松花江上游地区汞污染的化学生态效应

采样分析了吉林省东部松花江上游金矿开采区及其附近水、土壤、动植物及河流沉积物样品中汞的含量，发现河流沉积物中汞的污染相当严重；受其影响当地的植物和两栖类动物——中国林蛙体内总汞和甲基汞含量也明显高于对照组。实验表明，林蛙内脏对汞的富集能力大于肌肉；秋季对汞的富集大于春季；河流沉积物中甲基汞的含量与林蛙体内甲基汞的含量有较好的正相关。汞污染的来源与区域内个体金矿的滥采滥排有直接关系，表明人类活动所产生的有毒重金属在地表过程中出现了化学生态效应。     

重要性权值的驾车导航POI表达规则

在导航电子地图中,针对驾车任务的POI自适应表达是提高导航电子地图信息传输效率的关键。针对这一问题,提出了基于重要性权值的驾车导航POI表达规则。首先,分析了POI重要性权值的影响因素;其次,从影响因素出发,研究了基于权值的POI规则表达的各规则项;最后,设计了POI自适应表达规则库,并在嵌入了数据处理规则库的绘图软件上进行了技术实现。试验结果表明,利用基于权值的POI表达规则进行地图表达,可以提高地图内容的层次性与清晰性,优化驾车导航服务。     

Satellite evidence for no change in terrestrial latent heat flux in the Three-River Headwaters region of China over the past three decades

Terrestrial latent heat flux (LE) in the Three-River Headwaters region (TRHR) of China plays an essential role in quantifying the amount of water evaporation and carbon sink over the high altitude Tibetan Plateau (TP). Global warming is expected to accelerate terrestrial hydrological cycle and to increase evaporation. However, direct field observations are lacking in this region and the long-term variability in LE remains uncertain. In this study, we have revised a semi-empirical Penman LE algorithm based on ground eddy covariance (EC) observations from an alpine grass site and provided new satellite-based evidence to assess LE change in the TRHR during 1982–2010. Our results show that the average annual terrestrial LE in the TRHR is about 38.8 W/m ² and there is no statistically significant change in annual LE from 1982 to 2010. We also found that during the same time period, terrestrial LE over the east region of the TRHR significantly decreased, on average, by 0.7 W/m ² per decade, which was driven primarily by the surface incident solar radiation (R_s) limitation, offsetting the increased LE over the west region of the TRHR caused by the increased precipitation (P) and soil moisture (SM).     

无内标-多外标校正激光剥蚀等离子体质谱法测定磁铁矿微量元素组成

激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)常用于磁铁矿原位微量元素分析,按照校正策略不同,主要分为内标法和无内标法。内标法需要用电子探针(EMPA)预先测定磁铁矿中内标元素Fe的含量,过程较繁琐,且待测元素含量会受到内标元素含量测定的影响。本文采用铁含量较高的玄武质玻璃BCR-2G、BIR-1G、BHVO-2G和GSE-1G作为外标,避免了内标元素含量的测定,建立了无内标-多外标校正LA-ICP-MS测定磁铁矿微量元素组成的分析方法。利用该方法测定了科马提岩玻璃GOR-128g和自然岩浆磁铁矿BC 28的微量元素组成以评估方法的可靠性。结果表明,科马提岩玻璃的测定结果与推荐值及前人内标法的测定值一致,多数元素的相对标准偏差RSD5%;自然岩浆磁铁矿的测定结果与推荐值相比,多数元素的RSD7%,低于前人内标法的RSD(15%)。由此说明无内标-多外标法可以实现富铁硅酸岩或磁铁矿微量元素含量的准确校正,克服了基体效应的影响。因此,无内标-多外标法是一种原位测定磁铁矿微量元素含量的快速、准确方法,具有一定的应用潜力。     

Biogenic volatile compound emissions from a temperate forest,China: model simulation

