Petrogenesis and Tectonic Significance of the Three‐Period Porphyries from the Daruoluolong Cu (Au) Deposit,Tibet, China

正Objective The Daruoluolong deposit is the first high-grade Cu(Au)deposit discovered in the middle section of the Bangonghu-Nujiang(herein after referred to as Ban-Nu)metallogenic belt,which has not been documented about previously.This deposit is located in Shuanghu County of northern Tibet,and its geotectonic position belongs to the     

Ore-forming Fluid and Mineral Source of the Hongshi Copper Deposit in the Kalatage Area, East Tianshan, Xinjiang, NW China

The Hongshi copper deposit is located in the middle of the Kalatage ore district in the northern segment of the Dananhu-Tousuquan island-arc belt in East Tianshan, Xinjiang, NW China. This study analyses the fluid inclusions and H, O, and S stable isotopic compositions of the deposit. The fluid-inclusion data indicate that aqueous fluid inclusions were trapped in chalcopyrite-bearing quartz veins in the gangue minerals. The homogenization temperatures range from 108°C to 299°C, and the salinities range from 0.5% to 11.8%, indicating medium to low temperatures and salinities. The trapping pressures range from 34.5 MPa to 56.8 MPa. The δ18OH2O values and δD values of the fluid range from ?6.94‰ to ?5.33‰ and from ?95.31‰ to ?48.20‰, respectively. The H and O isotopic data indicate that the ore-forming fluid derived from a mix of magmatic water and meteoric water and that meteoric water played a significant role. The S isotopic composition of pyrite ranges from 1.9‰ to 5.2‰, with an average value of 3.1‰, and the S isotopic composition of chalcopyrite ranges from ?0.9‰ to 4‰, with an average value of 1.36‰, implying that the S in the ore-forming materials was derived from the mantle. The introduction of meteoric water decreased the temperature, volatile content, and pressure, resulting in immiscibility. These factors may have been the major causes of the mineralization of the Hongshi copper deposit. Based on all the geologic and fluid characteristics, we conclude that the Hongshi copper deposit is an epithermal deposit.     

湖北建始地区志留系钻获致密砂岩气和页岩气

正1研究目的(Objective)勘探实践证明,志留系是我国目前最为有利、最有前景的页岩气勘探开发层系,已在四川盆地的涪陵、长宁—威远等地区取得了页岩气重大突破,进入商业开发阶段。基础地质调查表明,四川盆地周缘地区志留系黑色页岩发育,尤其是鄂西—渝东北地区,志留系底部龙马溪组富含笔石黑色页岩发育,厚度大,页岩有机质丰度高,生烃潜力大。20世纪80年代以来,中石化、中石油实施的常规油气钻井,在志留系龙马溪组均见到了不同程度的页岩气显示,展示了其     

粤东南燕山期热隆伸展及其古水热系统——以恩平-新丰拆离断层为例

粤东南地区广泛发育燕山期NE-SW走向的拆离断层系统。文章对恩平-新丰拆离断层进行了野外地质调查和室内测试分析,重点研究了拆离断层之下韧性剪切带中的糜棱岩和拆离断层上盘与高角度脆性正断层伴生的硅化岩。初步认为,研究区热隆伸展构造于燕山早期开始形成,糜棱岩的变形温度在350℃左右,硅化岩内石英中气液包裹体的均一温度在155℃~326℃,盐度在2.74%~21.61% NaCl_eqv,平均盐度为11.17% NaCl_eqv,古热液流体沸腾时的温度在235℃~241℃,激光拉曼光谱分析结果表明,含硅热液的成分为富含Si、CO₂的NaCl-H₂O溶液。硅化岩流体包裹体的H-O稳定同位素组成表明古水热流体为岩浆水与大气降水混合作用的产物。沿着正断层分布的硅化岩可能是燕山期古水热型地热能的重要标志。燕山期热隆伸展构造系统及其深层与浅层相结合的古水热系统对认识现代地热能的类型、成因及其分布规律有一定的意义。     

极地深部冰层取心钻探孔壁水压致裂研究

为了维护极地深部冰层取心钻探工作中钻孔的稳定,避免孔内事故的发生,冰层孔壁的水压致裂问题是亟待解决的重要科学问题之一。本文在深入分析国内外冰层钻探资料的基础上,结合冰盖动力学相关理论,计算得出了钻孔所在区域冰层的密度、温度及内部应力随深度的变化规律。在此基础上,结合油气资源勘探水力压裂技术与冰层钻进钻井液等相关理论,建立了合理的孔壁压差计算方法,深入探讨了适用于深部冰层钻探孔壁水压致裂机理。研制了冰层钻孔水压致裂模拟实验装置,可分析研究不同围压条件下冰样的脆性变形机理。结合我国Dome A深冰心钻探工程实际,提出钻孔可能发生水压致裂的深度区域及孔壁所需的起始裂纹长度判定,以期为后续的安全高效冰层钻进提供重要的理论依据。     

