Lahnsteinite, Zn4(SO4)(OH)6 · 3H2O, a new mineral from the Friedrichssegen Mine, Germany

A new mineral, lahnsteinite, has been found in the dump of the Friedrichssegen Mine, Bad Ems district, Rhineland-Palatinate (Rheinland-Pfalz), Germany. Lahnsteinite, occurring as colorless tabular crystals in the cavities of goethite, is associated with pyromorphite, hydrozincite, quartz, and native copper. The Mohs’ hardness is 1.5; the cleavage is perfect parallel to (001). D _calc = 2.995 g/cm³, D _meas = 2.98(2) g/cm³. The IR spectrum is given. The new mineral is optically biaxial, negative, α = 1.568(2), β = 1.612(2), γ = 1.613(2), 2V _meas = 18(3)°, 2V _calc = 17°. The chemical composition (wt %, electron microprobe data; H₂O was determined by gas chromatography of ignition products) is as follows: 3.87 FeO, 1.68 CuO, 57.85 ZnO, 15.83 SO₃, 22.3 H₂O, total is 101.53. The empirical formula is (Zn_3.3Fe_0.27Cu_0.11)_Σ3.91(S_0.98O₄)(OH)₅ · 3H_2.10O. The crystal structure has been studied on a single crystal. Lahnsteinite is triclinic, space group P1, a = 8.3125(6), b = 14.545(1), c = 18.504(2) Å, α = 89.71(1), β = 90.05(1), γ = 90.13(1)°, V = 2237.2(3) ų, Z = 8. The strong reflections in the X-ray powder diffraction pattern [d, Å (I, %)] are: 9.30 (100), 4.175 (18), 3.476 (19), 3.290 (19), 2.723 (57), 2.624 (36), 2.503 (35), 1.574 (23). The mineral has been named after its type locality near the town of Lahnstein. The type specimen of lahnsteinite is deposited in the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, registration number 4252/1.     

Structure of magnetite lodes at the Estyunino iron deposit in the central Urals

The structure of magnetite lodes is determined by iron and sulfur distribution, as well as texture and structure of ore. These features have been revealed by documentation of cores from ore intervals in exploration boreholes penetrating two main lodes 21 and 22 of the Estyunino iron deposit. The documentation of cores was accompanied by sampling for microscopic examination of texture and structure of ore and selection of Fe and S contents in ore. Then these data were summarized as sections of the lodes. It was established that the structure of magnetite lodes is characterized by conformable ore layers distinguished by texture, structure, and Fe and S contents. Banded and spotty ores containing less than 50% magnetite are predominant. Layers of homogeneous massive ore are infrequent. The textural pattern indicates a volcaniclastic nature of host rocks. The spotty texture is characteristic of hyaloclastites with vitreous shards. The banded texture with oriented distribution of fiamme is inherent to volcaniclastic rocks. In both cases, magnetite selectively replaces dark-colored vitreous fragments and is also dispersed in the salic matrix and lava fragments. No indications of crosscutting superposed relationships are observed. The available data can be satisfactorily explained by an impregnation-metasomatic mode of ore deposition.     

Application of the photoacoustic method for characterization of natural galena (PbS)

Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D _T≈0.16 × 10^?5 m² s^?1), the coefficient of diffusion (D between 0.15×10^?2 0.16×10^?2 m² s^?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s _g≈65.5 m s^?1 and s _b≈66.4 m s^?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×10¹⁸ cm^?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed.     

Eduard Suess' relations to the Pre-1950 schools of thought in global tectonics

Two main schools of thought in global tectonics are recognized during the first half of the XXth century on the basis of their proponents' attitude towards the principle of uniformitarianism and their belief in an inherent order and regularity vs. disorder and irregularity in tectonics. One group, here called the Wegener-Argand school, had a unifomitarian approach to global tectonics and believed in an inherently irregular Nature, in which probability rather than determinism was believed to be a realistic approach. The other, here called the Kober-Stille school, was largely non-uniformitarian (neocatastrophist) and believed in an orderly, regular Nature. These two schools correspond to Argand's mobilists and fixists respectively. In this paper I show that Eduard Suess was a convinced uniformitarian as far as his views on global tectonics are concerned and denied any inherent regularity in tectonic phenomena, temporal or spatial. In his interpretations of the causes and nature of orogeny, nature of geosynclines, and causes and nature of stabilisation, Suess appears to be the predecessor of the Wegener-Argandians, i. e. of the mobilists and not of the Kober-Stilleans as hitherto assumed. Although he remained a fixist and contractionist to the end Suess seems to have paved the way for the mobilists much as he did for the nappists during the last quarter of the XIX^th century.

