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Adsorption of Heavy Metal Ions, Dyes and Proteins by Chitosan Composites and Derivatives- A Review

Chitosan composites and derivatives have gained wide attentions as effective biosorbents due to their low costs and high contents of amino and hydroxyl functional groups. They have showed significant potentials of removing metal ions, dyes and pro- teins from various media. Chemical modifications that lead to the formation of the chitosan derivatives and chitosan composites have been extensively studied and widely reported in literatures. The aims of this review were to summarize the important information of the bioactivities of chitosan, highlight the various preparation methods of chitosan-based active biosorbents, and outline its potential applications in the adsorption of heavy metal ions, dyes and proteins from wastewater and aqueous solutions.     

莱芜市破解用地瓶颈措施解析

当前,国家收紧地根,从严控制新增建设用地指标成为各地建设项目顺利落地的制约瓶颈。为破解这一难题,结合莱芜实际,分析了规划修编、指标利用、挖潜存量、加快供地等做法,对保障项目用地提出了建议和对策。     

扬子板块西缘攀西地区白草矿区黄铁矿标型元素特征及其指示意义

黄铁矿是重要的金属硫化物矿物,在多种矿床中均有产出,其标型特征对矿床成因、矿体空间分布等具有重要的指示意义.以扬子板块西缘攀西地区白草矿区黄铁矿为研究对象,利用矿相学、电子探针等分析方法来对比研究浸染状、致密块状、斑杂状、网脉状矿石中黄铁矿的标型元素特征.结果表明:白草矿区黄铁矿Fe、S平均含量(质量分数,下同)分别为...     

Effect of Penetration Rates on the Piezocone Penetration Test in the Yellow River Delta Silt

Partial drainage often occurs during piezocone penetration testing on Yellow River Delta silt because of its intermediate physical and mechanical properties between those of sand and clay.Yet,there is no accurate understanding for the range of penetra-tion rates to trigger the partial drainage of silt soils.In order to fully investigate cone penetration rate effects under partial drainage condi-tions,indoor 1 g penetration model tests and numerical simulations of cavity expansion at variable penetration rates were carried out on the Yellow River Delta silt.The boundary effect of the model tests and the variation of key parameters at the different cavity ex-pansion rates were analyzed.The 1 g penetration model test results and numerical simulations results consistently indicated that the penetration rate to trigger the partially drainage of typical silt varied at least three orders of magnitude.The numerical simulations also provide the reference values for the penetration resistance corresponding to zero dilation and zero viscosity at any given normalized penetration rate for silt in Yellow River Delta.These geotechnical properties can be used for the design of offshore platforms in Yel-low River Delta,and the understanding of cone penetration rate effects under the partially drained conditions would provide some technical support for geohazard evaluation of offshore platforms.     

Geochemical Evidence for Coal and Carbonaceous Mudstone as the Possible Major Oil Source Rock in the Jurassic Turpan Basin,Northwest China

Petroleum geologists have debated whether the hydrocarbons from Jurassic coal measures are derived from the coals, carbonaceous mudstones or coal-measure mudstones in the Turpan Basin. Based on the geochemistry analysis of the 20 crude oils and 40 source rocks from the Turpan Basin, some data have been obtained as follows: carbon preference index and methylphenanthrene index of the Jurassic oils are 1.16–1.45 and 0.28–0.80, and the ααα C29 sterane 20S/(20S+20R) and C29 sterane ββ/(ββ+αα) are 0.44–0.51 and 0.4–0.54 respectively, which show the normal maturity of oils; the vitrinite reflectance of the source rocks from the Xishanyao to Badaowan Formations range from 0.47% to 0.97%, which indicate immature to mature thermal evolutionary stage and sufficient conditions for generating mass mature oil. The effect of hydrocarbon expulsion should be considered when studying the source of coal-derived oil by using Biomarkers. Biomarkers in the Jurassic oils from the basin are similar to those in the coals and carbonaceous mudstones, with a strong predominant content of pristane, relatively high ratio of C15/C16 sesquiterpenoids (>1), a relatively high content of low carbon number tricyclic terpanes and C24 tetracyclic terpane, little gammacerane and C29 Ts detected, an absolute predominant content of C29 sterane and a relatively high content of diasterane. However, the opposite characteristics are shown in mudstones, with an approximately equal content of pristane and phytane, relatively low ratio of C15/C16 sesquiterpenoids (<1), a relatively high content of high carbon number tricyclic terpanes and a low content of C24 tetracyclic terpane, peaks of gammacerane and C29 Ts detected obviously and an increasing C27 sterane content. All of these characteristics identify the coals and carbonaceous mudstones as the possible major oil source rocks in this area, and they were formed in the stronger oxidizing environment with shallower water than mudstones.     

GPS天线相位中心校正对GRACE卫星精密定轨的影响

使用GRACE卫星星载GPS观测数据,研究地面获取的先验PCV模型和利用残差法估计的在轨PCV模型对低轨卫星精密定轨的影响,并采用GFZ精密轨道对比和SLR检核手段对其进行评估。结果表明,使用先验PCV模型会降低GRACE卫星定轨精度,相反利用在轨PCV模型可以提高定轨精度,提升数量级可达mm级。     

辽河西部凹陷南段油气运移史研究与有利聚集区预测

通过流体包裹体均一温度测试、含油气包裹体指数GOI统计和盆地模拟,研究了渤海湾盆地辽河西部凹陷南段的油气运移史,预测了油气聚集的有利地区.包裹体均一温度资料表明,本区有三期成藏:东二期、东一期和明化镇期;以前两期为主.盆地模拟研究表明,尽管沙河街组烃源岩在沙一期末开始生烃,但在东营期才开始大规模排烃和成藏.GOI的统计分析表明,GOI>5%的区域为油气聚集的有利地区,其中的圈闭应成为下步首选的钻探目标,已发现的欢喜岭油田和双南油田就分布在GOI>5%的区域内.     

缺损桩的导纳谱判别法及应用

利用振动工程中的模态分析技术,对桩基系统的振动特性进行研究。根据桩基系统的集中质量参数振动模型,对完整桩和各种缺损桩模型的导纳谱进行了大量的正演计算,按照导纳谱特征与桩基的缺损类型及缺损位置之间的对应关系,编制了相应的判读软件DSP1.0系统,实现了桩基完整性以及缺损桩缺损位置和缺损性质的计算机自动判读。