Geochemistry evidence for depositional settings and provenance of Jurassic argillaceous rocks of Jiyuan Basin,North China

This paper aims to discuss the depositional settings and provenances for the Jurassic in Jiyuan basin, North China, based on the rare earth element (REE) and trace element features of 16 Jurassic argillaceous rock samples from the Anyao, Yangshuzhuang and Ma’ao Formations, respectively. Generally, geochemical analysis results show that chondrite-normalised REE distribution patterns of all the three formations are characterised by light-REE (LREE) enrichment, moderately negative Eu anomalies, slightly negative Ce anomalies, and strong fractionation between LREE and heavy-REE (HREE). Trace element proxies V/(V + Ni), Ce _anom index, Ce/La, Sr/Ba, and Sr/Cu indicate a weak oxidation–reduction environment, progressively decreasing reducibility and water depth from the bottom up during Jurassic in Jiyuan basin. Palaeoclimate varied from humid in the Early Jurassic to arid in the Middle Jurassic, corresponding with the variations of palaeoredox and palaeosalinity. The provenances of Jurassic rocks in Jiyuan basin are mainly from felsic sources related to active continental margin and continental island arc. The Early–Middle Jurassic (Anyao and Yangshuzhuang Formations) provenances are mainly derived from North Qinling and partially from the eroded recycled felsic sedimentary covers of Taihang Mountain. In the late stage of Middle Jurassic (Ma’ao Formation), Taihang Mountain has been the primary source to Jiyuan basin. We conclude that the Jurassic rocks of Jiyuan basin reveal the progressive uplift and denudation processes of the Taihang Mountain.     

吉尔吉斯斯坦塔尔迪布拉克斑岩型金铜矿床地球化学特征及其意义

塔尔迪布拉克斑岩型金铜矿床位于吉尔吉斯西北部的Kipchak奥陶纪岛弧带,是吉尔吉斯斯坦重要的斑岩型金铜矿床之一。本文在前人研究基础上,对该矿床的地质、地球化学特征进行系统研究。研究结果显示,该矿床斑岩体具有高的SiO_2、Al_2O_3、碱质含量,低的Na_2O、CaO、P_2O_5、Th、Y含量和低Al_2O_3/TiO_2比值,属于典型的钙碱性强过铝质S型花岗岩,是高温条件下发生深熔作用的产物。该矿床轻、重稀土元素分馏明显,相对富集LREE和LILE元素,亏损HFSE元素,其源岩可能为杂砂岩,主要来源于地壳物质。此外,稀土、微量元素特征及其区域构造演化特征均显示,该矿床可能是捷尔斯克伊洋演化末期成熟岛弧环境下岩浆-热液活动的产物。     

大兴安岭北段富林矽卡岩铜矿床成因:印支期含矿岩浆源区特征、蚀变矿物学及勘查意义

新近发现的印支期富林矽卡岩铜矿床位于大兴安岭北段新林区新林镇东约90km。矿区发育与成矿直接相关的花岗岩和侵入花岗岩中的花岗斑岩,矿体主要赋存于花岗岩与古元古代兴安桥组大理岩和早奥陶世黄斑脊山组钙质粉砂岩接触带内。富林矿床矿化与矽卡岩密切相关,整个矿化过程可分为两期:矽卡岩期和石英-硫化物期,5个阶段:早期矽卡岩阶段、退化蚀变阶段、氧化物阶段、早期硫化物阶段和晚期硫化物阶段,其中铜矿化主要发生在早期硫化物阶段。硫化物主要包括黄铜矿和黄铁矿,并含少量闪锌矿、方铅矿、斑铜矿等。蚀变类型包括石榴子石-透辉石矽卡岩化、阳起石-透闪石矽卡岩化、绿帘石矽卡岩化、绿泥石化、绢云母-粘土化、钾长石化和局部角岩化。电子探针分析(EMPA)结果表明:矿区内的石榴子石属钙铝-钙铁榴石系列,主要为钙铁榴石,辉石为透辉石-钙铁辉石系列,以透辉石为主,闪石主要为透闪石、阳起石以及少量镁绿钙闪石和铁浅闪石,帘石为黝帘石-绿帘石系列。黑云母以镁铁黑云母和铁叶云母为主,绿泥石主要为密绿泥石和铁叶绿泥石,长石以正长石和钠长石为主。石榴子石成分剖面显示从核部到边部,石榴子石呈现出钙铝榴石和钙铁榴石交替变化的环带特征,且Fe~(3+)含量的逐渐升高暗示后期成矿流体氧逸度升高,结合黑云母Mg-Fe~(3+)-Fe~(2+)图解,说明富林矽卡岩型铜矿床形成于较强的氧化环境。锆石LA-ICP-MS U-Pb测年结果显示花岗岩形成于~253Ma,花岗斑岩形成于~244Ma,为大兴安岭地区一期新的成矿事件。锆石原位Hf同位素测试结果表明,花岗岩εHf(t)介于-1.60~2.23,花岗斑岩εHf(t)介于-3.53~1.90,二者均具有古老的两阶段模式年龄,结合前人对区域构造背景的研究,认为富林花岗质岩石可能来自于松辽地块和兴安地块后碰撞背景下俯冲板片断离软溜圈上涌导致古老下地壳的部分熔融并卷入少量地幔物质而形成的岩浆。花岗斑岩及与斑岩有关的脉状矿化和蚀变的出现暗示富林地区可能存在印支期的斑岩型矿床,此外结合石榴子石、辉石成分特征以及辉石Mn/Fe比值与世界矽卡岩矿床对比,指出富林矿区外围找矿应综合考虑铜、钼、铁、金、铅、锌等矿化组合。     

