Conceptual model for early diagenetic chert and dolomite, Amuri Limestone Group, north-eastern South Island, New Zealand

The Late Cretaceous to Early Eocene, dominantly micritic, Amuri Limestone Group (ALG) was deposited in an approximately NW trending trough, in eastern Marlborough, New Zealand. The ALG comprises: the Mead Hill Formation; the Teredo, Lower and Middle Limestone formations; and the Upper and Lower Marl formations. Chert and dolomite are concentrated in the Mead Hill Formation, which contains five of six recognized diagenetic zones: Zone I at the base of the ALG consists almost entirely of chert; Zone II consists solely of chert and dolomite; Zone III comprises chert and limestone; Zone IV is composed of chert plus dolomite; Zone V is a chertified mudstone; and the minor amounts of chert found in the Middle Limestone Formation comprise Zone VI. With the exception of Zones IV and V, chert decreases stratigraphically upwards and away from the basin centre. All the dolomites are composed of <1 mm diameter rhombohedra in discontinuous beds and lenses. Generally Ca-rich, and non- to slightly ferroan, the dolomite contains approximately 500–900 ppm Mn and 200–400 ppm Sr. δ¹³C values average 1–2%_PDB with δ¹⁸O ratios of about -4%_PDB. Mass balance calculations indicate that the Mg²⁺ for dolomitization was derived from sea water. Sr, Fe and Mn concentrations are interpreted as indicating dolomite formation in the marine environment, with no influence from meteoric waters. The intimate association with pyrite implies dolomite formation in association with sulphate reduction, in the upper sediment column. δ¹⁸O data show that the bulk of the dolomite formed at temperatures below 50°C. All chert samples contain in excess of 90 wt% SiO₂, about 1 wt% Al₂O₃ and 1 wt% from losses on ignition. Generally all other major elements total less than 2 wt% oxide. δ¹⁸O values range from 26·8 to 29·0%_SMOW. Chert chemistry is consistent with the replacement of host carbonate and expulsion of carbonate-bound components from the site of chertification, and the effective dilution by SiO₂ of non-carbonate-bound insoluble residues. δ¹⁸O data indicate that chert formed in fluids of similar composition and temperature as the dolomite. The abundance of disseminated pyrite in cherts implies an association with sulphate reduction. Silica for chertification is thought to have initially come from dissolution of siliceous organisms. However, there is insufficient biogenic silica available to form the volumes of chert observed. It is suggested that the bulk of the silica came from SiO₂-rich pore waters generated by clay mineral reactions in the thick underlying mudstones. The ALG compacted down through these pore waters. Chert and dolomite nucleation are considered to have been penecontemporaneous. Dolomitization was initially probably the faster process, continuing as long as sulphate reduction prevailed and there was an adequate supply of Mg²⁺. The nucleation of chert, although initially slower (probably due to a relatively lower initial SiO₂ supply), continued after cessation of dolomitization to the extent of completely chertifying the dolomite intercrystalline matrix. The amount of chertification decreased progressively as SiO₂ supplies diminished, both stratigraphically upwards and away from the basin centre.     

Transmission electron microscope study of quartz microstructures produced by aeolian bombardment

The near-surface structure produced by laboratory aeolian bombardment of Brazilian quartz has been studied with transmission electron microscopy (TEM). Thin specimens of the abraded surface were prepared by a one-sided ion etching technique, and control specimens of unabraded material were prepared by standard ion etching methods. The abraded sample exhibited a vastly larger number of defects than the unabraded specimen. The abraded sample contained areas with very little surface disruption, presumably where pieces of material up to several tens of microns in diameter had broken away. Other areas of the abraded surface were extremely disrupted, with open and closed microcracks spaced from a few tens of angstroms to a few microns apart. Electron diffraction indicated significant rotation among submicron blocks bounded by the fractures. These observations suggest that surface disruption occurs primarily by a mechanism involving brittle fracture, rather than plastic deformation. This study demonstrates the feasibility of studying the effects of abrasion on near-surface structure with TEM. The degree and scale of fracturing also suggest a mechanism for forming submicron particles in quantity during aeolian abrasion.     

