东印度洋水体输运的季节变化及相关盐度变化

利用20年（1992-2012年）的ECCO2模式模拟数据,主要研究了东印度洋（EIO）水体输运的季节变化.在EIO选取3个断面,分别为赤道、80°E和6°N.研究结果表明,跨赤道和80°E的季节输运主体部分大致相补偿.跨赤道的大部分水体输运局限在上层100 m,80°E的水体输运具有复杂结构,与显著的季风流、Wyrtki Jets（WJs）、赤道潜流（EUC）等有关.6°N上层水体净输运较小,但存在较强的边界流和相对较弱的内区流.纬向流的显著变化发生在80°E.在季风盛行季节,由于WJs减弱,赤道附近的水体输运以西向的梯度流为主,上层100 m的其余区域则主要受季风流控制.同样,由于EUC减弱,西向的梯度流与次表层东向的EUC之间也存在转换.在季风转换季节,季风流减弱,WJs与EUC分别在上层100 m和次表层占主导地位.此外,本研究还讨论了与季风流、WJs和EUC相关的盐水和暖水交换,有助于了解研究区域内温度和盐度的水平和垂直结构.     

On the Retrieval of Volcanic Sulfur Dioxide Emissions from GOME Backscatter Measurements

We focus on the retrieval of volcanic sulfur dioxide (SO₂) emissions from an analysis of atmospheric UV backscatter spectra obtained by the Global Ozone Monitoring Experiment (GOME) spectrometer on board the ESA European Remote Sensing Satellite (ERS-2). Here, the last major eruptions of Mt. Etna on Sicily (Italy) in July/August 2001 and October/November 2002 provided an excellent opportunity to study the retrieval of SO₂ columnar amounts from ground-based, LIDAR and satellite measurements. Our study shows that the bulk of emitted SO₂ was confined in the troposphere, mainly between 700 hPa and 400 hPa which is confirmed by trajectory analysis, by LIDAR observations and AVHRR observations. The area of influence of Mt. Etna eruptions ranges from the Western Saharan Desert to Greece and the near east states and even down to the basin of Tschad, Africa. Our analysis revealed that information about the plume height of volcanic eruptions and aerosol parameters is necessary for a reliable quantitative retrieval of SO₂ from space-borne sensor data at periods perturbed by volcanic eruptions.     

The Use of Geographically Weighted Regression for Spatial Prediction: An Evaluation of Models Using Simulated Data Sets

Increasingly, the geographically weighted regression (GWR) model is being used for spatial prediction rather than for inference. Our study compares GWR as a predictor to (a) its global counterpart of multiple linear regression (MLR); (b) traditional geostatistical models such as ordinary kriging (OK) and universal kriging (UK), with MLR as a mean component; and (c) hybrids, where kriging models are specified with GWR as a mean component. For this purpose, we test the performance of each model on data simulated with differing levels of spatial heterogeneity (with respect to data relationships in the mean process) and spatial autocorrelation (in the residual process). Our results demonstrate that kriging (in a UK form) should be the preferred predictor, reflecting its optimal statistical properties. However the GWR-kriging hybrids perform with merit and, as such, a predictor of this form may provide a worthy alternative to UK for particular (non-stationary relationship) situations when UK models cannot be reliably calibrated. GWR predictors tend to perform more poorly than their more complex GWR-kriging counterparts, but both GWR-based models are useful in that they provide extra information on the spatial processes generating the data that are being predicted.     

Electronic environments in carrollite, CuCo2S4, determined by soft X-ray photoelectron and absorption spectroscopy

Fracture surfaces of a natural carrollite specimen have been characterised by synchrotron and conventional X-ray photoelectron spectroscopy and near-edge X-ray absorption spectroscopy. For the synchrotron X-ray measurements, the mineral surfaces were prepared under clean ultra high vacuum and were unoxidised. The characterisation was undertaken primarily to establish unequivocally the oxidation state of the Cu in the mineral, but also to obtain information on the electronic environments of the Co and S, and on the surface species. Experimental and simulated Cu L_2,3-edge absorption spectra confirmed an oxidation state of Cu^I, while Co 2p photoelectron and Co L_2,3 absorption spectra were largely consistent with the Co^III established previously by nuclear magnetic resonance spectroscopy. S 2p photoelectron spectra provided no evidence for S to be present in the bulk in more than one state, and were consistent with an oxidation state slightly less negative than S^-II. Therefore it was concluded that carrollite can be best represented by Cu^ICo^III₂(S₄)^-VII. The Cu^I oxidation state is in agreement with that expected for Cu tetrahedrally coordinated by S, but is in disagreement with the Cu^II deduced previously from some magnetic, magnetic resonance and Cu L-edge X-ray absorption spectroscopic measurements. A significant concentration of S species with core electron binding energies both lower and higher than the bulk value were formed at fracture surfaces, and these entities were assigned to monomeric and oligomeric surface S species. The density of Cu d states calculated for carrollite differed from that previously reported but was consistent with the observed Cu L₃ X-ray absorption spectrum. The initial oxidation of carrollite in air under ambient conditions was confirmed to be congruent, unlike the incongruent reaction undergone by a number of non-thiospinel sulfide minerals.     

Changing patterns of population distribution in Zimbabwe

This paper critically evaluates the causes and consequences of changes in population distribution in Zimbabwe during the colonial period and since independence in 1980. Five main aspects of population geography are examined. Firstly, by way on background on contemporary patterns of settlement and land use, the history of tenure policies is outlined. Secondly, the distribution of the African population as revealed in the 1982 census is described and major changes between the census years of 1962, 1969 and 1982 are discussed. Thirdly, changing patterns of settlement and land use within the peasant farming areas (Communal Lands) are examined in the context of increasing population pressures. Fourthly, trends in the growth of the main urban centres and the process of urbanisation of the African population are described. Fifthly, post-independence development policies directed at effecting changes in the distribution of population are discussed with particular reference to the land resettlement programme. The present distribution of population is seen as the product of interacting political, economic and environmental factors, knowledge of which is essential in devising appropriate development strategies to achieve a more equable balance of population and resources.