Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.     

昆明城市气候水平空间分布特征

以昆明城市为研究对象，对城市西南-东北剖线的实测资料比较研究，从气温、水汽压、相对湿度、风速、风向等方面分析了昆明城市气候特征、变化规律及城市热岛效应。研究表明：在昆明存在热岛效应，以夜间最为明显，其最强度效应可达5.0℃，出现时刻（3时）与国内外多数研究结果（傍晚）有所不同；昆明城市昼间呈现明显的干岛效应。所得结论可为探讨昆明城市气候特片和形成机制，城市环境污染防治及建筑规划、设计等提供依据。     

扬子板块北缘下志留统龙马溪组重晶石结核特征及其成因机制分析

在扬子板块北缘城口明中剖面及巫溪徐家坝剖面下志留统龙马溪组底部的硅质岩、泥岩中发现椭球状重晶石结核。其矿物组成主要为重晶石颗粒与作为"基质"的黄铁矿、粘土矿物和石英。通过重晶石岩石学、矿物学及锶同位素分析表明,重晶石结核形成于早期成岩阶段松软沉积物的孔隙水中。上升洋流带来丰富的营养及富钡物质,表层海水的高初始生产力促使生物繁盛,海水中的钡通过生物作用富集形成生物钡,生物钡(bio-barite)在埋藏过程中的硫酸盐耗竭区(sulfate depleted zones)通过硫酸盐细菌作用(BSR)溶解被激活提供了钡的来源。围岩岩性(黑色泥岩和硅质泥岩)表明重晶石结核形成于缺氧的环境中。上述研究对深入理解早志留世时期扬子板块北缘古海洋环境有一定的启示作用。     

Delineating the Source of Lead in the Urban Atmospheric Dust Based on Stable Isotopic Ratio: A Case Study from Panzhihua City of Southwest China

正Objective Atmospheric lead pollution is a global problem. Mining, coal mining, iron and steel smelting, and chemical and coal-fired power plants are major industries in Panzhihua City of southwest China. Many toxic and harmful heavy metals, including Pb, are emitted in production activities. Pb seriously affects human health and natural ecosystems. Thus, Pb source tracing is important for Pb pollution     

胶东新城金矿地质构造特征及深部找矿方向

新城金矿历经20余年的开采,保有矿量服务年限逐渐减少,影响了矿山可持续发展。Ⅴ号盲矿体的发现,证明了矿床深部具有良好的成矿地质条件,为矿山深部第二富集带找矿提供了依据。本文为胶东金矿成矿规律及矿床深部找矿方向的研究,提供了有重要参考价值的资料。      

黑龙江省闪电活动特征及其与地面相对湿度的响应关系

利用2006-2017年黑龙江省闪电定位资料和日平均地面相对湿度资料,采用数理统计、Pearson相关分析、GIS空间分析技术,研究了闪电密度和强度对地面相对湿度（R_H）的响应关系。结果表明：地面R_H过小或过大都不利于闪电活动产生;当R_H < 25%时,几乎无闪电发生,当R_H < 77%时,R_H增加有利于闪电活动发生,当R_H>79%时,随着R_H增加,闪电活动减少;当R_H < 77%时,闪电密度与之呈正相关,闪电强度与之呈负相关;当R_H>79%时,闪电密度与之呈负相关,闪电强度与之呈正相关;地面R_H的临界值域约为77%-79%;70%≤ R_H ≤ 90%区间为闪电易发湿度区间,在闪电密度与湿度相关度高的区域,闪电更趋于集中发生在闪电易发湿度区间。     

哈密黄山铜镍矿蚀变矿物近红外光谱特征分析

在哈密黄山铜镍矿区,采用PIMA(便携式短波红外矿物分析仪)进行野外光谱测试,用新引进的TSG(光谱地质专家)软件进行了矿物种类及相对含量识别、光谱处理分析,为蚀变矿物光谱分析起到了示范作用。详细论述了几类典型蚀变矿物的光谱特征;对绿泥石特征光谱吸收强度D(Fe-OH)、D(Mg-OH)与矿物成分的关系进行了探讨。结果表明,绿泥石Fe-OH和Mg-OH吸收强度比值可以大体上代替Fe2+/Mg2+比值,D[Mg-OH)/(Fe-OH)+(Mg-OH)]值绝大部分在0.4~0.8之间。用HyMap数据做地质信息半定量反演,准确反映了各岩相主要金属元素含量的变化。研究结果对高光谱技术识别矿物种类、反演岩矿成分具有重要意义。     

地质勘探过程中煤层气联测氢气方法

瓦斯的危害和煤层气的利用,不断在推进着瓦斯地质理论、煤层气开发利用技术的进步和发展。在以往的诸多研究中,不论是防治瓦斯的危害还是着眼于煤层气的利用,甲烷都是研究的重点。但是,除甲烷之外,还有没有其它影响或控制瓦斯危害和煤层气利用的组分或因素呢？煤层气（瓦斯）联测氢气的方法和应用研究,就是循着这一思路而做的探索性工作。     

东亚地区现代地壳运动特征与构造变形

根据“中国地壳运动观测网络”首次发布的GPS观测结果以及国际地球自转服务中心在 2 0 0 0年发布的ITRF97下的站速度矢量和“东南亚地球动力学项目”GPS网的观测结果 ,讨论了东亚地区现今地壳运动和构造变形特征。在ITRF97参考系下 ,中国大陆东部现今地壳运动以向南东方向(12 0 130°)运动为主 ,量值平均为 35mm/a ,西部受印度板块向北东碰撞的影响 ,运动方向发生偏转 ,呈显北东—近东西向运动 ,但这种影响涉及的范围达到了准噶尔盆地北缘一线 ,说明碰撞型板块边界对板内变形的影响远大于俯冲型板块边界。平均来看 ,75 %以上的印度板块相对于欧亚板块间的南北向缩短是通过地壳增厚变形来吸收的 ,这意味着在调节整个青藏高原构造变形的过程中 ,逆断和地壳增厚起了主要的作用。东南亚块体总体上与欧亚板块的运动有所差异 ,相对于欧亚大陆有 10mm/a左右向东的运动。菲律宾板块南部向西的运动速度只有 2 4mm/a。包括华南地块在内的东南亚块体的运动不仅仅是与印度板块的碰撞过程有关 ,也应当与沿着东南亚块体东边界的俯冲过程有关。     

A Large-Eddy Simulation and Lagrangian Stochastic Study of Heavy Particle Dispersion in the Convective Boundary Layer

Large-eddy simulation and Lagrangian stochastic dispersion models were used to study heavy particle dispersion in the convective boundary layer (CBL). The effects of various geostrophic winds, particle diameters, and subgrid-scale (SGS) turbulence were investigated. Results showed an obvious depression in the vertical dispersion of heavy particles in the CBL and major vertical stratification in the distribution of particle concentrations, relative to the passive dispersion. Stronger geostrophic winds tended to increase the dispersion of heavy particles in the lower CBL. The SGS turbulence, particularly near the surface, markedly influenced the dispersion of heavy particles in the CBL. For reference, simulations using passive particles were also conducted; these simulation results agreed well with results from previous convective tank experiments and numerical simulations.