---

Zusammenfassung Während der ersten Hälfte des XX. Jahrhunderts kann man zwei globaltektonische Denkungsweisen oder Großschulen unterscheiden, die gekennzeichnet sind durch ihre Stellungnahme zum aktualistischen Prinzip in der Tektonik und ob sie an eine ordentliche und regelmäßige Natur glaubten oder nicht. Die erste, hier die Wegener-Argand-Schule genannt, hatte die Gültigkeit des aktualistischen Prinzips in der Tektonik anerkannt und die Natur, im Grunde genommen, als unordentlich und unregelmäßig betrachtet. Die Anhänger dieser Denkweise glaubten, daß probablistische Lösungen tektonischer Probleme realistischer seien als deterministische. Die andere Großschule, hier die Kober-Stille-Schule genannt, war im Grunde genommen anti-aktualistisch (Neo-Katastrophistisch) und glaubte, daß die Natur ordentlich und regelmäßig sei. Diese zwei Schulen entsprechen Argands' Einteilung in Mobilisten und Fixisten. In diesem Artikel zeige ich, daß E. Suess ein überzeugter Aktualist in bezug auf seine tektonischen Ansichten war, und daß er jede Regelmäßigkeit, zeitlicher oder räumlicher Art, der tektonischen Ereignisse ablehnte. In seinen Interpretationen der Ursachen und der Art der Orogenese, der Art der Geosynklinalen und der Ursache und der Art der Erstarrung, erscheint Suess als ein Vorgänger der Wegener-Argand-Schule, d. h. der Mobilisten, deren Gedankengänge er viel näher stand als dem der Kober-Stille-Schule. Obwohl Suess selbst bis zuletzt ein Fixist und Kontraktionist blieb, bereitete er eigentlich den Weg für die Mobilisten, wie er es früher auch für die Nappisten getan hatte.

---

Résumé Durant la première moitié du XX^e siêcle, on peut distinguer deux principales écoles de pensée en tectonique globale, selon l'attitude de ses adhérents envers le principe de l'actualisme et selon leur croyance ou non à un ordre et une régularité intrinsèques en tectonique. Le premier groupe, ici appelé l'école de Wegener-Argand, suivit une voie actualiste et crût la Nature essentiellement irrégulière, de telle sorte qu'un traitement probabiliste fût considéré plus réaliste qu'un traitement déterministe. L'autre, appelé ici l'école de Kober-Stille, était essentiellement non-actualiste (néo-catastrophiste) et crût à une Nature ordonnée, régulière. Ces deux écoles correspondent aux mobilistes et aux fixistes d'Argand. Dans cet article, je montre que E. Suess, fût un actualiste convaincu, du moins en ce qui concerne ses opinions sur la tectonique globale, et qu'il rejetta toute notion de régularité dans les phénomènes tectoniques, autant spatiaux que temporaux. Dans ses interprétations des causes et de la nature de l'orogenèse, de la nature des géosynclinaux, et des causes et de la nature de la «stabilisation», Suess est un des précurseurs des «Wegener-Argandiens», c'est à dire des mobilistes. Bien qui'il fût demeuré, jusqu'à la fin de sa vie, fixiste et un avocat de la contraction, il semble que Suess ait préparé la voie aux mobilistes, de la mème façon qu'il l'avait fait pour les nappistes pendant le derier quart du XIX^e siècle.

---

20- , , , . , -, , . , , . , -, (- ) , . , , . , 3 , . , 3 ee-, . . , -; , , .

     

IR photometry and dust-shell models for two carbon stars

We present JHKLM photometry of the carbon stars ST And and T Lyn acquired in 2000–2010. Along with brightness variations due to pulsations, changes on timescales of 2000–3000 days are also observed. Our combined light curves can be satisfactorily represented with light elements derived from visual observations, but the maxima are delayed relative to the calculated times. A color-index analysis demonstrates that the dust shell of ST And is fairly weak, and is manifest only episodically, while the presence of hot dust was always detected for T Lyn. These results confirm models of spherically symmetric stellar dust shells based on mean-flux data, supplemented with observations in the intermediate IR from the IRAS and AKARI satellites. The visual optical depth of the relatively cool dust shell of ST And assuming a dust temperature at the inner edge of T ₁ = 510 K is very low: τ _V = 0.047. The dust shell of T Lyn is considerably hotter (T ₁ = 940 K), with τ _V = 0.95. We estimate the mass-loss rate to be 1.8 × 10⁻⁷ M _⊙/year for ST And and 3.7 × 10⁻⁷ M _⊙/year for T Lyn.     

New observations of anomalous X-ray pulsars at low frequencies

We report the results of new observations of three anomalous X-ray pulsars: 1E 2259+586, 4U 0142+61, and XTE J1810-197. The observations were carried out on high-sensitivity radio telescopes of the Pushchino Radio Astronomy Observatory: the Large Phased Array at 111MHz and the DKR-1000 at 62 MHz. New, digital, multi-channel receivers designed for pulsar observations were used. Pulse profiles and dynamical spectra for the three pulsars are presented. The mean flux density for XTE J1810-197 is estimated to be ∼160 mJy at 62 MHz. An estimated spectral index for this pulsar is also presented.     