Emissions of biogenic volatile organic compounds (BVOC) were measured using a relaxed eddy accumulation (REA) technique on an above-canopy tower in a temperate forest (Changbai Mountain, Jilin province, China) during the 2010 and 2011 summer seasons. Solar global radiation and photosynthetically active radiation (PAR) were also measured. Based on PAR energy dynamic balance, an empirical BVOC emission and PAR transfer model was developed that includes the processes of BVOC emissions and PAR transfer above the canopy level, including PAR absorption and consumption, and scattering by gases, liquids, and particles (GLPs). Simulated emissions of isoprene and monoterpenes were in agreement with observations. The averages of the relative estimator biases for the flux were 39.3 % for isoprene, and 27.1 % for monoterpenes in the 2010 and 2011 growing seasons, with NMSE (normalized mean square error) values of 0.133 and 0.101, respectively. The observed and simulated mean diurnal variations of isoprene and monoterpenes in the 2010 and 2011 growing seasons were evaluated for the validation of the empirical model. Under observed atmospheric conditions, the sensitivity analysis showed that emissions of isoprene and monoterpenes were more sensitive to changes in PAR than to water vapor content or to the magnitude of the scattering factor. The emissions of isoprene and monoterpenes in the 2010 and 2011 growing seasons (from June to September) were estimated using this empirical model along with hourly observational data, with mean hourly emissions of 1.71 and 1.55 mg m^?2 h^?1 for isoprene, and 0.48 and 0.47 mg m^?2 h^?1 for monoterpenes in 2010 and 2011, respectively. As formaldehyde (HCHO) is considered as the main oxidation product of isoprene and monoterpenes, it is necessary to investigate the link between HCHO and BVOC emissions. GOME-2 HCHO vertical column densities (VCDs) can be used to estimate BVOC emission fluxes in the Changbai Mountain temperate forest.     

TRMM星载测雨雷达和地基雷达反射率因子数据的三维融合

TRMM卫星上的测雨雷达(TRMMPR)探测资料分布均匀且具有很高的垂直分辨率,但灵敏度较低;地基雷达(GR)水平分辨率较高且具有较高的灵敏度,但其垂直分辨率低。通过将TRMM PR与GR反射率因子数据的三维数据融合,得到了更优的反射率因子图像。测雨雷达与地基雷达三维数据融合主要分为以下几步:测雨雷达与地基雷达数据预处理——如去杂波、衰减校正;测雨雷达与地基雷达时空匹配;选取和应用合适的三维图像融合算法;对融合后的图像进行效果评估。试验结果表明:融合后的图像不仅增大了信息量,更好地检测弱降水,还提高了空间三维(3D)分辨率,能更好地反映降水区域细节,且使得数据总体上具有更高的完整性和可靠性。此外,还将基于雷达资料估测的降水数据与地面雨量计数据进行对比,估计反射率因子数据融合在降水测量上的有效性。      

南京雷达数据的一致性分析和订正

运用几何匹配法处理了南京雷达和热带测雨卫星(Tropical Rainfall Measuring Mission,TRMM)上搭载的测雨雷达(Precipitation Radar,PR)的反射率因子探测资料,统计分析了2008—2013年共245个时次的匹配数据。 以TRMM PR工作多年持续稳定特征为参照,揭示了南京雷达6 a的探测资料情况。结果表明,南京雷达和TRMM PR探测降水具有较强的一致性,6 a时间里南京雷达存在一定的运行不稳定情况,南京雷达0℃层以下数据存在“3段特征”:时段Ⅰ2008年1月—2010年3月,时段Ⅱ2010年3月—2013年5月,时段Ⅲ2013年5—10月。3个时段之间整体回波强度有差异,时段Ⅱ整体回波强度比时段Ⅰ、Ⅲ偏小2—3 dB;而3个时段内的回波整体保持相对的稳定,南京雷达与TRMM PR的回波强度差值随回波强度的变化呈线性关系;在中低回波值时TRMM PR比南京雷达大,在中高回波值时南京雷达比TRMM PR大。基于两种雷达回波强度值的拟合关系,对南京雷达的反射率因子进行分段线性订正,有效地改善了南京雷达的一致性:3个时段回波强度的整体差异减小到0.75 dB以内;在245个匹配时次和105894个匹配点上南京雷达和TRMM PR的反射率因子的相关系数增大,南京雷达-TRMM PR值的标准差减小。