Controlling factors of groundwater hydrochemistry in a small island’s aquifer

Factor analysis was applied to the hydrochemical data set of Manukan Island in order to extract the principal factors corresponding to the different sources of variation in the hydrochemistry. The application of varimax rotation was to ensure the clear definition of the main sources of variation in the hydrochemistry. The geochemical data of dissolved major, minor and trace constituents in the groundwater samples indicates the main processes responsible for the geochemistry evolution. By using Kaiser normalization, principal factors were extracted from the data for each location. The analysis reveals that there are four sources of solutes: (1) seawater intrusion; (2) leaching process of underlying rock mediated by pH; (3) minerals weathering process and (4) dissolution of carbonate minerals characterized by high loadings of Ca, Zn and Mg. Such processes are dominated by the significant role of anthropogenic impact from the over abstraction of fresh water from the aquifer. Those factors contributed to the changes of the groundwater geochemistry behavior explain the effect of rising extraction of freshwater from the aquifer.     

Contrasting soils and landscapes of the Piedmont and Coastal Plain, eastern United States

The Piedmont and Coastal Plain physiographic provinces comprise 80 percent of the Atlantic Coastal states from New Jersey to Georgia. The provinces are climatically similar. The soil moisture regime is udic. The soil temperature regime is typically thermic from Virginia through Georgia, although it is mesic at altitudes above 400 m in Georgia and above 320 m in Virginia. The soil temperature regime is mesic for the Piedmont and Coastal Plain from Maryland through New Jersey. The tightly folded, structurally complex crystalline rocks of the Piedmont and the gently dipping “layer-cake” clastic sedimentary rocks and sediments of the Coastal Plain respond differently to weathering, pedogenesis, and erosion. The different responses result in two physiographically contrasting terrains; each has distinctive near-surface hydrology, regolith, drainage morphology, and morphometry.The Piedmont is predominantly an erosional terrain. Interfluves are as narrow as 0.5 to 2 km, and are convex upward. Valleys are as narrow as 0.1 to 0.5 km and generally V-shaped in cross section. Alluvial terraces are rare and discontinuous. Soils in the Piedmont are typically less than 1 m thick, have less sand and more clay than Coastal Plain soils, and generally have not developed sandy epipedons. Infiltration rates for Piedmont soils are low at 6–15 cm/h. The soil/saprolite, soil/rock, and saprolite/rock boundaries are distinct (can be placed within 10 cm) and are characterized by ponding and/or lateral movement of water. Water movement through soil into saprolite, and from saprolite into rock, is along joints, foliation, bedding planes and faults. Soils and isotopic data indicate residence times consistent with a Pleistocene age for most Piedmont soils.The Coastal Plain is both an erosional and a constructional terrain. Interfluves commonly are broader than 2 km and are flat. Valleys are commonly as wide as 1 km to greater than 10 km, and contain numerous alluvial and estuarine terrace sequences that can be correlated along valleys for tens of kilometers. Coastal Plain soils are typically as thick as 2 to 8 m, have high sand content throughout, and have sandy epipedons. These epipedons consist of both A and E horizons and are 1 to 4 m thick. In Coastal Plain soils, the boundaries are transitional between the solum and the underlying parent material and between weathered and unweathered parent material. Infiltration rates for Coastal Plain soils are typically higher at 13–28 cm/h, than are those for Piedmont soils. Indeed, for unconsolidated quartz sand, rates may exceed 50 cm/h. Water moves directly from the soil into the parent material through intergranularpores with only minor channelization along macropores, joints, and fractures. The comparatively high infiltration capacity results in relatively low surface runoff, and correspondingly less erosion than on the Piedmont uplands.Due to differences in Piedmont and Coastal Plain erosion rates, topographic inversion is common along the Fall Zone; surfaces on Cenozoic sedimentary deposits of the Coastal Plain are higher than erosional surfaces on regolith weathered from late Precambrian to early Paleozoic crystalline rocks of the Piedmont. Isotopic, paleontologic, and soil data indicate that Coastal Plain surficial deposits are post-middle Miocene to Holocene in age, but most are from 5 to 2 Ma. Thus, the relatively uneroded surfaces comprise a Pliocene landscape. In the eastern third of the Coastal Plain, deposits that are less than 3.5 Ma include alluvial terraces, marine terraces and barrier/back-barrier complexes as morphostratigraphic units that cover thousands of square kilometers. Isotopic and soil data indicate that eastern Piedmont soils range from late Pliocene to Pleistocene in age, but are predominantly less than 2 Ma old. Thus, the eroded uplands of the Piedmont “peneplain” comprise a Pleistocene landscape.     

