北极秋季海冰密集度与中国初冬降雨之间的关系

本文通过对中国地区实测降水及北极海冰卫星数据的分析,研究了北极秋季海冰密集度与中国初冬降雨的关系。合成分析的研究结果表明2000年之前中国南方和北方冬季降水偏少,中部降水偏多,这之后中国南方和北方冬季降水增加,中部降水减少。SVD研究结果显示,北极海冰减少使得近三十年来中国南方和北方冬季降雨呈现逐渐增多,中部地区(从青藏高原向东北方向至日本)降雨逐步减少的趋势。随着北极海冰的进一步减少,如遇合适的气候条件,南方冻雨出现的概率会加大。北极秋季海冰异常的回复过程加之冬季海冰异常的延续信号在中国、蒙古及日本北部激发一个阻塞高压,以巴伦支海/卡拉海为中心激发一个异常低压。这使得来自北冰洋大西洋扇区的冷空气南下至欧洲大陆和亚洲北部,在阻塞高压的影响下,冷空气进一步南下,进入东亚地区。这不仅使得亚洲冬季温度降低,也为中国北部降水增加提供条件。     

A statistical analysis of mesoscale eddies in the Bay of Bengal from 22–year altimetry data

本文使用一种基于SLA数据的涡旋识别方法,通过22年的AVISO高度计测高数据对孟加拉湾的中尺度涡特征进行了研究。本文主要分析了孟加拉湾涡旋的地理分布、涡旋极性、涡旋生命周期和传播距离、涡旋产生和消失位置、涡旋传播方向和移动轨迹、涡旋运动特征、涡旋属性的演化以及涡旋活动的季节和年际变化等特性。涡旋主要分布在孟加拉湾西部海域,并且大部分涡旋向西移动。涡旋极性分布显示气旋涡更经常出现在湾的西北部和南部,而反气旋涡主要出现在湾的东部。在22年间,共追踪探测到生命周期超过30天的气旋涡565个、反气旋涡389个;对所有生命周期和传播距离而言都是气旋涡数量居多。所有观测到的涡旋的运动属性分析显示气旋涡的涡旋平均振幅大于反气旋涡;对平均半径和平均移动速度而言,气旋涡和反气旋涡相差不大。而且,涡旋属性演化显示生命周期超过90天的涡旋具有明显的双阶段演化特征,包括一个前50天的涡旋成长阶段和一个50天之后的涡旋消亡阶段。针对涡旋活动的季节变化,气旋涡在春季居多而反气旋涡在夏季较多;长生命周期的涡旋季节分布显示在孟加拉湾涡旋活动具有明显的季节分布特征。涡旋数量的年际变化与EKE变化有一个明显的负相关。     

天津市滨海新区芦苇湿地恢复适宜性评价

利用综合评价模型,结合地理信息系统技术的空间分析功能,以土地利用、土壤类型、坡度、降雨量和人类干扰活动作为评价因子,对天津滨海新区芦苇湿地恢复进行了适宜性评价。结果表明,较适宜开展湿地恢复的比例为21.46%,一般适宜比例为21.87%,不适宜比例占56.68%,其中较适宜湿地恢复的区域集中分布在北大港湿地自然保护区周边、独流减河下游、北塘入海口以及沿海滩涂,海河流域两侧也有零星分布。在适宜性评价基础上,对未来芦苇湿地恢复与建设的重点区域进行了成效预评估,芦苇对TC、TN、TP的年吸收通量约为1.3935×104、0.0258×104、0.0017×104t,能有效地减少入海排污压力和污染物对近岸海域环境质量的影响。研究结论可为天津湿地治理与生态恢复、土地利用结构调整、景观优化等提供理论依据和科学参考。     

基于同步风场的机载SAR海浪参数反演方法

针对机载合成孔径雷达(SAR)对海探测特点,采用多入射角法从SAR数据本身得到与海浪参数反演区域时空匹配的同步海面风速和风向,并结合线性变换关系,计算得到海浪初猜谱对应的仿真SAR图像谱,将仿真SAR图像谱和观测SAR图像谱输入代价函数中进行迭代运算,通过非线性方程的解算得到最适海浪谱;采用交叉谱法去除海浪传播180°方向模糊,最终得到海浪参数。论文提出的基于同步风场的机载SAR海浪参数反演方法,充分利用了机载SAR海洋环境探测的优势,解决了传统SAR海浪参数反演中初猜谱构造依赖外部风场的问题,机载同步飞行试验的海浪参数反演结果与浮标观测值的有效波高、波向的均方根误差分别为0.23 m和13.23°,验证了该方法的有效性,可为机载SAR海浪参数反演业务化提供支持。     

Study of Influence of Regional Geodynamic Background on Strata Behaviors in China's Tongxin Mine

