Chemical composition of Russian Arctic precipitation in 2007-2015

The results of observations of the chemical composition of precipitation in the Russian Arctic in 2007-2015 are summarized including the data from NP-35 drifting ice station obtained in 2007-2008 in the framework of the joint program of Arctic and Antarctic Research Institute and Voeikov Main Geophysical Observatory. The qualitative and quantitative difference in the chemical composition of precipitation in the Atlantic, Siberian, and Pacific sectors of the Russian Arctic is revealed. It is found that the concentration of microelements (heavy metals) in precipitation at NP-35 ice station did not exceed 12% of total ions at the lowest mineralization. The comparative analysis is presented of the concentration of sulfate ions in precipitation in Norilsk and at NP-35 ice stations.     

The temple of apollo (Delphi) strengthens novel thermoluminescence dating method

The temple of Apollo in Delphi (Greece), built in 550 B.C., has been used to reconfirm a novel method of dating carved megalithic stone buildings using thermoluminescence (TL) (Liritzis, 1994). A calcitic (marble) sample was taken from the western side of the well-known inscribed polygonal wall, which constitutes the southern external support foundations of the temple. A partially bleached TL methodology was devised to determine first the ancient residual TL and then the correct archaeological dose. The obtained TL age of 420 ± 300 B.C. is compatible, within the margin of error, with the archaeological age. © 1997 John Wiley & Sons, Inc.     

Controlling factors of the δ 11B-pH proxy and its research direction

Significant boron isotope fractionation occurs in nature (?70 ‰ to +75 ‰) due to the high geochemical reactivity of boron and the large relative mass difference between ¹⁰B and ¹¹B. Since the 1990s, reconstruction of ancient seawater pH using the isotopic composition of boron in bio-carbonates (δ ¹¹B_carb), and then calculation of the past pCO₂ have become important issues for the international isotope geochemistry community, and are called the δ ¹¹B-pH proxy. Although many achievements have been made by this proxy, various aspects of boron systematics require rigorous evaluation. Based on the previous researches, mechanism of boron isotope fractionation, variation of boron isotope (δ ¹¹B) in nature (especially in bio-carbonates) and controlling factors of the δ ¹¹B-pH proxy, such as the dissociation constant of B(OH)₃ in seawater (pK_a), the δ ¹¹B of seawater (δ ¹¹B_SW), the boron isotopic fractionation factor between B(OH) ₄ ^? and B(OH)₃ (α _4–3), and the incorporated species of boron into bio-carbonates, are reviewed in detail and the research directions of this proxy are proposed. Generally, the controversy about pK_a, δ ¹¹B_sw, and α _4–3 is relatively less, but whether boron incorporated into bio-carbonates only in the form of B(OH) ₄ ^? remains doubtful. In the future, it is required that the physicochemical processes that control boron incorporation into carbonates be rigorously characterized and that the related chemical and isotopic fractionation be quantified. It is also necessary and important to establish a “best-fit empirically equation” between δ ¹¹B_carb and pH of seawater based on the precipitation experiments of inorganic or culture experiments of corals or foraminifera. In addition, extended application of the δ ¹¹B-pH proxy to the earlier part of the Phanerozoic relying on the Brachiopods is worthy of studying. Like other geochemical indicators, there are limiting factors of δ ¹¹B; however, it remains a very powerful tool in the reconstruction of past seawater pH at present.     

On the atomic constants of ReI

We have experimentally studied the excitation of the rhenium atom by collisions with slow monoenergetic electrons and measured 47 excitational cross sections for lines of ReI at an electron energy of 50 eV. Previously published information about the probabilities of radiative transitions of ReI is analyzed. The data for two experimental studies of the ratios Iλ/gA for transitions with a common upper level differ by three orders of magnitude.     

