膜分离技术的应用及发展趋势

综述世界和中国膜分离技术的发展，并对膜分离技术的基本特性、技术特点、膜材料、分类及膜分离装置进行了简单介绍；并介绍了膜分离法在化工及石油工业、食品工业、医药工业和医疗设备、生物技术和环境工程中的应用，并分析了膜分离技术将会在膜材料、新的膜过程和集成膜过程3个方面的发展趋势。同时指出如果能解决膜产品的价格、膜污染和膜分离性能的提高这3个膜的制约因素，膜分离技术将在人类社会的发展史上起到不可替代的作用。     

An experimental study of magnesium-isotope fractionation in chlorophyll-a photosynthesis

Measurements are presented of the magnesium isotopic composition of chlorophyll-a, extracted from cyanobacteria, relative to the isotopic composition of the culture medium in which the cyanobacteria were grown. Yields of 50-93% chlorophyll-a were achieved from the pigment extracts of Synechococcus elongatus, a unicellular cyanobacteria. This material was then digested using concentrated nitric acid to extract magnesium. Separation was accomplished using columns of cation-exchange resin, which achieved a 103 ± 10% yield of magnesium from chlorophyll-a. This procedure ensured accurate measurement of the magnesium-isotopic ratios without isobaric interferences using a multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We find a slight depletion in the heavier isotopes of magnesium in chlorophyll-a relative to culture medium, early growth phase: Δ²⁶Mg = −0.71(±0.35)‰ and Δ²⁵Mg = −0.37(±0.18)‰; late growth phase: Δ²⁶Mg = −0.53(±0.20)‰ and Δ²⁵Mg = −0.26(±0.11)‰, due to an apparent mass-dependent fractionation. We suggest that the small fractionation results from chelation during intracellular processes. A likely candidate for this chelation step involves the magnesium-chelatase enzyme, which mediates the insertion of magnesium to the tetrapyrrole ring during chlorophyll-a biosynthesis. Proof of this hypothesis can be tested with biological controls whereby steps in the enzymatic pathways of chlorophyll synthesis are selectively suppressed.     

Increasing critical sensitivity of the Load/Unload Response Ratio before large earthquakes with identified stress accumulation pattern

The Load/Unload Response Ratio (LURR) method is proposed for short-to-intermediate-term earthquake prediction [Yin, X.C., Chen, X.Z., Song, Z.P., Yin, C., 1995. A New Approach to Earthquake Prediction — The Load/Unload Response Ratio (LURR) Theory, Pure Appl. Geophys., 145, 701–715]. This method is based on measuring the ratio between Benioff strains released during the time periods of loading and unloading, corresponding to the Coulomb Failure Stress change induced by Earth tides on optimally oriented faults. According to the method, the LURR time series usually climb to an anomalously high peak prior to occurrence of a large earthquake. Previous studies have indicated that the size of critical seismogenic region selected for LURR measurements has great influence on the evaluation of LURR. In this study, we replace the circular region usually adopted in LURR practice with an area within which the tectonic stress change would mostly affect the Coulomb stress on a potential seismogenic fault of a future event. The Coulomb stress change before a hypothetical earthquake is calculated based on a simple back-slip dislocation model of the event. This new algorithm, by combining the LURR method with our choice of identified area with increased Coulomb stress, is devised to improve the sensitivity of LURR to measure criticality of stress accumulation before a large earthquake. Retrospective tests of this algorithm on four large earthquakes occurred in California over the last two decades show remarkable enhancement of the LURR precursory anomalies. For some strong events of lesser magnitudes occurred in the same neighborhoods and during the same time periods, significant anomalies are found if circular areas are used, and are not found if increased Coulomb stress areas are used for LURR data selection. The unique feature of this algorithm may provide stronger constraints on forecasts of the size and location of future large events.     

那棱格勒河流域及尾闾盐湖水文循环动力学模型的选择

流域水文模型的研制是水文科学中最重要的分支之一。其中包括集总式和分布式流域水文模型,分布式流域水文模型的种类很多,在我国的研究和应用比较普遍。那棱格勒河是柴达木盆地最大的一条河流,正确评价该河流的水文情况,对开发柴达木盆地盐湖资源具有十分重要的意义。应用分布式流域水文模型理论,对适用于那棱格勒河流域的水文循环动力学模型的类型进行选择,通过分析对比,选择出最适合本地区特殊条件的TOPKAPI模型,以便于探讨该地区水文循环的特点与规律,从而阐明盐湖区各类水体间的相互补给关系。     

大气CO2浓度升高对土壤中不同粒级碳的影响

不同粒级土壤中的碳有着不同的周转规律，在高CO2浓度条件下，它们含量的变化将在一定程度上反映土壤碳是累积还是减少，对明确土壤碳的变化趋势有重要意义．采用田间培养试验初步模拟研究在高CO2浓度条件下土壤不同粒级碳的分布．结果表明，加入秸秆培养1年，由于CO2浓度升高的原因导致在低氮（LN）、常规氮（NN）和高氮（HN）水平下土壤中碳分别增加0．01、1．10、1．22g／kg，表现为粒级〈53μm土壤颗粒中碳分别增加1．53、2．19、2．70g／kg．粒级〈53μmm土壤颗粒碳量的增加，主要是由于其重量分配百分数显著增加36．2％，碳浓度增加5．4％；粒级〉250μm和250～53μm土壤颗粒部分虽然其碳浓度分别增加20．8％和17．3％（P〈0．05），怛由于重量分配百分数分别显著降低22．8％和36．1％，结果碳量降低．试验表明高CO2浓度导致不同粒级土壤的分配及碳浓度的变化；高氮施肥水平下有增加土壤碳量特别是小粒级土壤碳量的趋势．     