安徽滁州地区闪长质岩锆石U-Pb年龄与地球化学:岩石成因和动力学意义

用LA-ICP-MS测得安徽滁州2个闪长玢岩样品中锆石~(206)Pb/~(238)U年龄为126.19±0.44Ma和126.4±0.7Ma,结合前人研究,得出滁州地区岩体的侵位时代应为120~130Ma之间,为早白垩世。岩石地球化学研究显示,Si O_2含量变化范围为56.75%~60.90%,具有高Al_2O_3(14.82%~15.77%)、Mg O(4%)、Sr(750×10~(-6))、Sr/Y(62~110)、La/Yb(20~36),低Y、Yb的特征,同时富集轻稀土元素和大离子亲石元素,亏损高场强元素,Eu异常不明显,属于典型的埃达克质岩。Mg~#值为39~45,K_2O/Na_2O值为0.57~0.96,平均值为0.75,明显低于大别造山带加厚下地壳埃达克岩,Ce/Pb值较低,大多集中在3~5之间,类似于陆壳而明显低于洋壳。研究认为,安徽滁州地区埃达克质岩由拆沉下地壳部分熔融形成,埃达克质岩浆在上升过程中与地幔橄榄岩发生反应,导致熔体Mg O、Cr、Ni等含量增加。早白垩世中国东部地壳伸展减薄导致下地壳拆沉,地幔物质的参与带来铜、金等成矿物质,埃达克质岩可作为该地区重要的找矿标志。     

四川西昌盆地白垩纪恐龙足迹群的新发现

四川西昌盆地白垩系小坝组尚未发现骨骼化石记录,其白垩系恐龙动物群的信息全赖于足迹化石。2017年,在喜德县洛甘发现小坝组迄今最大型的恐龙足迹群。该足迹点保存了大量的兽脚类足迹。足迹保存条件较差,但具备了基本的形态学特征。总体来看,兽脚类足迹具有尺寸较小(8~13cm),中等中趾前凹(0.5~0.6)和第Ⅱ趾和第Ⅳ趾间较宽趾间角(70°~100°)的特征;少量足迹保存了跖骨垫。初步分析认为,洛甘兽脚类足迹与四川盆地夹关组的兽脚类足迹Eubrontes和Grallator形态类型相似,为两地在白垩纪中期具有类似的恐龙动物群的观点提供了新的证据。该发现对于西昌盆地的古气候、古地理和地层对比都具有重要的意义,足迹详细分类还有待进一步研究。     

滇东南富宁地区基性侵入岩及喷出岩时代

在滇东南富宁地区基性侵入岩、喷出岩较发育,前人将其划分为"半瓦型"侵入岩、"安定型"侵入岩和"龙康型"喷出岩3类,3类岩石普遍缺乏可靠的同位素年代学资料。在对富宁地区基性侵入岩、喷出岩进行区域地质调查的基础上,应用LAICP-MS技术对其进行锆石U-Pb测年,在半瓦型侵入岩和安定型侵入岩中分别获得了254.0±2.0Ma和244.2±4.4Ma的加权平均年龄,在龙康型喷出岩中获得251.9±3.0Ma和255.92±0.72Ma加权平均年龄。结合野外调查和综合研究,将富宁地区"安定型"侵入岩的时代界定于中三叠世,将"半瓦型"侵入岩和"龙康型"喷出岩的时代界定于晚二叠世。     

Synthesis and characterisation of a multifunctional oil-based drilling fluid additive

An oil-based drilling fluid additive H-DEA (or humic acid-cocamide diethanolamine) was synthesised using humic acid and cocamide diethanolamine as raw materials. The rheological behaviors of H-DEA showed that the synthesised product has the good properties in both decreasing the filtrate loss and improving rheology property of oil-based drilling fluids compared with other commercially available additives. Under the optimal additive amount of 3%, both API filtrate loss and yield point changed remarkably from 5.40 to 0.41 mL and 9.0 to 25.6 Pa, respectively. Furthermore, differential scanning calorimetry (DSC) showed that H-DEA has good thermal stability in a wide temperature range up to 170 °C. Infrared spectroscopy (IR) and rheological analysis revealed that the possible mechanism of the multifunctional effects may be attributed to the existing of high density of strong polar groups, hydrogen bonds, electrostatic forces, and intermolecular association on H-DEA molecular structure. The results of the study showed that the synthesised H-DEA can be potentially used as a multifunctional oil-based drilling fluid additive in oil-drilling excavation.