Granite fracture index to check suitability of granite outcrops for quarrying

A correct knowledge of fracture patterns previous to quarrying is important for economical exploitation. This work comprises the general characterization of the discontinuities of 10 granite rock masses in NE Portugal. During the study some discontinuity characteristics such as orientation, persistence, aperture, trace length and spacing were evaluated. The differences in the characteristics of the selected granites were described, and the most important exploration factors were identified. In the granites studied, most of the joints are oriented from N10°E to N50°E, which is compatible with the regional fracture pattern. Concerning joint termination, the XX type is common, while the RR type is rare; the persistence index ranges from 3.5% to 25.4%. Closed joints are predominant in the granites studied (> 72.4%), and openings of the others are about 1–2 mm as a result of superficial displacement of the granite blocks. The percentage of filled joints, usually by quartz and pegmatite, is different from one granite to another, but most are < 20%. The average joint length ranges from 11.1 m in post-tectonics granites to 4.6 m in syntectonic granites. Joint spacing varies from 0.98 to 2.8 m with higher values in post-tectonic granites. Joint-space distributions of the granites studied are close to log-normal and exponential distributions. Volumetric joint count (Jv) ranges from 0.8 to 2.1 joints/m³ and is used for categorizing the places of each granite. The relationships between Jv and other joint characteristics, such as length, spacing and number of joint sets, were investigated. A Granite Fracturing Index (GFI) is introduced, computed on the basis of volumetric joint count, number of joint sets and true joint spacing. The GFI classification of studied places allows us evaluate the suitability for profitable exploitation.     

Diamonds in the products of the 2012–2013 Tolbachik eruption (Kamchatka) and mechanism of their formation

The origin of diamonds in the lava and ash of the recent Tolbachik eruption of 2012–2013 (Kamchatka) is enigmatic. The mineralogy of the host rocks provides no evidence for the existence of the high pressure that is necessary for diamond formation. The analysis of carbon isotope systematics showed a similarity between the diamonds and dispersed carbon from the Tolbachik lava, which could serve as a primary material for diamond synthesis. There are grounds to believe that the formation of Tolbachik diamonds was related to fluid dynamics. Based on the obtained results, it was suggested that Tolbachik microdiamonds were formed as a result of cavitation during the rapid movement of volcanic fluid. The possibility of cavitation-induced diamond formation was previously theoretically substantiated by us and confirmed experimentally. During cavitation, ultrahigh pressure is generated locally (in collapsing bubbles), while the external pressure is not critical for diamond synthesis. The conditions of the occurrence of cavitation are rather common in geologic processes. Therefore, microdiamonds of such an origin may be much more abundant in nature than was supposed previously.     

Analysis of the Dynamic Performance of an Underground Excavation in Jointed Rock under Repeated Seismic Loading

Results from field observations of dynamic behaviour of an underground excavation have been compared with numerical studies of the rock deformation history. The field behaviour shows progressive accumulation of rock displacement and excavation deformation under successive episodes of dynamic loading. It is possible to reproduce the modes of rock response quite well using a Distinct Element model of the rock mass, but the way displacements develop is dependent on the joint model used in the analysis. It is suggested that, in rock masses subject to repeated dynamic loading, excavation design may need to take account of the prospect of repeated episodes of transient loading at the excavation site.     

Porphyroblast rotation during crenulation cleavage development: an example from the aureole of the Mooselookmeguntic pluton, Maine, USA

In the low‐pressure, high‐temperature metamorphic rocks of western Maine, USA, staurolite porphyroblasts grew at c. 400 Ma, very late during the regional orogenesis. These porphyroblasts, which preserve straight inclusion trails with small thin‐section‐scale variation in pitch, were subsequently involved in the strain and metamorphic aureole of the c. 370 Ma Mooselookmeguntic pluton. The aureole shows a progressive fabric intensity gradient from effectively zero emplacement‐related deformation at the outer edge of the aureole ～2900 m (map distance) from the pluton margin to the development of a pervasive emplacement‐related foliation adjacent to the pluton. The development of this pervasive foliation spanned all stages of crenulation cleavage development, which are preserved at different distances from the pluton. The spread of inclusion‐trail pitches in the staurolite porphyroblasts, as measured in two‐dimensional (2‐D) thin sections, increases nonlinearly from ～16° to 75° with increasing strain in the aureole. These data provide clear evidence for rotation of the staurolite porphyroblasts relative to one another and to the developing crenulation cleavage. The data spread is qualitatively modelled for both pure and simple shear, and both solutions match the data reasonably well. The spread of inclusion‐trail orientations (40–75°) in the moderately to highly strained rocks is similar to the spread reported in several previous studies. We consider it likely that the sample‐scale spread in these previous studies is also the result of porphyroblast rotation relative to one another. However, the average inclusion‐trail orientation for a single sample may, in at least some instances, reflect the original orientation of the overgrown foliation.     

