郯庐断裂带南段张八岭群地层时代的重新厘定

扬子板块东北缘的浅变质岩被认为是三叠纪大陆俯冲过程中从扬子板块剥离而来的,其原岩主要为新元古代中期岩浆岩和沉积岩,是理解扬子板块东北缘新元古代构造演化的重要对象。郯庐断裂带张八岭隆起北段夹持于大别造山带和苏鲁造山带之间,出露一套绿片岩相—低角闪岩变火山—沉积序列,即由西冷组变火山岩和北将军组变碎屑岩组成的张八岭群。然而,西冷组与北将军组之间的关系和张八岭群的形成时代都尚存在争议。为此,本文对张八岭群开展了详细的野外地质调查和MC-LA-ICP-MS锆石U-Pb定年工作。锆石U-Pb定年结果显示,西冷组顶部石英角斑岩的原岩时代为723±7 Ma;北将军组底部变粉砂岩的碎屑锆石年龄变化于916～614 Ma之间,与西冷组、肥东杂岩内新元古代岩浆活动时间相一致,暗示它们的物质主要由西冷组和肥东杂岩提供,其中,最年轻碎屑锆石谐和年龄（677±12 Ma）限定了北将军组沉积时代下限。结合野外地质特征和前人张八岭群上覆震旦系盖层沉积初始时间（635 Ma）,本文认为北将军组的沉积时限为677～635 Ma,是覆盖于西冷组之上的中新元古代晚期沉积地层。对比研究显示,张八岭群可能是扬子东北缘新元古代中期裂谷火山—沉积岩系的重要组成部分。     

高地温对隧道岩爆发生的影响性研究

新建拉林铁路桑珠岭隧道高地应力、高地温隧道开挖过程中岩爆灾害突出。考虑开挖卸荷与温降共同耦合作用,对隧道开挖过程中不同温度时洞周应力释放过程进行数值模拟,同时对隧道开挖后的二次应力进行现场实测,就高地温对隧道洞周应力的影响进行了比较分析,最后就不同岩爆判据下高地温对岩爆发生的影响性进行了讨论。研究结果表明,采用应力释放率和温降指标反映开挖卸荷与温降共同耦合作用能合理描述高地应力高地温段开挖过程中的应力特征和岩爆发生规律。当温降超过55 ℃,应力释放率大于40%以后, 及 量值随应力释放率增大而线性增长,当应力释放率达到100%时达到最大,不同位置洞周应力拱脚处增长最快,拱顶次之,其他位置较低。在开挖中受高地温影响岩爆发生时间提前,岩爆发生等级亦不断增加。     

压重顶进框构下穿高铁引起桥墩变形及控制技术

以某高速公路下穿京沪高铁工程为例,提出一种基于"卸载-加载平衡"理念的压重顶进框构方案,并对高铁桥墩变形及控制技术进行研究。结果表明,高速公路在高铁桥下开挖10 m深,开挖体量近10万方。采用压重顶进框构方案,施工中边顶进、边监测、边通过框顶堆土、桥下堆土、框内留土等措施加载压重,可有效控制高铁的隆起变形。在通车运营3个月后,高铁相邻桥墩累计最大差异沉降为2.7mm,距离规范限值留有46%的余量,满足规范要求。轨检表明,无砟轨道平顺性满足运营要求。对比分析表明,数值模型中粉质黏土压缩模量可采用P0~P0+100 kPa(P0为土体自重应力)应力区间对应的模量值,卸载模量可取为压缩模量的3~5倍。     

Rock Mass Characteristics in Beishan, A Preselected Area for China’s High-Level Radioactive Waste Disposal

