冬小麦遥感冠层温度监测土壤含水量的试验研究

在冬小麦主要生育期(2002年4月初到5月底),对不灌溉的冬小麦测定了冠层温度、地温、气温以及土壤含水量,计算了冠气温差且分析了冠层温度和冠气温差与不同土层厚度的土壤含水量相关关系。结果表明:14:00的冠层温度能较好地反映20cm土层的土壤含水量变化,但与其它各土层相关性有较大的波动性;14:00的冠气温差能较好地反映40cm以上土层的土壤含水量变化,二者的相关性很高,在20cm、40cm土层,两者相关系数R2分别为0.98866、0.99389,这为用区域遥感数据反演主要生育期冬小麦的冠气温差进而监测区域40cm土壤含水量提供了实验性的依据;拔节期和灌浆期,用14:00冠气温差来拟合各土壤层的土壤含水量有较高的精度,从而为用区域遥感数据监测区域土壤含水量提供了经验性的模型。     

Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Rare earth elements in the clay fraction of coaliferous sediments of the Arkagalinskoe (Magadan district) and Dolinskoe (Sakhalin Island) coalfields

The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.     

A 2D finite volume model for bebris flow and its application to events occurred in the Eastern Pyrenees

FLATModel is a 2D finite volume code that contains several original approaches to improve debris-flow simulation. Firstly, FLATModel incorporates a ＂stop-and-go＂ technique in each cell to allow continuous collapses and remobilizations of the debris-flow mass. Secondly, flow velocity and consequently yield stress is directly associated with the type of rheology to improve boundary accuracy. Thirdly, a simple approach for entrainment is also included in the model to analyse the effect of basal erosion of debris flows. FLATMODEL was tested at several events that occurred in the Eastern Pyrenees and simulation results indicated that the model can represent rather well the different characteristics observed in the field.     

Rock-weathering rates as functions of time

The scarcity of documented numerical relations between rock weathering and time has led to a common assumption that rates of weathering are linear. This assumption has been strengthened by studies that have calculated long-term average rates. However, little theoretical or empirical evidence exists to support linear rates for most chemical-weathering processes, with the exception of congruent dissolution processes. The few previous studies of rock-weathering rates that contain quantitative documentation of the relation between chemical weathering and time suggest that the rates of most weathering processes decrease with time. Recent studies of weathering rinds on basaltic and andesitic stones in glacial deposits in the western United States also clearly demonstrate that rock-weathering processes slow with time. Some weathering processes appear to conform to exponential functions of time, such as the square-root time function for hydration of volcanic glass, which conforms to the theoretical predictions of diffusion kinetics. However, weathering of mineralogically heterogeneous rocks involves complex physical and chemical processes that generally can be expressed only empirically, commonly by way of logarithmic time functions. Incongruent dissolution and other weathering processes produce residues, which are commonly used as measures of weathering. These residues appear to slow movement of water to unaltered material and impede chemical transport away from it. If weathering residues impede weathering processes then rates of weathering and rates of residue production are inversely proportional to some function of the residue thickness. This results in simple mathematical analogs for weathering that imply nonlinear time functions. The rate of weathering becomes constant only when an equilibrium thickness of the residue is reached. Because weathering residues are relatively stable chemically, and because physical removal of residues below the ground surface is slight, many weathering features require considerable time to reach constant rates of change. For weathering rinds on volcanic stones in the western United States, this time is at least 0.5 my.     

On the eigenvalues of kinematic α-effect dynamos

The kinematic α-effect dynamo problem is investigated in the case of an exterior perfect conductor. It is shown that certain approximate symmetries discovered in the numerical analysis of ROBERTS (1972) are exact for this case. As an illustration, an exact solution is given in a cylindrical geometry, where the equations can be written in terms of one variable. The implications for the earth's dynamo are discussed.     

A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...