Strata behaviors are mainly affected by regional geodynamic background. The influence of rock mass stress and energy distribution on strata behaviors in the Tongxin mine is studied in terms of regional tectonic movement, seismic activity and tectonic stress field. The results show that the extrusion lifting movement of Kouquan fault adjacent to the Tongxin mine results in the stress concentration in the rock of the Carboniferous coal bed and accumulation of a large amount of elastic energy and forms structural background of Tongxin mine. Due to various seismic activities in the mine area, the strain energy is known to reach much higher levels, up to 0.5×10⁸ J^1/2. Since the stratigraphic structure is sensitive to the mining operation, the strain energy could cause strong strata behaviors. A special geological structure model of the Tongxin mine is established based on the geodynamic division method. The distribution of regional structure stress field is determined by the rock mass stress analysis system. Based on this model, Tongxin mine is divided into five areas with high stress, eight areas with low stress and eight areas with gradient stress. The strong strata behaviors mostly occur in high stress areas. These results could provide guidance to predict the strength of regional or mine pressure and control strata behavior in different areas.     

A new landslide-induced tsunami simulation model and its application to the 1792 Unzen-Mayuyama landslide-and-tsunami disaster

By combining landslide dynamics research and tsunami research, we present an integrated series of numerical models quantitatively simulating the complete evolution of a landslide-induced tsunami. The integrated model simulating the landslide initiation and motion uses measured landslide dynamic parameters from a high-stress undrained dynamic-loading ring shear apparatus. It provides the numerical data of a landslide mass entering and moving under water to the tsunami simulation model as the trigger of tsunami. The series of landslide and tsunami simulation models were applied to the 1792 Unzen-Mayuyama megaslide and the ensuing tsunami disaster, which is the largest landslide disaster, the largest volcanic disaster, and the largest landslide-induced tsunami disaster to have occurred in Japan. Both the 1792 megaslide and the tsunami portions of the disaster are well documented, making this an excellent test of the reliability and precision of the new simulation model. The simulated tsunami heights at the coasts well match the historical tsunami heights recorded by “Tsunami-Dome-Ishi” (a stone showing the tsunami reaching point) and memorial stone pillars.     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

硫酸镁对仿刺参幼参麻醉效果的研究

本研究以硫酸镁作为麻醉剂,比较了在不同水温条件下硫酸镁对仿刺参幼参的麻醉效果,分析了不同浓度硫酸镁对仿刺参幼参的麻醉效果。实验水温设置11℃、13℃、15℃、17℃、19℃和21℃六个温度梯度,实验用仿刺参幼参规格分为大规格(L)40.26±1.84g、中规格(M)21.83±1.72g、小规格(S)11.03±1.63g。实验结果显示:1.在硫酸镁麻醉剂浓度相同时,仿刺参规格越大麻醉所需时间越长,复苏时间却越短;随着麻醉剂浓度增加,对仿刺参幼参麻醉时间相应缩短,但复苏时间呈现逐渐延长。不同浓度硫酸镁麻醉剂对不同规格仿刺参的麻醉效果具有显著差异(P0.05)。2.在水温11℃~20℃范围内,随着水温的升高,对仿刺参幼参的麻醉时间从26.13±17.78min缩短到21.47±3.52min,但复苏时间从26.13±17.78min增加到71.05±12.32min,不同水温条件下硫酸镁对仿刺参幼参麻醉效果影响显著(P0.05)。研究表明,仿刺参体重在20g以下的适宜麻醉浓度为0.1~0.25mol·L-1,体重在20g以上的适宜麻醉浓度为0.25~0.35mol·L~(-1)。     

全珊瑚骨料海水混凝土力学性能试验研究

为了探讨全珊瑚骨料海水混凝土的基本力学性能,并比较其与普通混凝土和轻集料混凝土的差异,通过实验系统测定了珊瑚混凝土的基本力学性能,建立了其轴心抗压强度(f_(c,m))、劈裂抗拉强度(f_(sp,m))、抗折强度(f_(t,m))与立方体抗压强度(f_(cu,m))之间的线性关系与计算公式。结果表明:在强度等级C20~C50的范围内,珊瑚混凝土的f_(c,m)和f_(sp,m)分别比普通混凝土的f_(c,m)和f_(sp,m)高出10%~48%和9%~33%,随着强度等级的提高,两种混凝土之间的差距在减小。珊瑚混凝土的f_(t,m)与普通混凝土的ft,m之间的差异规律与强度等级有关,较低强度等级的C30珊瑚混凝土ft,m比普通混凝土的f_(t,m)要高4%,而较高强度等级的C55珊瑚混凝土f_(t,m)比普通混凝土的f_(t,m)低13%。较高强度等级的C50珊瑚混凝土f_(c,m)、f_(sp,m)和f_(t,m)分别比页岩陶粒轻集料混凝土的f_(c,m)、f_(sp,m)和f_(t,m)低11%、0.9%和4%。