Occurrence and conceptual sedimentary model of Cambrian gypsum-bearing evaporites in the Sichuan Basin,SW China

During the Cambrian, gypsum-bearing evaporites formed in the Sichuan Basin, SW China. These rocks are important for oil and gas sealing, but details of their distribution and origin are not well established. This study examines the regional distribution and origin of the gypsum-bearing evaporites using a comprehensive analysis of drilling data from 34 wells, 5 measured cross-sections in the basin and surrounding area, and 96 maps of area-survey data. Results show that in the stratigraphic succession, the gypsum-bearing evaporites occur mainly in the Lower Cambrian Longwangmiao Formation, the Middle Cambrian Douposi Formation, and the Middle-Upper Cambrian Xixiangchi Group. Geographically, the rocks are found mainly in the southeastern part of the basin, and the distribution of deposits shows an overall SW-NE trend. The sedimentary environments for evaporite formation were evaporative lagoon and inter-platform basin in a platform setting. Gypsum was generated by the underwater concentration of sea water in a strongly evaporative environment. Both an evaporative restricted platform and a mixeddeposition restricted platform model appear to be applicable to the development of gypsum in the Sichuan Basin. The gypsum-bearing evaporites with the best sealing capacity are located mostly in the southeastern part of the basin. These constraints can be applied directly to regional exploration, and have implications for the regional paleogeography and paleoclimate.     

内蒙古巴拉格歹地区构造混杂岩带中浊积岩、震积岩特征及意义——以内蒙古哈拉黑等八幅1:5万区域地质调查为例

浊积岩为具有鲍马序列的古海沟沉积,其部分沉积物与古海沟地震密切相关,由于岛弧外弧海沟地质构造复杂,洋板块俯冲及火山岩的喷发,地震活动强烈、频繁,沉积岩在成岩过程不断受到地震扰动,形成具有地震活动特点的震积岩。通过对巴拉格歹地区构造混杂岩带中浊积岩、震积岩的研究,识别出浊积岩系的具递变层理的槽模、沟模等冲刷铸模,包卷层理构造及最顶部黑色粉砂质泥岩段;识别出震积岩系的液化脉、地震震碎角砾岩、滑塌角砾岩、震褶岩-卷曲、纹层状、阶梯状断层构造等,建立并确认浊积岩、地震岩识别标志,恢复古地理构造环境,认为原划分的大石寨组应该解体,应为一套弧前盆地古海沟浊积岩沉积。结合浊积岩中的火山岩、基性岩及区域上化石山发现的超基性岩,初步确认,在测区浊积岩与岛弧火山岩、洋壳沉积物受板块碰撞拼接作用,由一系列逆冲断裂将上述各种块体构造就位在一起,形成构造混杂岩,为二连-贺根山缝合带在本区东延问题提供了资料。     

A preliminary study on the spatial distribution characteristics and causes of strontium-rich mineral water in the Dushan complex

The mountain rocks in the Dushan Complex are Sr-rich granite with a much higher Sr level than those in other crustal lithospheres in eastern China. That presents a high potential for developing Sr-rich mineral water. In this study, 6 groups of rock samples, together with 30 groups of water samples, were collected. Combining with the existing data, the Sr contents in three different types of underground water were obtained, which are the Quaternary pore water, the meshed bedrock fissure water in weathered zones and the tectonic bedrock fissure water. On the basis of preliminary understanding for the distribution characteristics of Sr-rich mineral water in the Dushan Mountain region, the causes for the Sr-rich mineral water were investigated. Our results showed that the Sr content of the rocks in the studied area ranges from 988 to 1 950 μg/g. In the horizontal direction, those in both the pore water and the meshed bedrock fissure water in weathered zones show high values in the west but low ones in the east, and high ones in the south but low ones in the north. Furthermore, both types of water meet the standard for Sr-rich mineral water in the western areas. In the vertical direction, the Sr content shows the lowest value in pore water(the average value is 0.707 mg/L), middle value in the meshed bedrock fissure water in weathered zones(the average value is 1.415 mg/L) and the highest value in the tectonic bedrock fissure water(the average value is 8.331 mg/L). It was thought that the widely-developed Sr-rich granite in this region provides physical sources for the formation of Sr-rich mineral water. The continuous dissolution of Sr during underground water runoff is the internal mechanism. In addition, the hydraulic interrelations may exist between the three vertical aquifers, leading a continuous accumulation of the Sr level during infiltration.     