Sedimentology and budget of a Recent carbonate mound, Florida Keys

The sedimentology of a Recent carbonate mound is investigated to further our understanding of mound building communities, surface and subsurface mound sediments, and the overall sediment budget of mounds. Nine sedimentary facies of the surface of Tavernier mound, Florida Keys are described. These sediments are composed of Neogoniolithon, Halimeda, Porites, mollusc and foraminiferal grains, and lime mud. Muds rich in aragonite and high magnesian calcite show little mineralogical variation over the mound surface. Geochemical evidence suggests that the mud is mainly formed from breakdown of codiacean algae and Thalassia blade epibionts. Production rates of the facies are established from in situ growth rate experiments and standing-crop surveys. Annual calcium carbonate production is c. 500gm^-2, intermediate between reef and other bay and lagoonal environment production rates in the Caribbean. The internal structure of the mound, studied from piston cores and sediment probes, indicates that seven facies can be identified. Five of these can be related to the present-day facies, and occur in the upper part of the mound (gravel-mound stage). The remaining two facies, characterized by molluscs and aragonite-rich muds, occur in the lower part of the mound (mud-mound stage), and are most similar to facies from typical Florida Bay mud mounds. Mangrove peats within the mound indicate former intertidal areas and C¹⁴ dates from these peats provide a time framework for mound sedimentation. The mound appears to have formed because of an initial valley in the Pleistocene surface which accumulated mud in a shallow embayment during the Holocene transgression. A sediment budget for the mound is presented which compares production rates from present-day facies with subsurface sediment masses. During the mud mound stage production rates were similar to accumulation rates and the mound was similar to the present-day mounds of Florida Bay. During the gravel mound stage (3400 yr BP-present day), conditions were more normal marine and the establishment of Porites and Neogoniolithon on the mound increased production rates 10% over accumulation rates. This excess sediment is thought to be transported off the mound to the surrounding seabed. Models are proposed which divide carbonate mounds on the basis of internal versus external sediment supply. Comparisons are made with other Recent and ancient mounds. Similarities exist between the roles of the biotic components of late Palaeozoic mounds but major differences are found when structures and early diagenesis are compared.     

Messinian stromatolite-thrombolite associations,Santa Pola,SE Spain: an analogue for the Palaeozoic?

Stromatolite-thrombolite associations are the dominant facies forming large portions of the Santa Pola carbonate platform (SE Spain) during deposition of the Terminal Carbonate Complex (TCC). The TCC, the last period of marine sedimentation in the Western Mediterranean associated with the Messinian Salinity Crisis, comprises a NE-SW trending thrombolite reef with occasionally interlayered stromatolite horizons and a predominantply stromatolite and oolite facies in the back-reef area. The stromatolites are mainly dome shaped, but fine-columnar or wavy-undulose forms can occur. The stromatolites form huge bioherms, extending tens to hundreds of metres. They are finely laminated with alternating layers of dolomicrite and dolomicrospar. The dolomicrite layers appear to be a primary dolomite precipitate, whereas the dolomite crystals in the dolomicrospar layers apparently formed around a meta-stable nuclei which was subsequently dissolved or degraded. The low content of sand-sized particles in the stromatolitic layers indicates formation under low-energy conditions, possibly on a tidal flat. As reported from other areas in the Western Mediterranean, deposition of the TCC at Santa Pola was apparently cyclic, whereby stromatolites generally terminate each depositional cycle. Subtidal Conophyton stromatolites, possibly the only known occurrence younger than Palaeozoic, are, however, found on the reef slope at the base of the first TCC depositional cycle. The dolomitic nature of the unadulterated stromatolitic laminations and the association of stromatolites and thrombolites as platform builders were a common feature in the Early Palaeozoic but are unusual in post-Ordovician carbonate facies. We propose that the conditions during TCC deposition were very restricted, possibly reflecting an environment similar to that of the Early Palaeozoic.     

Subglacial to proglacial sediment transition in a shallow ice-contact lake

A complete subglacial to glacial-lacustrine facies transition is described from a temporary exposure in the Lake Michigan bluffs of southeastern Wisconsin. This transition occurs where a Late Woodfordian terminal moraine intersects the bluff line and grades from basal meltout till to chaotic diamicton to rhythmites over an abrupt 90 m lateral distance. The boundary of the subglacial meltout deposits is marked by an abrupt increase in pebbles and cobbles, which cluster at specific horizons, producing an incipient stratification. Thereafter, the diamicton develops contorted flow structures with progressive segregation into coarse and fine-grained fractions, ultimately into well-stratified rhythmites.     

