Isotopic order, biogeochemical processes, and earth history: Goldschmidt lecture, Davos, Switzerland, August 2002

The impetus to interpret carbon isotopic signals comes from an understanding of isotopic fractionations imposed by living organisms. That understanding rests in turn on studies of enzymatic isotope effects, on fruitful concepts of isotopic order, and on studies of the distribution of ¹³C both between and within biosynthetic products. In sum, these studies have shown that the isotopic compositions of biological products are governed by reaction kinetics and by pathways of carbon flow.Isotopic compositions of individual compounds can indicate specific processes or environments. Examples include biomarkers which record the isotopic compositions of primary products in aquatic communities, which indicate that certain bacteria have used methane as a carbon source, and which show that some portions of marine photic zones have been anaerobic. In such studies, the combination of structural and isotopic lines of evidence reveals relationships between compounds and leads to process-related thinking. These are large steps. Reconstruction of the sources and histories of molecular fossils redeems much of the early promise of organic geochemistry by resolving and clarifying paleoenviron-mental signals. In turn, contemplation of this new information is driving geochemists to study microbial ecology and evolution, oceanography, and sedimentology.     

A constrained 2D gravity model of the Sebastián Vizcaíno Basin, Baja California Sur, Mexico

The subsurface geometry of the Sebastián Vizcaíno Basin is obtained from the 2D inversion of gravity data, constrained by a density-versus-depth relationship derived from an oil exploration deep hole. The basin accumulated a thick pile of marine sediments that evolved in the fore-arc region of the compressive margin prevalent along western North America during Mesozoic and Tertiary times. Our interpretation indicates that the sedimentary infill in the Sebastián Vizcaíno Basin reaches a maximum thickness of about 4 km at the centre of a relatively symmetric basin. At the location of the Suaro-1 hole, the depth to the basement derived from this work agrees with the drilled interface between calcareous and volcaniclastic members of the Alisitos Formation. A sensitivity analysis strongly suggests that the assumed density function leads to a nearly unique solution of the inverse problem.     

The radio luminosity function and the luminosity diameter function of extragalactic radio sources

On the basis of a radio index-surface brightness diagram recently published, the luminosity function and the luminosity diameter function are obtained. The uncertainties due to the incompleteness of the sample are of the same order as the statistical uncertainties. The luminosity function differs considerably from a simple power law and supports the distinction of two populations. The density of the weak population (P<10³⁵ W Hz⁻¹ ster⁻¹ at 1400 MHz) follows nearly a power law in P and increases towards small diameters at least down to I kpc. The density of the strong population (the high luminosity and small diameter part of which is occupied by the quasars) has a maximum between 10²⁵ and 10²⁸ W Hz⁻¹ ster⁻¹ and around 100 kpc. A strong evolution effect is clearly present and is in a good agreement with the models obtained from the log N-log S counts.     

Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Rare earth elements in the clay fraction of coaliferous sediments of the Arkagalinskoe (Magadan district) and Dolinskoe (Sakhalin Island) coalfields

The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.