下扬子皖南地区上二叠统(泾页1井)发现海陆过渡相页岩气

<正>1研究目的(Objective)中国下扬子地区上二叠统广泛发育大隆组—龙潭组暗色页岩,但勘查程度较低,一直未获页岩气调查突破。通过前期综合研究,在下扬子皖南坳陷孤峰向斜西翼部署实施了泾页1井,在上二叠统见良好页岩气显示。开展了系统分析测试工作,评价了区域页岩气资源潜力,分析了页岩气成藏条件与富集规律,为页岩气资源评价和进一步调查部署提供了依据。     

鄂西巴东地区(巴页1井)发现海陆过渡相页岩气

<正>1研究目的(Objective)根据富有机质页岩沉积环境可将页岩气分为海相、陆相和海陆过渡相(含煤岩系)3大类型。近年,中国已在海相页岩和陆相页岩地层页岩气勘探中取得重大突破,而海陆过渡相的页岩气勘探工作尚处于起步阶段,整体研究程度较低。鄂西巴东地区地处四川盆地东缘,该区广泛发育上二叠统龙潭组暗色泥页岩,厚度大,有机碳含量高,埋深适中,是实现海陆过渡相页岩气勘探发现的有利远景区。为此,在野外地质调查的基础上,优选实施钻     

基于动三轴试验的层间错动带动孔压特性及能量分析

2008年汶川地震触发的大光包滑坡滑带形成背景是渗水层间错动带,该带强度变化是决定滑坡启动的主要因素,动孔压发展是土体材料强度劣化的根本原因,故基于系列室内动三轴试验研究该带材料孔压特性。结果表明,动载下层间错动带材料孔压快速增长,循环剪应力比越大,孔压增长越快,不同荷载条件下应变达到5%时动孔压比等于1,材料液化,根据动孔压比与振次比曲线的拟合关系提出幂函数应力模型。从能量角度描述层间错动带材料孔压增长特性,揭示出循环剪应力比对累积能量耗损与动孔压比曲线影响较小而围压对其影响较大,并进一步提出孔压增长的能量模型。     

Effects of Deep Fluids on Hydrocarbon Generation and Accumulation in Chinese Petroliferous Basins

Deep fluids in a petroliferous basin generally come from the deep crust or mantle beneath the basin basement, and they transport deep substances(gases and aqueous solutions) as well as heat to sedimentary strata through deep faults. These deep fluids not only lead to large-scale accumulations of CO_2, CH_4, H_2, He and other gases, but also significantly impact hydrocarbon generation and accumulation through organic-inorganic interactions. With the development of deep faults and magmatic-volcanic activities in different periods, most Chinese petroliferous basins have experienced strong impacts associated with deep fluid activity. In the Songliao, Bohai Bay, Northern Jiangsu, Sanshui, Yinggehai and Pearl Mouth Basins in China, a series of CO_2 reservoirs have been discovered. The CO_2 content is up to 99%, with δ~(13)C_(CO2) values ranging from-4.1‰ to-0.37‰ and ~3He/~4He ratios of up to 5.5 Ra. The abiogenic hydrocarbon gas reservoirs with commercial reserves, such as the Changde, Wanjinta, Zhaozhou, and Chaoyanggou reservoirs, are mainly distributed in the Xujiaweizi faulted depression of the Songliao Basin. The δ~(13)CCH4 values of the abiogenic alkane gases are generally -30‰ and exhibit an inverse carbon isotope sequence of δ~(13)C_(CH4)δ~(13)C_(C2H6)δ~(13)C_(C3H8)δ~(13)C_(C4H10). According to laboratory experiments, introducing external H_2 can improve the rate of hydrocarbon generation by up to 147% through the kerogen hydrogenation process. During the migration from deep to shallow depth, CO_2 can significantly alter reservoir rocks. In clastic reservoirs, feldspar is easily altered by CO_2-rich fluids, leading to the formation of dawsonite, a typical mineral in high CO_2 partial pressure environments, as well as the creation of secondary porosity. In carbonate reservoirs, CO_2-rich fluids predominately cause dissolution or precipitation of carbonate minerals. The minerals, e.g., calcite and dolomite, show some typical features, such as higher homogenization temperatures than the burial temperature, relatively high concentrations of Fe and Mn, positive Eu anomalies, depletion of 18 O and enrichment of radiogenic ~(87)Sr. Due to CO_2-rich fluids, the development of high-quality carbonate reservoirs is extended to deep strata. For example, the Well TS1 in the northern Tarim Basin revealed a high-quality Cambrian dolomite reservoir with a porosity of 9.1% at 8408 m, and the Well ZS1 C in the central Tarim Basin revealed a large petroleum reserve in a Cambrian dolomite reservoir at ~6900 m. During the upward migration from deep to shallow basin strata, large volumes of supercritical CO_2 may extract petroleum components from hydrocarbon source rocks or deep reservoirs and facilitate their migration to shallow reservoirs, where the petroleum accumulates with the CO_2. Many reservoirs containing both supercritical CO_2 and petroleum have been discovered in the Songliao, Bohaiwan, Northern Jiangsu, Pearl River Mouth and Yinggehai Basins. The components of the petroleum trapped with CO_2 are dominated by low molecular weight saturated hydrocarbons.     