江西省宜春城区地面塌陷特征及防治建议

宜春城区属岗阜低丘地形,分布石炭系-二叠系覆盖型及裸露型碳酸盐岩,占城区面积近70%。浅部岩溶发育,覆盖层厚度一般小于20m,土洞较多,基岩面起伏大,第四系岩性结构复杂,地下水埋藏浅。由于抽采地下水及建筑施工振动等人为因素影响,诱发地面塌陷12处,造成重大经济损失。在城市规划功能布局时应充分考虑地面塌陷的易发程度及场地建设适宜性;应限制诱发塌陷因素的强度,在易发区须严格控制地下水开采,严禁新建开采井;塌陷治理的主要方法有填堵、跨越、灌注、深基础控制抽排水强度、及其它综合治理或避让方法,同时做好灾害的监测预报工作。     

三种高程传递方法的精度分析

通过试验对悬挂钢尺、GPS测高和全站仪垂直测高三种高程传递方法进行了理论分析与精度比较,并讨论了各种方法在实际应用中的优点与局限性。     

土地利用规划电子政务系统的设计与实现

本文在分析了电子政务的内涵和作用的基础上,阐述了建设土地利用规划电子政务系统的必要性。依据国土资源电子政务系统建设目标和规范,在MapGuide平台上应用办公自动化、GIS、Oracle数据库等技术,确定了系统的总体设计。完成了土地利用规划电子政务系统的建设,实现了规划和国土资源管理的公平、公开、公正和公信,促进了规划和国土资源管理的科学化和规范化,大大提高了土地利用规划工作的效率。     

裂缝性岩石裂缝扩展的光弹构造物理模拟——以南华北盆地户部寨沙河阶组为例

以南华北盆地户部寨第三系沙河阶组粉砂岩低渗透储层为例,总结了其中发育的5种类型构造裂缝组合,即:①南北向雁形张节理组成的共轭剪节理带;②东西向雁形张节理组成的共轭剪节理带;③缠结状多组剪切构造裂缝;④组合状交切的多组剪切构造裂缝及张裂缝;⑤散状无序排列的构造裂缝。在此基础上,建立光弹性试验构造物理模型,沿现应力场96°方向,均匀地对该模型逐步增加外载力。结果表明,沿各组合裂缝尖端分别形成对称于裂缝走向、且主轴垂直于裂缝的Ⅰ型等色线条纹;对称于裂缝走向、且主轴平行于裂缝走向的Ⅱ型条纹和斜交于裂缝走向的复合型(Ⅲ型)条纹。第①类组合裂缝尖端以Ⅰ型等色线条纹的拉张应力和张剪应力为主;第②类组合裂缝尖端以复合型(Ⅲ型)等色线条纹的挤压应力为主;第③、④和⑤类组合裂缝尖端的应力分布较为复杂。当模型外载荷接近1000kg时,裂缝尖端起裂,并开始发育显微裂缝,而当外载荷达1100-1200 kg时,沿裂缝尖端部位形成宏观裂缝,并开始扩展。5种类型的裂缝组合扩展发育程度由强至弱依次为:①,③,⑤,②,④。其中第①类共轭裂缝组合起裂最早,扩展最快,裂缝间的连通趋势最好,说明规则分布的构造裂缝组合,在垂直于外施加载衙时更易达到连通的目的。     

北京市区春季燃烧源大气颗粒物的污染水平和影响因素

以大气中PM2.5和PM10为研究对象,于2005-03-13—25共7天的时间内,在中国地质大学(北京)测试楼顶、首钢焦化厂和首钢东门设立3个采样点进行采样监测。结果表明:PM2.5和PM10质量浓度的日变化呈现一定规律性,在不同时段PM2.5和PM10的质量浓度不尽相同,且变化较大,在特定时刻出现峰值,主要受污染源排放和气象因素的控制;PM2.5和PM10质量浓度随气温的升高而降低,这与高温有利于颗粒物扩散、低温容易形成逆温层有关;在一定的相对湿度范围内(以大气中水汽不发生重力沉降为界限),PM2.5和PM10质量浓度与相对湿度呈正相关关系;而当发生降水时,由于水滴的冲刷和附带作用,PM2.5和PM10质量浓度降低;PM2.5和PM10质量浓度与风级呈明显的负相关关系。通过北京市与国内8个省会城市的PM2.5和PM10质量浓度的对比,发现北京市PM2.5和PM10污染比较严重,PM2.5和PM10质量浓度分别超过了1996年中国制定的PM10排放标准和1997年美国EPA制定的PM2.5排放标准。