Characterization of deep saline aquifers in the Bécancour area,St. Lawrence Lowlands,Québec,Canada: implications for CO2 geological storage

The present paper provides a case study of the assessment of the potential for CO₂ storage in the deep saline aquifers of the Bécancour region in southern Québec. This assessment was based on a hydrogeological and petrophysical characterization using existing and newly acquired core and well log data from hydrocarbon exploration wells. Analyses of data obtained from different sources provide a good understanding of the reservoir hydrogeology and petrophysics. Profiles of formation pressure, temperature, density, viscosity, porosity, permeability, and net pay were established for Lower Paleozoic sedimentary aquifers. Lateral hydraulic continuity is dominant at the regional scale, whereas vertical discontinuities are apparent for most physical and chemical properties. The Covey Hill sandstone appears as the most suitable saline aquifer for CO₂ injection/storage. This unit is found at a depth of more than 1 km and has the following properties: fluid pressures exceed 14 MPa, temperature is above 35 °C, salinity is about 108,500 mg/l, matrix permeability is in the order of 3 × 10^?16 m² (0.3 mDarcy) with expected higher values of formation-scale permeability due to the presence of natural fractures, mean porosity is 6 %, net pay reaches 282 m, available pore volume per surface area is 17 m³/m², rock compressibility is 2 × 10^?9 Pa^?1 and capillary displacement pressure of brine by CO₂ is about 0.4 MPa. While the containment for CO₂ storage in the Bécancour saline aquifers can be ensured by appropriate reservoir characteristics, the injectivity of CO₂ and the storage capacity could be limiting factors due to the overall low permeability of aquifers. This characterization offers a solid basis for the subsequent development of a numerical hydrogeological model, which will be used for CO₂ injection capacity estimation, CO₂ injection scenarios and risk assessment.     

Extensional Late Paleozoic deformation on the western margin of Pangea, Patlanoaya area, Acatlán Complex, southern Mexico

New mapping in the northern part of the Paleozoic Acatlán Complex (Patlanoaya area) records several ductile shear zones and brittle faults with normal kinematics (previously thought to be thrusts). These movement zones separate a variety of units that pass structurally upwards from: (i) blueschist-eclogitic metamorphic rocks (Piaxtla Suite) and mylonitic megacrystic granites (Columpio del Diablo granite ≡ Ordovician granites elsewhere in the complex); (ii) a gently E-dipping, listric, normal shear zone with top to the east kinematic indicators that formed under upper greenschist to lower amphibolite conditions; (iii) the Middle–Late Ordovician Las Minas quartzite (upper greenschist facies psammites with minor interbedded pelites intruded by mafic dikes and a leucogranite dike from the Columpio del Diablo granite) unconformably overlain by the Otate meta-arenite (lower greenschist facies psammites and pelites): roughly temporal equivalents are the Middle–Late Ordovician Mal Paso and Ojo de Agua units (interbedded metasandstone and slate, and metapelite and mafic minor intrusions, respectively) — some of these units are intruded by the massive, 461 ± 2 Ma, Palo Liso megacrystic granite: decussate, contact metamorphic muscovite yielded a ⁴⁰Ar/³⁹Ar plateau age of 440 ± 4 Ma; (iv) a steeply-moderately, E-dipping normal fault; (v) latest Devonian–Middle Permian sedimentary rocks (Patlanoaya Group: here elevated from formation status). The upward decrease in metamorphic grade is paralleled by a decrease in the number of penetrative fabrics, which varies from (i) three in the Piaxtla Suite, through (ii) two in the Las Minas unit (E-trending sheath folds deformed by NE-trending, subhorizontal folds with top to the southeast asymmetry, both associated with a solution cleavage), (iii) one in the Otate, Mal Paso, and Ojo de Agua units (steeply SE-dipping, NE–SW plunging, open-close folds), to (iv) none in the Patlanoaya Group. ⁴⁰Ar/³⁹Ar analyses of muscovite from the earliest cleavage in the Las Minas unit yielded a plateau age of 347 ± 3 Ma and show low temperature ages of  260 Ma. Post-dating all of these structures and the Patlanoaya Group are NE-plunging, subvertical folds and kink bands. An E–W, vertical normal fault juxtaposes the low-grade rocks against the Anacahuite amphibolite that is cut by megacrystic granite sheets, both of which were deformed by two penetrative fabrics. Amphibole from this unit has yielded a ⁴⁰Ar/³⁹Ar plateau age of 299 ± 6 Ma, which records cooling through  490 °C and is probably related to a Permo-Carboniferous reheating event during exhumation. The extensional deformation is inferred to have started in the latest Devonian ( 360 Ma) during deposition of the basal Patlanoaya Group, lasting through the rapid exhumation of the Piaxtla Suite at  350–340 Ma synchronous with cleavage development in the Las Minas unit, deposition of the Patlanoaya Group with active fault-related exhumation suggested by Mississippian and Early Permian conglomerates ( 340 and 300 Ma, respectively), and continuing at least into the Middle Permian (≡ 260 Ma muscovite ages). The continuity of Mid-Continent Mississippian fauna from the USA to southern Mexico suggests that this extensional deformation occurred on the western margin of Pangea after closure of the Rheic Ocean.     