黔东地区航磁特征与岩性构造填图

为了弄清黔东深覆盖地区的成矿地质背景,以2014年该区1:5万比例尺的直升机航磁资料为基础,结合地质、重力等资料,研究了该区不同岩浆岩、断裂构造的航磁特征,在综合分析的基础上,编制了该区的岩性构造图。通过分析对比,本次新圈定具有一定规模的隐伏岩体7处、蚀变岩15处,新圈定不同规模的断裂17条 。上述成果对黔东地区基础地质研究和找矿工作具有重要意义。     

中国—吉尔吉斯斯坦天山构造格架与演化

中国—吉尔吉斯斯坦天山地处中亚天山造山带中段,地质构造复杂,矿产资源丰富。在前人资料基础上,基于区域构造-岩石组合的分布发育及时空属性特征,统一将研究区划分为哈萨克斯坦和塔里木两大板块,二者由南天山晚古生代缝合带所焊接。其中,进一步划分为5个二级单元,18个三级单元。研究认为,研究区内北、中、南天山构造格架连续,在800 Ma(相当于南华纪下限)前后都完成了大陆块体的拼合,成为全球新元古代罗迪尼亚超大陆的组成部分。此后经历了大致相同的构造演化史,从中二叠世开始全区转化成陆内盆山构造格局,新生代印度大陆同欧亚大陆碰撞使这一陆内盆山构造格局不断臻于完善。     

Middle Jurassic–Early Cretaceous tectonic evolution of the Bayanhushuo area,southern Great Xing’an Range,NE China: constraints from zircon U–Pb geochronological and geochemical data of volcanic and subvolcanic rocks

This study presents new zircon U–Pb geochronology, geochemistry, and zircon Hf isotopic data of volcanic and subvolcanic rocks that crop out in the Bayanhushuo area of the southern Great Xing’an Range (GXR) of NE China. These data provide insights into the tectonic evolution of this area during the late Mesozoic and constrain the evolution of the Mongol–Okhotsk Ocean. Combining these new ages with previously published data suggests that the late Mesozoic volcanism occurred in two distinct episodes: Early–Middle Jurassic (176–173 Ma) and Late Jurassic–Early Cretaceous (151–138 Ma). The Early–Middle Jurassic dacite porphyry belongs to high-K calc-alkaline series, showing the features of I-type igneous rock. This unit has zircon ε_Hf(t) values from +4.06 to +11.62 that yield two-stage model ages (T_DM2) from 959 to 481 Ma. The geochemistry of the dacite porphyry is indicative of formation in a volcanic arc tectonic setting, and it is derived from a primary magma generated by the partial melting of juvenile mafic crustal material. The Late Jurassic–Early Cretaceous volcanic rocks belong to high-K calc-alkaline or shoshonite series and have A₂-type affinities. These volcanics have ε_Hf(t) and T_DM2 values from +5.00 to +8.93 and from 879 to 627 Ma, respectively. The geochemistry of these Late Jurassic–Early Cretaceous volcanic rocks is indicative of formation in a post-collisional extensional environment, and they formed from primary magmas generated by the partial melting of juvenile mafic lower crust. The discovery of late Mesozoic volcanic and subvolcanic rocks within the southern GXR indicates that this region was in volcanic arc and extensional tectonic settings during the Early–Middle Jurassic and the Late Jurassic–Early Cretaceous, respectively. This indicates that the Mongol–Okhotsk oceanic plate was undergoing subduction during the Early–Middle Jurassic, and this ocean adjacent to the GXR may have closed by the Late Middle Jurassic–Early Late Jurassic.     

延边农坪富金斑岩铜矿床花岗闪长斑岩年代学、地球化学及其地质意义

农坪金铜矿床位于吉林省珲春市春化境内,是一座中型富金斑岩型矿床。文章采用LA-ICP-MS锆石U-Pb定年方法,对农坪含矿花岗闪长斑岩进行了锆石U-Pb分析,获得加权平均年龄为(95.6±1.6)Ma,表明花岗闪长斑岩形成于晚白垩世。地球化学分析显示,农坪含矿斑岩富碱(5.6%~6.7%),高Mg#(47~55)、富集LILE和LREE,亏损HFSE和HREE,高Sr/Y(32~57)、(La/Yb)N(10~21)比值,具有埃达克质岩石的特点,岩浆的形成可能存在壳幔混合及分离结晶作用。结合区域大地构造背景和同一构造带上其他矿床的形成时代和特征,笔者认为农坪矿床是晚白垩世古太平洋板块向欧亚大陆斜向俯冲背景下陆缘弧岩浆作用及热液活动的产物。     

