Glacial to Holocene terrigenous organic matter input to sediments from Orca Basin, Gulf of Mexico — A combined optical and biomarker approach

In this study we assessed changes in the contribution of terrigenous organic matter (OM) to the Gulf of Mexico over the course of the last deglaciation (the last 25 kyr). To this end, we combined optical kerogen analyses with bulk sedimentary, biomarker, and compound-specific carbon isotope analyses. Samples were obtained from core MD02-2550 from Orca Basin (2249 m water depth at 26°56.77N, 91°20.74W) with temporal resolution ranging from multi-decadal to millennial-scale, depending on the proxy. All proxies confirmed larger terrigenous input during glacial times compared to the Holocene. In addition, the kerogen analyses suggest that much of the glacial OM is reworked (at least 50% of spores and pollen grains and 40% of dinoflagellate cysts). The Holocene sediments, in contrast, contain mainly marine OM, which is exceptionally well preserved. During the deglaciation, terrigenous input was generally high due to large meltwater fluxes, whereby discrepancies between different proxies call for additional influences, such as the change in distance to the river mouth, local productivity changes, and hydrodynamic particle sorting. It is possible that kerogen particles and the terrigenous biomarkers studied here represent distinct pools of land-derived OM with inputs varying independently.     

Trace-element distribution in lavas from Anjouan and Grande Comore,western Indian Ocean

The elements Cr, Ni, Cu, Zn, Rb, Sr, Y, Zr and Ba have been determined by X-ray fluorescence for 65 basaltic and differentiated lavas from Anjouan, while Sc, V, Cr, Co, Ni, Cu, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba and Hf have been determined by spark-source mass spectrometry for selected lavas from Anjouan and Grande Comore, the most recently formed of the Comores Archipelago. Basaltic lavas studied range through nephelinite, basanite, alkali basalt and hypersthene-normative basalt, while differentiated lavas belong mainly to the trends: alkali basalt - trachyte and basanite - phonolite. The results indicate that during magmatic fractionation behaviour of large-ion elements such as Rb, Sr, Y, Zr, Ba and Nb is controlled by size/charge criteria, resulting in their exclusion from crystallising phases until the late trachytic and phonolitic stages. These elements are clearly fractionated by amphibole, plagioclase and alkali feldspar. Variation of transition elements due to crystal-liquid differentiation is largely in accord with the predictions of crystal field theory. The behaviour of Zn is not readily accounted for. Fractionation of K/Rb, K/Cs and probably Zr/Nb and discrepancies in abundance levels of large-ion elements between the main basaltic types are best accounted for in terms of high-pressure processes and probably also reflect inherent features of source-region geochemistry, coupled with the effects of variable partial melting.     

1000 years of climate variability in central Asia: assessing the evidence using Lake Baikal (Russia) diatom assemblages and the application of a diatom-inferred model of snow cover on the lake

The mainly endemic phytoplankton record of Lake Baikal has been used in this study to help interpret climate variability during the last 1000 years in central Asia. The diatom record was derived from a short core taken from the south basin and has been shown to be free from any sedimentary heterogeneities. We employ here a diatom-based inference model of snow accumulation on the frozen lake for the first time (r²_boot=0.709; RMSEP=0.120 log cm). However, palaeoenvironmental reconstructions have been improved by the use of correction factors, specifically developed for the dominant phytoplankton (Aulacoseira baicalensis, Aulacoseira skvortzowii, Cyclotella minuta, Stephanodiscus meyerii and Synedra acus) in the south basin of Lake Baikal. Cluster analysis identifies three significant zones in the core, zone 1 (c. 880 AD–c. 1180 AD), zone 2 (c. 1180–1840 AD) and zone 3 (c. 1840–1994 AD), coincident with the Medieval Warm Period (MWP), the Little Ice Age (LIA) and the period of recent warming, respectively. Our results indicate that S. acus dominated the diatom phytoplankton within zone 1 coincident with the MWP. S. acus is an opportunistic species that is able to increase its net growth when A. baicalensis does not. During this period, conditions are likely to have been unfavourable for the net increases in A. baicalensis growth due to the persistence of warm water in the lake, together with an increased length of summer stratification and delay in timing of the autumnal overturn. In zone 2, spring diatom crops blooming under the ice declined in abundances due in part to increased winter severity and snow cover on the lake. Accumulating snow on the lake is likely to have arisen from increased anticyclonic activity, resulting in prolonged winters expressed during the LIA. Thick, accumulating snow cover inhibits light penetration through the ice, thereby having negative effects on cell division rate and extent of turbulence underneath the ice. Consequently, only taxa whose net growth occurs during autumn overturn (C. minuta) predominate in the lake at this time. Diatom census data and reconstructions of snow accumulation suggest that warming in the Lake Baikal region started as early as c. 1750 AD, with a shift from taxa that bloom during autumn overturn to assemblages that begin to grow underneath the frozen lake in spring. Very recent increases and subsequent decline of S. acus in the surface sediments of the lake mirror monitoring records of this species over the last 50 years. Our study confirms that, over the last 1000 years, physical processes are important in determining planktonic diatom populations in the lake and highlights the value of integrated plankton, trap, and sediment studies for improving quantitative palaeoenvironmental reconstructions from fossil material.     