A Raman spectroscopic study on the structural disorder of monazite–(Ce)

This study addresses whether Raman spectra can be used to estimate the degree of accumulated radiation damage in monazite-(Ce) samples whose chemical composition was previously determined. Our results indicate that the degree of disorder in monazite–(Ce), as observed from increasing Raman band broadening, generally depends on both the structural state (i.e., radiation damage) and the chemical composition (i.e., incorporation of non-formula elements). The chemical effects were studied on synthetic orthophosphates grown using the Li-Mo flux method, and non radiation-damaged analogues of the naturally radiation-damaged monazite–(Ce) samples, produced by dry annealing. We found that the “chemical” Raman-band broadening of natural monazite–(Ce) can be predicted by the empirical formula, $$ {\hbox{FWHM}} {\hbox{[c}}{{\hbox{m}}^{ - {1}}}{]} = {3}{.95} + {26}{.66} \times {\hbox{(Th}} + {\hbox{U}} + {\hbox{Ca}} + {\hbox{Pb)}} {\hbox{[apfu]}} $$ where, FWHM = full width at half maximum of the main Raman band of monazite–(Ce) (i.e., the symmetric PO₄ stretching near 970?cm^?1), and (Th+U+Ca+Pb) = sum of the four elements in apfu (atoms per formula unit). Provided the chemical composition of a natural monazite–(Ce) is known, this “chemical band broadening” can be used to estimate the degree of structural radiation damage from the observed FWHM of the ν₁(PO₄) band of that particular sample using Raman spectroscopy. Our annealing studies on a wide range of monazite–(Ce) reference materials and other monazite–(Ce) samples confirmed that this mineral virtually never becomes highly radiation damaged. Potential advantages and the practical use of the proposed method in the Earth sciences are discussed.     

Deciphering the Variscan tectonothermal overprint and deformation partitioning in the Cadomian basement of the Teplá–Barrandian unit, Bohemian Massif

The Teplá–Barrandian unit (TBU) has long been considered as a simply bivergent supracrustal ‘median massif’ above the Saxothuringian subduction zone in the Variscan orogenic belt. This contribution reveals a much more complex style of the Variscan tectonometamorphic overprint and resulting architecture of the Neoproterozoic basement of the TBU. For the first time, we describe the crustal-scale NE–SW-trending dextral transpressional Krakovec shear zone (KSZ) that intersects the TBU and thrusts its higher grade northwestern portion severely reworked by Variscan deformation over a southeastern very low grade portion with well-preserved Cadomian structures and only brittle Variscan deformation. The age of movements along the KSZ is inferred as Late Devonian (~380–370?Ma). On the basis of structural, microstructural, and anisotropy of magnetic susceptibility data from the KSZ, we propose a new synthetic model for the deformation partitioning in the Teplá–Barrandian upper crust in response to the Late Devonian to early Carboniferous subduction and underthrusting of the Saxothuringan lithosphere. We conclude that the Saxothuringian/Teplá–Barrandian convergence was nearly frontal during ~380–346?Ma and was partitioned into pure shear dominated domains that accommodated orogen-perpendicular shortening alternating with orogen-parallel high-strain domains that accommodated dextral transpression or bilateral extrusion. The synconvergent shortening of the TBU was terminated by a rapid gravity-driven collapse of the thickened lithosphere at ~346–337?Ma followed by, or partly simultaneous with, dextral strike-slip along the Baltica margin-parallel zones, driven by the westward movement of Gondwana from approximately 345?Ma onwards.     

Ore belts of the Greater Altai and their ore resource potential

The results of comprehensive geological and metallogenic studies of the Greater Altai are presented. This project has been carried out since 1997 under the guidance of Academician G.N. Shcherba. The importance of these investigations is determined by the need to enhance and further develop mineral resources of nonferrous, noble, rare, and other metals for operating mining and metallurgical enterprises of Kazakhstan. The great body of information on the geology, geophysics, and metallogeny of the region obtained over many years has been integrated on the basis of new global tectonics. The Greater Altai embraces the Hercynides of the Rudny Altai, Qalba-Narym, West Qalba, Zharma-Saur, and the adjacent territories of Russia and China. The present-day tectonic units are considered to be detached blocks of ancient continental massifs that drifted in the Paleoasian ocean and then amalgamated into the structure of the Greater Altai during the Hercynian collision. The tectonic and metallogenic demarcation of the studied territory made possible the recognition of the Rudny Altai, Qalba-Narym, West Qalba, and Zharma-Saur ore belts, different in geology, geodynamic evolution, and metallogeny. The formation conditions and localization of volcanic-hosted massive sulfide, gold, and rare-metal deposits pertaining to certain ore-bearing geochronological levels were specified, and the potential of the region for various mineral resources was estimated.