湖南及邻区志留纪兰多弗里世鲁丹期至埃隆期岩相古地理及加里东期板块构造演化

湖南兰多弗里世鲁丹期岩相古地理格局以桃江—白马山—苗儿山一线为界,其南东为华夏洋壳板块兰多弗里统鲁丹阶周家溪组陆屑浊积深水盆地相,陆屑来自更南东的湘中南褶皱山地;其北西为扬子陆壳板块兰多弗里统鲁丹阶龙马溪组沉积洋盆,南东后缘是上陆棚相,北西前缘是下陆棚相,陆屑都由南东湘中南褶皱山地提供。至兰多弗里世埃隆期岩相古地理发生巨变：龙马溪组顶部Coronograptus cyphus笔石带末即大约440.8±1.2 Ma时,发生华夏洋壳板块向扬子陆壳板块俯冲碰撞事件,华夏洋壳板块周家溪组本身褶皱造山为华夏褶皱山地,华夏洋壳板块洋盆关闭。同时华夏洋壳板块以A型俯冲形式下插到扬子陆壳板块之下,并使扬子陆壳板块南东前缘崛起形成加里东期雪峰造山带。后者将扬子陆壳板块南东前缘牵引、挠曲和凹陷成华夏洋壳板块弧后前陆盆地,小河坝组是该弧后前陆盆地的沉积盖层,陆屑都由南东的雪峰造山带提供。该弧后前陆盆地沉积了三角洲相—滨海相的小河坝组,向北东、北西和南西方向相变为台地相石牛栏组,再向北西陕南紫阳相变为盆地相斑鸠关组。小河坝组两次采集的重砂样均出现蓝闪石,它是蓝闪石片岩标志矿物,蓝闪石片岩是确认加里东期华夏洋壳板块与扬子陆壳板块俯冲碰撞及形成雪峰造山带的判别标志。     

鄂尔多斯盆地东北部构造热演化史的磷灰石裂变径迹分析

运用磷灰石裂变径迹(AFT)分析的构造热年代学研究方法,系统探讨鄂尔多斯盆地东北部不同区段中新生代以来的热演化历史,为盆地东北部石油和天然气等多种沉积能源矿产的勘探预测提供新的约束条件。模拟结果表明:盆地东北部经历了250~150 Ma缓慢埋藏增温过程,平均增温速率为0.9℃/Ma;150~120 Ma为快速增温阶段,平均增温速率高达2.1℃/Ma,地层温度达到最高,且均大于130℃。之后不同区段经历差异降温过程:北缘露头区经历了120~65 Ma快速降温,平均冷却速率约1.3℃/Ma;65~10 Ma缓慢降温,平均冷却速率约为0.4℃/Ma。南缘露头区及盆地沉降区则经历了120~30 Ma缓慢降温,平均冷却速率约为0.9℃/Ma;30~10 Ma快速降温,平均冷却速率约为1.5℃/Ma。10 Ma以来,盆地东北部整体抬升冷却,平均冷却速率约6.5℃/Ma。分析结果认为燕山中期构造热事件之最高热增温作用的关键时刻为(120±10)Ma,促成鄂尔多斯盆地东北部主要烃源岩层系的成熟生烃和大规模油气成藏。在后期的差异抬升冷却过程中,北缘露头区在65 Ma±通过了110℃等温面,南缘露头区及盆地的沉降区在30 Ma±通过了110℃等温面,有利于相邻地区原生油气藏的积聚和保存,古近纪晚期(30 Ma)尤其是新近纪晚期近10 Ma以来的强烈构造抬升作用有可能是引发原生油气藏调整—改造和次生成藏的关键因素。     

Chemical and Strontium Isotopic Compositions of the Hanjiang Basin Rivers in China: Anthropogenic Impacts and Chemical Weathering

The Hanjiang River, the largest tributaries of the Changjiang (Yangtze) River, is the water source area of the Middle Route of China’s South-to-North Water Transfer Project. The chemical and strontium isotopic compositions of the river waters are determined with the main purpose of understanding the contribution of chemical weathering processes and anthropogenic inputs on river solutes, as well as the associated CO₂ consumption in the carbonate-dominated basin. The major ion compositions of the Hanjiang River waters are characterized by the dominance of Ca²⁺ and HCO₃ ⁻, followed by Mg²⁺ and SO₄ ²⁻. The increase in TDS and major anions (Cl⁻, NO₃ ⁻, and SO₄ ²⁻) concentrations from upstream to downstream is ascribed to both extensive influences from agriculture and domestic activities over the Hanjiang basin. The chemical and Sr isotopic analyses indicate that three major weathering sources (dolomite, limestone, and silicates) contribute to the total dissolved loads. The contributions of the different end-members to the dissolved load are calculated with the mass balance approach. The calculated results show that the dissolved load is dominated by carbonates weathering, the contribution of which accounts for about 79.4% for the Hanjiang River. The silicate weathering and anthropogenic contributions are approximately 12.3 and 6.87%, respectively. The total TDS fluxes from chemical weathering calculated for the water source area (the upper Hanjiang basin) and the whole Hanjiang basin are approximately 3.8 × 10⁶ and 6.1 × 10⁶ ton/year, respectively. The total chemical weathering (carbonate and silicate) rate for the Hanjiang basin is approximately 38.5 ton/km²/year or 18.6 mm/k year, which is higher than global mean values. The fluxes of CO₂ consumption by carbonate and silicate weathering are estimated to be 56.4 × 10⁹ and 12.9 × 10⁹ mol/year, respectively.     