H2 Diagnostics of Magnetic Molecular Shocks in Bipolar Outflows

The shock waves associated with molecular outflows may be of continuous (C) type or jump (J) type, depending on conditions in the preshock gas, notably the magnetic field strength and the degree of ionisation. Intermediate situations also exist, in which a J-discontinuity terminates or is embedded in a C-type flow. We show that proper allowance for the departure of the chemistry from equilibrium (particularly the dissociation/reformation of H₂) and for the inertia of charged dust grains, is crucial for an accurate treatment of the C to J transition. We illustrate the use of H₂ population diagrams and H₂ line profiles, in conjunction with our detailed shock model, to constrain conditions in shocks propagating in molecular outflows. We show that H₂ pure rotational lines yield evidence for C-type precursors in bipolar outflows from young stars, with transverse magnetic field strengths B (μG) ? 1–10 × $\sqrt {n_{H/{\text{cm}}^{ - 3} } } $ similar to those inferred from Zeeman splitting and from the dispersion of dust polarization vectors in dense clouds.     

Diagnosing the conditions in molecular outflow sources: New developments in shock wave models with non-equilibrium chemistry

The shock waves associated with molecular outflows may be of continuous (C) type or jump (J) type, depending on conditions in the preshock gas, notably the degree of ionization. Intermediate situations also exist, in which a J-discontinuity terminates or is embedded in a C-type flow. We consider the results of recent modelling of several important cases where shock waves will comprise both C and J components, namely: (1) in the evolution of a planar J into a planar C type shock wave, prior to the attainment of a stationary state; (2) at shock speeds exceeding the maximum value for a planar C type shock, when the cooling flow encounters a sonic point; (3) in a curved bowshock, when the shock speed at the apex exceeds the maximum value for a C type shock while the bow wings remain of C type. We show that proper allowance for the departure of the chemistry from equilibrium, particularly the dissociation/reformation of H₂, is crucial for an accurate treatment of the C to J transition. All the possible modes of shock propagation need to be considered when interpreting observations of molecular outflow sources. An important diagnostic tool in this context is the H₂ excitation diagram, which plots the logarithm of the column densities of the H₂ rotational levels, divided by the statistical weights, against their excitation energies. There can be large differences between the dynamical and physical conditions implied by J type shocks (with and without a precursor), C type shocks, and bowshocks which best fit the observed excitation diagram. We discuss, by means of examples, the use of the excitation diagram, in conjunction with our sophisticated shock model, to constrain conditions in shocks propagating in molecular outflows.     

Temporal evolution of MHD shocks in the interstellar medium

We undertake calculations of the time-dependent structure of shock waves propagating in dark and diffuse interstellar clouds. The results of the time-dependent model are compared with those obtained by means of an independent steady-state code and found to agree well at sufficiently late times. Discontinuities in the flow of the neutral fluid are handled by introducing a pseudo-viscosity. Special procedures are adopted to correct for the associated widening of the discontinuity, in order not to distort the role of inelastic collision processes. We find that, in dark clouds, C shocks will tend to predominate, but are unlikely to have attained steady state in the cloud lifetime. On the other hand, in diffuse clouds, steady state may be reached but the discontinuity in the flow of the neutral fluid remains. We find no evidence for the existence of C* shocks, in which the neutral fluid undergoes a continuous transition from supersonic to subsonic flow (in the reference frame of the shock wave). Attention is drawn to the possible importance of these results for the interpretation of H₂ rovibrational line intensities.     

Emission and cooling by CO in interstellar shock waves

We have calculated emission by CO molecules from interstellar shock waves. Two approximations have been used to determine the population densities,   n_J   , of the rotational levels, J : steady state  (∂/∂ t ≡ 0)  and statistical equilibrium  (d/d t ≡ 0)  . A large-velocity-gradient approximation to the line-transfer problem was adopted in both cases. We find that there can be substantial differences between the values of the integrated rotational line intensities calculated in steady state and in the limit of statistical equilibrium. On the other hand, although CO can be the dominant coolant towards the rear of the cooling flow which follows the dynamical heating of the gas, the rate of cooling computed assuming statistical equilibrium is likely to be reasonably accurate, given that the limit of statistical equilibrium is approached in this region.     

The rotational excitation of H2 by H2

We present rate coefficients for rotational transitions induced in collisions between H₂ molecules. Rotational levels J  ≤ 8 and kinetic temperatures T  ≤ 1000 K are considered. The interaction potential computed by Schwenke has been used, together with the quantal coupled channels method of calculating the cross-sections. Comparison is made with the more recent of previous results.