（E）叠加,为潮坪潮下带沉积;远源风暴岩具完整和不完整的风暴岩垂向沉积序列,以粒序段（B）+平行层理段（C）+丘状（洼状）层理段（D）叠加为特征,属浅海陆棚沉积。风暴层序自下而上沉积环境为浅海陆棚→潮坪,风暴岩的分布差异表明形成环境向上变浅的沉积特征。该发现为本区古环境的演变提供了重要依据。     

涟源凹陷泥盆纪佘田桥组沉积与地震相特征

涟源凹陷泥盆纪佘田桥组为台盆相间的海相沉积,盆地相为有利的页岩气富集区.目前对台盆相研究多依靠地质露头和少量测井资料,对台盆相地震相特征研究较少,从而制约着本区页岩气勘探进展.本文基于新采集的二维地震资料,从湘新地3井钻井岩心资料和测录井资料入手,通过对该井主要目的层的合成记录标定、目的层反射轴响应特征分析等工作,开展佘田桥组沉积相序划分及地震相特征分析.结果 表明:泥盆纪佘田桥组台地相地震反射特征为不连续弱振幅杂乱-亚平行结构,盆地相地震反射特征为连续强振幅平行结构,并在此基础上利用地震相特征开展佘田桥组有利相区平面预测,明确了佘田桥组盆地相分布范围,为佘田桥组页岩气勘探提供部署依据.     

蒸发岩中硫同位素的地球化学特征及其沉积学意义——以思茅盆地MZK- 3井为例

思茅盆地目前是中国唯一的含古代固体钾盐矿床的沉积盆地,其钾盐形成时代、物源特征、海侵方向等多年来一直存在争议。本文依据海相硬石膏的形成条件、存在形式、同位素分馏机理,重点分析了盆地内MZK-3井蒸发岩硫同位素的地球化学特征。结果表明:①岩盐中的硬石膏在蒸发盆地析岩盐阶段即可形成,单独成层的硬石膏是由原始沉积的石膏经历了沉积埋藏升温进而脱水而成;②岩盐中硬石膏的硫同位素值具有"双峰"特征,分别为14‰～16‰和8‰～10‰或6‰～8‰,这体现了硫酸盐的双重来源——原始海水中的硫酸盐和陆源淡水输入的硫酸盐或火山活动提供的硫源;③硬石膏层的硫同位素在区域上具有对比性,结合~(87)Sr/~(86)Sr值的特征,认为其代表了海相的沉积环境;④硬石膏层的硫同位素值平面上由南向北降低,可能反映了在此方向陆源淡水或火山活动对蒸发岩盆地的影响逐渐增强,进而说明这可能也是海侵的方向。可见对硬石膏硫同位素的研究,不仅在沉积学上能揭示物源、沉积环境、海侵方向等信息,更能对研究区钾盐矿床勘查提供有益的参考。     

矿山环境治理过程中资金运作模式探索与实践

矿山环境治理恢复基金制度之所以取代矿山地质环境治理恢复保证金制度,目的之一是通过基金的合理运营,为矿山环境治理提供长效稳定的资金保障。通过对矿山地质环境治理恢复保证金制度中的资金问题进行剖析,从基金来源、基金运营、基金投入三个方面提出矿山环境治理过程中新的商业运作模式,并从市场化角度对社会资本进入矿山复绿和综合利用进行了探索,以期对矿山环境治理恢复基金制度的建立提供一定的指导和参考。     

Environmental significance of snowpit chemistry in the typical monsoonal temperate glacier region,Baishui glacier no. 1, Mt Yulong,China