Scaling impact melting and crater dimensions: Implications for the lunar cratering record

Abstract— The dimensions of large craters formed by impact are controlled to a large extent by gravity, whereas the volume of impact melt created during the same event is essentially independent of gravity. This “differential scaling” fosters size-dependent changes in the dynamics of impact-crater and basin formation as well as in the final morphologies of the resulting structures. A variety of such effects can be observed in the lunar cratering record, and some predictions can be made on the basis of calculations of impact melting and crater dimensions. Among them are the following: (1) as event magnitude increases, the volume of melt created relative to that of the crater will grow, and more will be retained inside the rim of the crater or basin. (2) The depth of melting will exceed the depth of excavation at diameters that essentially coincide with both the inflection in the depth-diameter trend and the simple-to-complex transition. (3) The volume of melt will exceed that of the transient cavity at a cavity diameter on the order of the diameter of the Moon; this would arguably correspond to a Moon-melting event. (4) Small lunar craters only rarely display exterior flows of impact melt because the relatively small volumes of melt created can become choked with clasts, increasing the melt's viscosity and chilling it rapidly. Larger craters and basins should suffer little from such a process. (5) Deep melting near the projectile's axis of penetration during larger events will yield a progression in central-structure morphology; with growing event magnitude, this sequence should range from single peaks through multiple peaks to peak rings. (6) The minimum depth of origin of central-peak material should coincide with the maximum depth of melting; the main central peak in a crater the size of Tycho should have had a preimpact depth of close to 15 km.     

ORNITHOPHILIA: THOUGHTS ON GEOGRAPHY IN BIRDING

The deeper motives of bird‐watchers have rarely been subjected to geographical inquiry. Birders are sometimes dismissed as hobbyists bent on compensating for feelings of inadequacy and lack of control in their personal lives. In this article, utilizing textual references as well as experiences from my own participant‐observer status as geographer‐cum‐birder and bird‐tour leader, I construct a geographically oriented approach to understanding the fascinations of bird‐watching. I detail ethnographically the annual Christmas Bird Count and a bird walk in the Honduran rain forest. Then, drawing from the nest‐as‐home metaphors of Gaston Bachelard and the “becoming‐bird” relationships suggested by Gilles Deleuze and Félix Guattari, I position birding as extraordinarily intimate exploration of place, reinforced by anticipation, repetition, experience of beauty, and the culminating encounter of human self, bird or bird spectacle, and landscape.     

Na Metasomatism in the Island-Arc Mantle by Slab Melt--Peridotite Interaction: Evidence from Mantle Xenoliths in the North Kamchatka Arc

The Pliocene (7 Ma) Nb-enriched arc basalts of the ValovayamVolcanic Field (VVF) in the northern segment of the Kamchatkaarc, Russia, host abundant mantle xenoliths, including spinelIherzolites. Textural and microstructural evidence for high-temperature,multi-stage, creep-related deformations in spinel Iherzolitessupports a sub-arc mantle derivation. Pyroxene chemistry indicatesthe existence of two compositional suites: (1) a Cr-diopsidesuite with low-Tt, moderate-Al clinopyroxene compositions, and(2) an Al-augite suite with high Al and Tt, and low Cr concentrationsin clinopyroxene. Some spinel lherzolite xenoliths contain metasomaticAl-augite-type clinopyroxene, Al-Tt spinel, and felsic veinssimilar to trondhjemite melt. The Al-augite series xenolithstypically contain high-Na plagioclase, Cr-poor, Al-Fe-Mg andAl-Tt-Fe spinels, with occasional almandine-grossularite garnetand high-Al and -Na pargasitic amphibole. Pyroxene and spinel compositional trends suggest that the Crdiopsideseries xenoliths from the VVF Nb-enriched arc basalts representan island-arc mantle affected by a metasomatic event. Occurrenceof high-Na plagioclase and trondhjemitic veins favors the additionof a metasomatic component with high Na, Al and Si to the northernKamchatka arc mantle. Trondhjemitic veins, representing siliceousslab melts, compositionally exemplify the metasomatic component.Na metasomatism by peridotite-slab melt interaction is an importantmantle hybridization process responsible for arc-related alkalinemagma generation from a veined sub-arc mantle. KEY WORDS: metasomatism; island arc; mantle xenoliths; Kamchatka; mantle