Experimental evaluation of biases associated with sampling estuarine fishes with seines

Beach seines are widely used to estimate the density and species richness of fishes in estuaries. We evaluated the causes and extent of bias in estimates from seines using a series of field experiments in small estuaries in southern California, USA. Seining in spatially paired areas that were either enclosed by block nets or not, revealed that seines used without block nets und erestimated density by more than 4-fold and species richness by more than 2-fold relative to blocked areas. Seining in paired blocked areas with seines of two lengths revealed that net length affected estimates of density, but not species richness; a 7.6-m long seine produced 1.6-fold higher estimates of total density than did a 15.2-m long seine due to increased catches of demersal fishes, but not midwater species. Paired sampling in blocked areas also revealed that many fishes initially evaded capture by the seine. Estimates of density but not species richness were significantly higher in areas through which a seine was swept 5 times compared to once. This was due to higher catches of demersal fishes but not midwater fishes in areas seined 5 times. Repeated seining through blocked areas revealed that the vast majority (90% or more) of species and individuals of midwater fishes were captured within the first 5 sweeps, compared to only about 50% of the individuals of demersal species. A mark-recapture study in blocked areas revealed lower probabilities of capture for demersal species relative to midwater species.     

Evaluation of significant sources influencing the variation of physico-chemical parameters in Port Blair Bay,South Andaman,India by using multivariate statistics

Port Blair is the capital city of Andaman & Nicobar Islands, the union territory of India. More than 50% of the population of these islands lives around Port Blair Bay. Therefore the anthropogenic effects in the bay water were studied for monitoring purpose from seven stations. Physico-chemical parameters of seawater were analyzed in samples collected once in every 3 months for 2 years from seven sampling stations located in Port Blair Bay, South Andaman Island to evaluate the spatial and tidal variation. Cluster analysis and factor analysis were applied to the experimental data in an attempt to understand the sources of variation of physico-chemical parameters. In cluster analysis, the stations Junglighat Bay and Phoenix Bay having high anthropogenic influence formed a separate group. The factors obtained from factor analysis indicated that the parameters responsible for physico-chemical variations are mainly related to land run-off, sewage outfall and tidal flow.     

Application of Hilbert‐like transforms for enhanced processing of full tensor magnetic gradient data

Commonly, geomagnetic prospection is performed via scalar magnetometers that measure values of the total magnetic intensity. Recent developments of superconducting quantum interference devices have led to their integration in full tensor magnetic gradiometry systems consisting of planar‐type first‐order gradiometers and magnetometers fabricated in thin‐film technology. With these systems measuring directly the magnetic gradient tensor and field vector, a significantly higher magnetic and spatial resolution of the magnetic maps is yield than those produced via conventional magnetometers. In order to preserve the high data quality in this work, we develop a workflow containing all the necessary steps for generating the gradient tensor and field vector quantities from the raw measurement data up to their integration into high­resolution, low­noise, and artefactless two‐dimensional maps of the magnetic field vector. The gradient tensor components are processed by superposition of the balanced gradiometer signals and rotation into an Earth‐centred Earth‐fixed coordinate frame. As the magnetometers have sensitivity lower than that of gradiometers and the total magnetic intensity is not directly recorded, we employ Hilbert‐like transforms, e.g., integration of the gradient tensor components or the conversion of the total magnetic intensity derived by calibrated magnetometer readings to obtain these values. This can lead to a better interpretation of the measured magnetic anomalies of the Earth's magnetic field that is possible from scalar total magnetic intensity measurements. Our conclusions are drawn from the application of these algorithms on a survey acquired in South Africa containing full tensor magnetic gradiometry data.     

Paleoclimatic implications of glacial and postglacial refugia for Pinus pumila in western Beringia

Palynological results from Julietta Lake currently provide the most direct evidence to support the existence of a glacial refugium for Pinus pumila in mountains of southwestern Beringia. Both percentages and accumulation rates indicate the evergreen shrub survived until at least ∼ 19,000 ¹⁴C yr BP in the Upper Kolyma region. Percentage data suggest numbers dwindled into the late glaciation, whereas pollen accumulation rates point towards a more rapid demise shortly after ∼ 19,000 ¹⁴C yr BP. Pinus pumila did not re-establish in any great numbers until ∼ 8100 ¹⁴C yr BP, despite the local presence ∼ 9800 ¹⁴C yr BP of Larixdahurica, which shares similar summer temperature requirements. The postglacial thermal maximum (in Beringia ∼ 11,000-9000 ¹⁴C yr BP) provided Pinus pumila shrubs with equally harsh albeit different conditions for survival than those present during the LGM. Regional records indicate that in this time of maximum warmth Pinus pumila likely sheltered in a second, lower-elevation refugium. Paleoclimatic models and modern ecology suggest that shifts in the nature of seasonal transitions and not only seasonal extremes have played important roles in the history of Pinus pumila over the last ∼ 21,000 ¹⁴C yr BP.