Variations in statistical parameters of the <Emphasis Type="Italic">NmF</Emphasis>2 winter anomaly with latitude and solar activity

The maximal R ratios of the winter-to-summer NmF2 values of each ionosonde are calculated for a specified UT under daytime quiet geomagnetic conditions and at approximately equal levels of solar activity, based on foF2 measurement data of 98 ionosondes at mid- and low geomagnetic latitudes of the Northern and Southern hemispheres for 1957–2009. The P(R > 1) conditional probability of NmF2 winter anomaly observations, as well as the most probable RMP and average <R> of R values are calculated for low, moderate, and high solar activity on the base of foF2 measurements during the periods December 22 ± 30 days and June 21 ± 30 days. Variations in P(R > 1), RMP, and 〈R〉 with latitude and solar activity are analyzed.     

Storm surge mitigation through vegetation canopies

The paper of Reid and Whitaker (1976) on the effects of a vegetation canopy on flow of water is re-examined. Their assumptions on the equality of various drag coefficients are replaced by more realistic calculations. A new method for calculating wind stress on water is presented for the case when the vegetation extends above the water surface.For the case of vanishingly small water depth, it is shown that the horizontal stress is approximately constant in the vertical. This results in a diagnostic relationship for the water current as a function of the wind stress and bottom roughness.A new expression for the vertically averaged frictional force per unit mass is derived on the assumption that the friction velocity varies linearly with height. The vertical rate of change of friction velocity depends on the mean water current, the wind stress, the bottom roughness, and the water depth. This work has a possible application in the mitigation of storm surges.     

Stratigraphic spatial variation on the inner shelf of a high-yield river,Waiapu River,New Zealand: Implications for fine-sediment dispersal and preservation

The inner shelves of active, energetic continental margins are frequently defined as regions of sediment segregation and fine-sediment bypassing. The Waiapu River, North Island, New Zealand presents an opportunity to study fine-sediment segregation and strata formation in a spatially constrained, highly energetic, aggradational setting, with one of the highest sediment yields on earth. We present evidence that the inner shelf of the Waiapu River plays a significant role in both the fate of fine-grained (<63 μm) riverine sediments and the formation of continental margin stratigraphy. Results obtained from high-resolution interferometric bathymetry and high-frequency seismic mapping ground-truthed by cores show significant stratigraphic spatial variation preserved on the Waiapu inner shelf. This spatial variation is likely controlled by spatially-distinct sediment deposition and resuspension processes as well as antecedent geology. Two distinct depositional regions are interpreted as: (1) surface plume-dominated with partial resuspension, characterized by acoustically transparent seismic reflection profiles and muddy sands; and (2) event-layer dominated, characterized by thickly laminated sediments. A modern-day bathymetric low overlying an observed paleochannel may influence the fate of hyperpycnal flows transiting the shelf via bathymetric steering. Fining-upward sequences found over the entire shelf are interpreted to represent deforestation-induced sedimentation that has overwhelmed the ability of the energetic system to resuspend and segregate fine sediments. We conclude that the primary control on strata formation on the inner shelf of the Waiapu River is local sediment supply.     