Samples were collected from two snowpits in Baishui glacier no. 1, Mt Yulong, China, in May 2006. Snowpit chemistry was studied, using ion tracer techniques, HYSPLIT model, factor analysis, correlation and trend analysis. It indicated that total cation concentration is higher in 4,900-m snowpit than in 4,750-m snowpit, whereas total anion concentration is higher in 4,750-m snowpit. Cations, especially Ca²⁺, dominate ionic concentrations in Baishui glacier no. 1. According to correlation analysis and factor analysis, ions can be categorized as follows: Cl⁻ and NO₃ ⁻ as Group 1, SO₄ ²⁻ as Group 2, Mg²⁺ and Ca²⁺ as Group 3, Na⁺ as Group 4, K⁺ as Group 5. Contribution made by terrestrial dust to ionic concentration accounts for 52.27, 100, 99.36, 98.91, 96.16 and 99.97% of Cl⁻, NO₃ ⁻, SO₄ ²⁻, K⁺, Mg²⁺ and Ca²⁺, respectively, in 4,900-m snowpit, and for 64.00, 100, 99.57, 98.63, 96.25 and 99.97% in 4,750-m snowpit. Local dust is the principal source of snowpit chemical components. Pollutants brought from industrial areas of South Asia, Southeast Asia and South China by monsoonal circulation also makes some contribution to anion concentrations, but pollution associated with human activities makes a very slight contribution in study area. The chemical characteristics of two snowpits are different owing to the difference of deposition mechanism and local environment in different altitudes.     

Decoupling of the East Asian summer monsoon and Indian summer monsoon between 20 and 17 ka

Marine Oxygen Isotope Stage (MIS) 2, with its profound environmental and climatic changes from before the last glacial maximum (LGM) to the last deglaciation, is an ideal period for understanding the evolution of the East Asian summer monsoon (EASM) and Indian summer monsoon (ISM), two Asian monsoon sub-systems. With 875 stable oxygen isotope ratios and 43 ²³⁰Th dates from stalagmites in Sanxing Cave, southwestern China, we construct and interpret a new, replicated, Asian summer monsoon (ASM) record covering 30.9–9.7 ka with decadal resolution. δ¹⁸O records from this site and other reported Chinese caves display similar long-term orbitally dominated trends and synchronous millennial-scale strong and weak monsoonal events associated with climate changes in high northern latitudes. Interestingly, Sanxing δ¹⁸O and Arabian Sea records show a weakening ISM from 22 to 17 ka, while the Hulu and Qingtian records from East and Central China express a 3-ka intensifying EASM from 20 to 17 ka. This decoupling between EASM and ISM may be due to different sensitivities of the two ASM sub-systems in response to internal feedback mechanisms associated with the complex geographical or land-ocean configurations.     

^40Ar／^39Ar Fast Neutron Activation Ages of Quartz from the Jinman Vein Copper Dposit in Western Yunnan and Their Significance

Quartz samples collected from the Jinman vein copper deposit in the Lanping Basin of western Yunnan were determined by⁴⁰Ar/³⁹Ar fast neutron activation techniques, and the spectra are characterized as being saddle-shaped. The samples yielded a plateau age of 58.05 ± 0.54 Ma, a minimum appearance age of 56.76 ±0.81 Ma and an isochron age of 54.30 ± 0.15 Ma, the three ages being close to each other, indicating that the ages of the quartz samples so far determined are true and reliable. The plateau age represents the time of formation of Cu-bearing quartz veins, which is corresponding to Early Himalayan. This age is also consistent with the time at which a tectonically thermal event (60 Ma) took place within the Lanping Basin, Yunnan Province. In consideration of the fact that copper ore and other ore types in the vast area of western Yunnan are concentrated mainly in the Early Himalayan strata, the authors believe that there must have existed some indispensable key factors leading to metallogenesis on a large scale during the Early Himalayan period in western Yunnan and also constraining in union the formation of ore deposits there.     

辽东湾北部浅海区泥沙输送及其沉积特征

根据实测资料，本文定量分析了辽东湾北部泥沙输送及其分布，并对辽河三角洲沉积区划作了初步讨论。研究表明本区泥沙以纵向搬运为特征。双台子河以西来沙和辽河西水道入海泥沙是区域东部拦门沙体和浅滩发育的主导因素。汛季大潮期，泥沙自西向东运移落淤在河口及毗邻浅水域；小潮期，泥沙除向东扩散外，大部泥沙向海方搬运。调查区可划分六个现代沉积作用区，即潮坪沉积区、辽河水下三角洲细粒沉积区、河口沙洲沉积区、波浪潮流冲蚀沉积区、河口冲积沉积区以及潮汐水道沉积区。