甲状腺乳头状癌组织坏死后矿化特征研究

组织坏死后矿（钙）化是甲状腺癌病灶中普遍存在的钙化形式之一,与病变关系密切。利用光学显微镜、环境扫描电镜、高分辨透射电镜及显微红外光谱研究了6例甲状腺乳头状癌中的组织坏死后矿化特征。结果表明,组织坏死后矿化往往发生在胶原纤维丰富的位置,与胶原关系密切。矿化表现出2种形态,矿（钙）化灶内为较为致密的隐晶集合体,其表面及其附近的胶原上沉淀有许多微米级矿化小球,离矿化灶较远的胶原纤维上也散布有矿化小球。一些矿化小球边缘还发育絮状矿化物质,使之形成绒球状外貌。矿化物质结晶程度均较差,由纳米多晶组成。钙化灶中央较致密部分的n（Ca）/n（P）比较高,接近羟基磷灰石的理论比值,而其边缘以及矿化小球的n（Ca）/n（P）比均较低,可能含有磷酸八钙等低n（Ca）/n（P）磷酸钙系列矿物。矿化初期形成纳米多晶组成的微米级矿化小球,矿化小球逐渐聚集形成大面积的矿化灶。     

非平稳条件下北京市最大月降水量频率特征分析

为探究气候变化下极端降水的频率变化特征,基于北京市22个雨量站实测月降水量数据,以时间为协变量构建平稳和非平稳GEV模型,对北京市最大月降水量序列(极值降水序列)进行模拟和频率分析,并采用Bootstrap方法对频率分析结果的不确定性进行评价.结果表明:所有极值降水序列的最优概率分布模型均为非平稳GEV模型,该模型能够...     

Spectral Estimation of Irregularly Sampled Nonstationary Multidimensional Processes by Time-Varying Periodogram

A multidimensional version of the time varying periodogram has been developed. The estimation method based on the multidimensional time-varying periodogram has been applied to a nonstationary multidimensional storm model. This work proposes that the multidimensional time varying periodogram is capable of estimating nonstationary spectral density functions in space and time.     

多工况下汉源二蛮山滑坡机理数值模拟

利用FLAC3D软件对四川省雅安市汉源县二蛮山滑坡坡体进行建模,模拟降雨滑坡过程,并进行应力应变特征及稳定性计算分析,从而为深入研究地震及降雨诱发再次滑坡及防灾减灾提供可靠依据。研究中假设地震工况,对边坡进行详细的动力分析,得到了各监测点动力特征曲线;通过降雨工况下坡体稳定性系数分析得到了不同强度折减安全系数。研究结果表明,滑源区相对特殊的地形条件和地质构造以及不利的结构面组合是滑坡的基础;前期强降雨期间饱水加载以及大量雨水沿斜沟张裂结构面的下渗软化作用,是诱发滑坡发生的关键因素。      

Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.     

乳腺炎症及增生症病灶中钙化的矿物学研究

选取9例乳腺炎症、7例乳腺增生的钙化样品,利用光学显微镜(OM)、环境扫描电镜(ESEM)、微区X射线衍射(μ-XRD)等矿物学分析方法对样品进行了原位形貌观察、分离后结构及成分的测试分析,探讨了病灶中钙化的矿物学特征及其组成成分和形成机制。研究结果表明,发生在炎症病灶中的钙化主要类型是脂肪坏死后的钙化,其发生和死亡的脂肪细胞和周围病变后期修复性Ⅲ型胶原有直接关系。增生症中的钙化主要有发生在扩张的导管内和在束状深度交联胶原中的坏死型钙化,扩张的导管边缘处Ⅳ型胶原和大片变性Ⅲ型胶原为钙化提供了成核位点,继而参与无机矿物的形成过程,最后形成较为致密的钙化。乳腺炎症和增生症中的钙化的主要成分均为碳羟磷灰石。     

岩土体渗流自由面问题的重心插值无网格方法

岩土体的渗透破坏、地下工程的防渗设计等无不与渗流计算有关。针对渗流自由面问题,提出一种重心拉格朗日插值的配点型无网格方法。由于渗流自由面问题的求解区域是不规则区域,该方法通过将不规则求解区域嵌入一个正则矩形区域,在正则区域上采用重心拉格朗日插值近似未知函数,利用配点法离散渗流问题的控制方程,将重心拉格朗日插值的微分矩阵离散成代数方程表达的矩阵形式。将自由面上的边界条件通过重心拉格朗日插值离散,通过置换方程法和附加方程法施加边界条件,利用正则区域上的重心插值配点法,通过迭代确定最终自由面的位置。数值算例表明所提出的无网格方法对于求解渗流自由面问题的正确性和高精度。