Chemistry of snow and lake water in Antarctic region

Surface snow and lake water samples were collected at different locations around Indian station at Antarctica, Maitri, during December 2004–March 2005 and December 2006–March 2007. Samples were analyzed for major chemical ions. It is found that average pH value of snow is 6.1. Average pH value of lake water with low chemical content is 6.2 and of lake water with high chemical content is 6.5. The Na⁺ and Cl^? are the most abundantly occurring ions at Antarctica. Considerable amount of SO ₄ ^2? is also found in the surface snow and the lake water which is attributed to the oxidation of DMS produced by marine phytoplankton. Neutralization of acidic components of snow is mainly done by NH ₄ ⁺ and Mg²⁺. The Mg²⁺, Ca²⁺ and K⁺ are nearly equally effective in neutralizing the acidic components in lake water. The NH ₄ ⁺ and SO ₄ ^2? occur over the Antarctica region mostly in the form of (NH₄)₂SO₄.     

Behavior of the cosmic ray density during the initial phase of the Forbush effect

Variations in the cosmic ray density during the initial phase of the Forbush effect during the first hours after the arrival of the interplanetary shock wave have been studied with the use of data on variations in the cosmic ray density with a rigidity of 10 GV obtained by the global survey method by the world network of neutron monitors in 1957?2012. It is found that behavior of this parameter after the arrival of the shock wave demonstrates high variability. A small (~1/5 of total number), though distinct, group of Forbush effects, in which the density of the cosmic ray increases (not decreases) after the arrival of the shock wave, is defined. As a whole, the initial variation in cosmic ray density is correlated with the Forbush effect magnitude and the strength of the associated geomagnetic disturbance.     

Peak response of 2-DOF uncoupled oscillator under two-directional base motion

This paper investigates the peak response of a 2-DOF uncoupled linear oscillator under arbitrarily oriented two-component horizontal earthquake motion. Input data consist of 22 two-component acceleration records from the magnitude 6.6, October 15, 1979 Imperial Valley earthquake. One-directional response spectra for each principal direction of the oscillator, and two-directional response spectra (amplitude of the peak resultant response and its direction with respect to principal directions) are calculated by considering all angles of incidence of the excitation. The results indicate that, for oscillators that are not too flexible (i.e. with natural frequencies greater than 0.8 Hz), the two-directional peak response is controlled by the weaker direction of the oscillator. For flexible oscillators the two-directional peak response is controlled by the direction whose natural frequency is closer to dominant ground motion frequencies. The results also show that when the two-directional peak response is expressed as a weighted sum of one-directional peak responses, the weighting factors are not constants, but functions of oscillator and dominant ground motion frequencies.     

Defining dynamic pelagic habitats in oceanic waters off eastern Australia

Although many species in the pelagic ocean are widespread, they are not randomly distributed. These species may have associations with particular water masses or habitats, but to best understand patterns in the ocean, these habitats must be identified. Previous efforts have produced static or seasonal climatologies, which still represent smearing over habitats. The Eastern Tuna and Billfish Longline Fishery (ETBF) targets a range of high trophic level species in oceanic waters off eastern Australia. In this study, dynamic ocean habitats in the region were identified for each month based on cluster analysis of five oceanographic variables averaged at a monthly time scale and a spatial scale of 0.5° for the period 1995-2006. A total of seven persistent habitats were identified off eastern Australia with intra and interannual variation in size and location, indicating the importance of spatial and temporal variation in the dynamics of the region. The degree to which these dynamic habitats were distinguished was tested using (i) stable isotope analysis of top fish predators caught in the region and (ii) estimates of variation in estimated abundance generated from catch data from the fishery. More precise estimates (measured as lower total CV) of isotopic values from swordfish (Xiphias gladius), yellowfin tuna (Thunnus albacares) and albacore (Thunnus alalunga) were obtained for 4 of 6 isotope comparisons using the dynamic habitat groupings, which indicate that stratifying by pelagic habitat improved precision. Dynamic habitats produced more precise abundance estimates for 7 of 8 large pelagic species examined, with an average reduction in total CV of 19% compared to when abundance was estimated based on static habitat stratification. These findings could be used to guide development of effective monitoring strategies that can distinguish patterns due to environmental variation, and in the longer term, climate change.