Geological and hydrological characteristics, joint geometric features, rock physical and mechanical properties and rock mass quality are studied in the Beishan area, preselected for China’s high-level radioactive waste (HLW) disposal engineering. A comprehensive survey method is developed to study joint geometric features in the outcrop and samples from borehole BS06 into the Xinchang rock mass were tested. The optimal joint sets are determined by rose diagrams and equal-area lower hemisphere plots of joint poles. Results show that: 1) the distribution of joint occurrence obeys a normal distribution, while the distribution of joint spacing obeys a negative exponential distribution; 2) concentric circular and tangent circular sampling windows are applied to study the trace length and the trace midpoint density. Results indicate that tangent circular sampling window is more stable and reasonable; 3) Beishan granite shows high density, low porosity and high strength based on many laboratory tests and the physical properties and mechanical properties are closely related; and 4) a synthesis index, Joint Structure Rating (JSR), is applied to evaluate the quality of rock mass. Through the research results of rock mass characteristics, the Xinchang rock mass in the Beishan preselected area has the favorable conditions for China’s HLW disposal repository site.     

High-Nb hawaiite–mugearite and high-Mg calc-alkaline lavas from northeastern Iran: Oligo-Miocene melts from modified mantle wedge

Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km²) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock ⁴⁰Ar/³⁹Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts.     

胶东黄铁矿显微构造变形与金富集关系：黄铁矿EBSD组构和地球化学约束

载金黄铁矿显微构造变形与金富集关系可以从显微-超显微尺度揭示金成矿作用和地质过程,探讨金的再活化或再聚集作用。在胶东焦家金矿带成矿期识别出4种类型的黄铁矿,文章应用光学显微镜、扫描电镜(SEM)、透射电镜(TEM)、电子背散射衍射(EBSD)和电子探针(EMPA)等技术方法,探讨黄铁矿显微构造特征、超微观结构与金的富集关系。结果显示:载金黄铁矿均不发育环带,其中w(Fe)为45.70%～46.85%,w(S)为52.57%～53.37%;显微构造变形既有脆性变形又有塑性变形;黄铁矿晶体优选方位(CPO)主要表现为平行于晶轴极密和复杂极密;黄铁矿晶格间距为0.58 nm,主要发育刃位错。焦家金矿带在金成矿作用过程中,可见金集合体经历了从复杂的纳米尺度到宏观尺度矿物载体富集的过程,包括成矿流体中金络合物、金-铋-硫族化合物富集等化学结构变化过程和纳米金、载金黄铁矿纳米颗粒、岩矿石显微-超显微构造微环境变化过程。因此,不同类型载金黄铁矿CPO受到化学结构变化和显微-超显微变形微环境变化的联合制约,间接反映出载金黄铁矿中金的富集与黄铁矿内部变形、表面形貌和结构缺陷有密切关系。     

气袋采样法对还原硫化物测定的影响因素分析及机理研究

还原硫化物是一Z类典型的恶臭物质,其特点是活性高、不易储存,因此适宜的储存条件对还原硫化物的准确测定具有重要意义。本文使用气相色谱-质谱联用技术,从气袋材质、还原硫化物初始浓度、还原硫化物性质和储存时间四个因素探究袋采样法储存还原硫化物过程的损失情况。以Tedlar~? PVF和Teflon~? FEP为目标采样袋,使用5个初始浓度(0. 001、0. 010、0. 100、1. 000和10. 000μg/m L)的混合还原硫化物,选择0、2、6、12、24、48以及72h的储存时间,以响应因子和相对回收率作为评价因子,并使用配对t检验法和吸附动力学,研究影响储存效果的主要因素、物质损失机理以及两种采样袋的储存能力。结果表明,储存时间越长、物质初始浓度越高,物质活性越强,损失情况越严重;在环境温度达到60℃时,Tedlar~? PVF的基质背景较Teflon~? FEP更复杂;相同条件下,还原硫化物在Teflon~? FEP储存过程中损失更严重。依据研究结果建议:(1)样品采集后避光保存;(2)低浓度含硫样品的测定在采样后8h内完成,高浓度含硫样品的测定在2h内完成;(3)若待测样品气体温度较高,优先选择Teflon~? FEP采样袋,气体温度较低条件下选择Tedlar~? PVF采样袋,可最大限度保持样品的原始状态。本研究成果有利于确保还原硫化物样品的储存稳定性,最大限度还原恶臭污染现场情况,为恶臭污染的分析测试以及后续的恶臭污染控制与治理提供技术支持。