Sedimentary Conditions of Evaporites in the Late Jurassic Xiali Formation, Qiangtang Basin: Evidence from Geochemistry Records

The Qiangtang Basin (QB), located in the central Tibetan Plateau, is a Jurassic marine basin and one of the most important prospective salt resource belts in China. In recent decades, many outcrops of gypsiferous?bed have been found in the Jurassic marine strata in the basin. Salt springs with abnormally high sodium (Na+) contents had been identified in the Late Jurassic Xiali Formation (Fm.) in the basin in the last years. However, to date, no potash or halite deposits have been identified in the QB. Gypsum outcrops and salt springs are very important?signs in the investigation of halite and potash deposits. Therefore, the Xiali Fm. is?a potentially valuable layer to evaluate for the possible presence of halite and potash deposits in the basin. However,?few studies?have explored the formation?conditions of evaporites in the unit. Here, we present detailed geochemical records from the Yanshiping section related to the study of the formation?conditions of evaporites in the Xiali Fm. of the QB. Climate proxies based on the obviously increased anion concentrations of SO42? and Cl? and the significant correlation?coefficients of Ca2+-SO42? (R = 0.985) and Na+-Cl? (R = 0.8974) reveal that the upper member of the Xiali Fm. (the upper Xiali Fm.) formed under an arid climate and evolved into the sulfate phase or early chloride phase. Provenance proxies based on the obviously increased K+ and Na+ ion concentrations and the significant correlation?coefficient of Na+-Cl? (R = 0.8974) suggest that the upper Xiali Fm. featured optimal provenance conditions for the possible formation of halite deposits. The regression and the semi-closed tidal?flat environment in the upper Xiali Fm. were favorable for the formation of potash and halite deposits. The low Mg2+ /Ca2+ values (mean value = 1.82) and significant Na+-Cl? correlation?coefficient (R = 0.8974) also suggest that the upper Xiali Fm. is the layer most likely to contain potential halite deposits. In addition, the macroscopic correlations of tectonism, provenance, paleoclimate, saliferous strata and sedimentary?environment between the QB and the adjoining Amu Darya Basin in Central Asia reveal that the two basins shared similar geologic settings that were favorable for the formation of evaporites during the Late Jurassic. Therefore, the upper Xiali Fm. is a valuable layer to explore for halite deposit and may be potentially valuable in the future exploration for potash deposits in the QB.     

A Discovery of ~3.1 Ga Basement in the Bohai Bay Basin

<正>Objective The North China Craton(NCC)is one of the oldest continental fragments,which underwent multistage crust growth during the early Precambrian from3.8 Ga to 1.8Ga.In previous studies,many zircon ages have been obtained from the exposed basement rocks.However,we know little about the hidden basement because of Phanerozoic to Cenozoic strata coverage.The drill holes provided a rare opportunity to obtain the basement rocks beneath the Bohai Bay Basin(BBB).In this study,we     

大兴安岭北段霍洛台铜铅锌矿区花岗闪长岩的岩石成因:地球化学和锆石U-Pb年代学制约

黑龙江省大兴安岭地区霍洛台花岗闪长岩的锆石LA-ICP-MS U-Pb年代学表明,霍洛台花岗闪长岩(145 Ma)为早白垩世岩浆侵入产物。元素地球化学组成表明,为一套具埃达克岩特征的高钾钙碱性系列岩石,表现为高SiO_2(65.64%~66.00%)、高K_2O(3.67%~3.77%)、低MgO(0.09%~1.21%)、高Sr含量(814.00×10~(-6)~893.00×10~(-6)),低Yb(0.194×10~(-6)~0.536×10~(-6))和Y(6.38×10~(-6)~7.73×10~(-6)),A/CNK为0.94~0.958,轻重稀土元素分异明显。La/Yb(92.54~245.88)、Th/La(0.17~0.2)、Th/U(4.01~4.84)和Mg~#值(26.70~29.22)等特征显示霍洛台花岗闪长岩为加厚下地壳部分熔融形成。结合区域构造演化背景,认为霍洛台花岗闪长岩为受蒙古—鄂霍茨克构造体系影响下地壳加厚挤压-伸展转换阶段作用产物。