Synoptic and local scale atmospheric circulation associated with air pollution episodes in an urban Mediterranean area

Air pollution episodes in urban coastal areas follow certain pre-determined patterns, being associated with certain local meteorological conditions and emission of primary pollutants. In this study, the synoptic and local scale atmospheric circulation that prevails during air pollution episodes in a coastal major city in Greece, Thessaloniki, is examined for a period of 15 years (1989–2004). The study signifies the importance of studying air pollution meteorological patterns between coastal areas with different terrain characteristics. For Thessaloniki, it was found that the episodes occur mainly during the cold period of the year, while four types of synoptic scale circulation were recognized (I, II, III, IV) and five patterns of the local scale circulation (A1, A2, B1, B2 and B3). The highest percentage of episodes is associated with the presence of an anticyclone over the northern Greece (types I and IV), being characterized by weak or very weak surface pressure gradient intensity, according to the position and extension of the anticyclone. Moreover, a temperature increase of at least 1°C during the previous 3 days is required in the lower troposphere. Consistent with the synoptic conditions, the development of the sea breeze plays a crucial role in the occurrence of the episodes, even in the cold period of the year, when the sea breeze can still develop with smaller frequency and intensity. Finally, it was found that a small number of episodes is related with the advection of polluted air masses from the industrial area in the northwest of the city and from the Eordaia area in the west, which is the largest lignite producing area of Balkans.     

IAP GCM模式大气背景环流在厄尔尼诺年的异常

本文分析了中国科学院大气物理研究所大气环流模式(IAP GCM)模式大气5～9月平均环流(本文称为背景环流)。结果表明;厄尔尼诺年一系列重要系统(南方涛动、瓦克环流、哈德莱环流、西太平洋副热带高压和热带辐合带)及大范围降水均发生明显异常;北半球西太平洋热带、副热带是环流异常的主要区域。它们与观测资料的分析结果基本一致,从而论证了该模式在低纬环流研究中的应用前景。     

Ionospheric measurements of relative coronal brightness during the total solar eclipses of 11 August, 1999 and 9 July, 1945

Swept-frequency (1/10 MHz) ionosonde measurements were made at Helston, Cornwall (50°06N, 5°18W) during the total solar eclipse on August 11, 1999. Soundings were made every three minutes. We present a method for estimating the percentage of the ionising solar radiation which remains unobscured at any time during the eclipse by comparing the variation of the ionospheric E-layer with the behaviour of the layer during a control day. Application to the ionosonde date for 11 August, 1999, shows that the flux of solar ionising radiation fell to a minimum of 25±2% of the value before and after the eclipse. For comparison, the same technique was also applied to measurements made during the total solar eclipse of 9 July, 1945, at Sörmjöle (63°68N, 20°20E) and yielded a corresponding minimum of 16 ± 2%. Therefore the method can detect variations in the fraction of solar emissions that originate from the unobscured corona and chromosphere. We discuss the differences between these two eclipses in terms of the nature of the eclipse, short-term fluctuations, the sunspot cycle and the recently-discovered long-term change in the coronal magnetic field.     

Paleolatitudes of the Kerguelen hotspot: new paleomagnetic results and dynamic modeling

The Kerguelen Plateau, a Large Igneous Province in the southern Indian Ocean, was formed as a product of the Kerguelen hotspot in several eruptive phases during the last 120 Myr. We obtained new paleolatitudes for the central and northern Kerguelen Plateau from paleomagnetic investigations on basalts, which were drilled during ODP Leg 183 to the Kerguelen Plateau-Broken Ridge. The paleolatitudes coincide with paleolatitudes from previous investigations at the Kerguelen Plateau and Ninetyeast Ridge (the track of the Kerguelen hotspot) and indicate a difference between paleolatitudes and present position at 49°S of the Kerguelen hotspot. We show that true polar wander, the global motion between the mantle and the rotation axis, cannot explain this difference in latitudes. We present numerical model results of plume conduit motion in a large-scale mantle flow and the resulting surface hotspot motion. A large number of models all predict southward motion between 3° and 10° for the Kerguelen hotspot during the last 100 Myr, which is consistent with our paleomagnetic results.