渝东南地区下寒武统牛蹄塘组页岩孔径分布测试方法研究

低温氮气吸附法已普遍用于评价页岩的孔隙结构,但是文献中报道的脱气温度和脱气时间等测试条件不尽相同,此外测试结果中经常出现滞后环不闭合的情况,严重影响了孔径分布等结构参数测试的准确性。为了评价和探索有效的页岩孔径分布测试方法,本文选取渝科1井下寒武统牛蹄塘组黑色页岩,重点研究应用低温氮气吸附法分析其孔径分布的测试条件,系统探讨了样品质量、脱气温度、升温速率和脱气时间对测试结果的影响,通过进一步优化参数建立了可靠的孔径分布测试方法,并成功用于测定其他页岩样品。结果表明:吸附-脱附等温线呈反C型,属于Brunauer等提出的BDDT等温吸附曲线分类中的V型,滞后环完全闭合,属于IUPAC分类中的H4型,对应狭窄的狭缝型孔隙,说明此类页岩中除了含有峰值孔径主要集中在3.5~4.5 nm的中孔和一定数量的大孔外,还存在大量微孔。研究认为脱气温度是影响测试结果的主要因素。该研究是页岩孔径分布测试方法的一项补充,为我国页岩气的深入研究提供了关键参数支持。     

碘化氨除锡后封闭酸溶-电感耦合等离子体质谱测定锡矿石中的共生和伴生元素

锡矿石是难分解的矿物,主要存在形式是锡石(SnO_2),且共生和伴生元素多,常用的酸溶方法几乎不能溶解SnO_2,从而给锡矿石中的共生与伴生元素的准确测定带来困难。本文基于碘化氨在较低温度下熔融可产生无水状态的碘化氢,利用碘化氢的酸性和氨的还原性分解SnO_2,使Sn呈SnI_4升华分离的原理处理锡矿石。实验中以高纯铂丝作催化剂,加入碘化铵在450℃的马弗炉中分解锡矿石30 min,使得Sn以SnI_4形式挥发,除锡率达到98%以上,再用2 mL氢氟酸和1 mL硝酸封闭溶解残渣,电感耦合等离子体质谱测定钴镍铜铌钽钍铀等24个共生和伴生元素。元素检出限在0. 001～2. 9μg/g之间,90%以上元素的相对标准偏差(RSD)小于5%,相对误差小于10%。本方法解决了锡矿石难分解的问题,可测定共存金属元素,也适合测定Sn含量在1. 27%～62. 49%之间的锡矿石中的微量和痕量元素及锡精矿中的微量元素。     

四川盆地：周缘活动主控下形成的叠合盆地

四川盆地位于扬子板块西缘和青藏高原东缘,地震勘探资料等揭示盆地前寒武纪基底保存完整的古俯冲带和地堑-地垒结构,说明盆地基底后期构造活动非常稳定;显生宙以来经历晚震旦世-石炭纪、二叠纪-中三叠世两幕克拉通边缘强拉张-强挤压,而克拉通内弱拉张-弱挤压的构造演化过程,体现出盆地内部稳定性结构沉积演化特征。克拉通内弱拉张初期以海相碳酸盐岩大面积稳定沉积（即震旦系灯影组和二叠系栖霞-茅口组）和随后的风化壳岩溶作用（即桐湾期、东吴期等不整合面）为特征,弱拉张期以拉张槽（如：绵阳-长宁拉张槽和开江-梁平拉张槽等）的形成为典型特征;弱挤压则以古隆起（如：加里东期乐山-龙女寺古隆起、印支期泸州古隆起等）的发育为典型特征。四川盆地晚三叠世后的前陆盆地演化阶段受控于其周缘造山带逆冲推覆构造活动,是现今地貌和构造盆地的主要建造期,形成了四川盆地周缘突变（线型）和渐变（弥散型）两种盆山结构。盆地西边界（龙门山）和北边界（米仓山-大巴山）即是线型突变边界,也是扬子地块（板块）的边界,边界几何形状和扬子板块刚性特征对盆山系统结构-构造特征等有较大的控制作用;四川盆地的东边界（齐岳山-大娄山）和西南边界（大凉山）即是渐变弥散型边界,同时也是板（陆）块内部的边界,它们受控于邻区（盆外）的构造变形和盆内沉积盖层中滑脱层的分布特征。受控于盆地（克拉通）周缘活动,四川盆地垂向上前寒武纪基底与盖层、盖层内早期和晚期构造具解耦特征。基底与盖层构造的解耦有利于盆地内部前寒武纪基底结构构造的保存和盖层内大型隆-坳结构的形成演化;盖层内早期和晚期构造的解耦有利于早期构造免遭后期破环,对深层油气藏的保存意义重大。总之,四川盆地可能是具独特形成过程和特征的叠合盆地新类型,其突出特征表现为周缘活动、内部稳定及早期和晚期构造解耦。