The Preboreal climate reversal and a subsequent solar‐forced climate shift

Accurate chronologies are essential for linking palaeoclimate archives. Carbon‐14 wiggle‐match dating was used to produce an accurate chronology for part of an early Holocene peat sequence from the Borchert (The Netherlands). Following the Younger Dryas–Preboreal transition, two climatic shifts could be inferred. Around 11 400 cal. yr BP the expansion of birch (Betula) forest was interrupted by a dry continental phase with dominantly open grassland vegetation, coeval with the PBO (Preboreal Oscillation), as observed in the GRIP ice core. At 11 250 cal. yr BP a sudden shift to a humid climate occurred. This second change appears to be contemporaneous with: (i) a sharp increase of atmospheric ¹⁴C; (ii) a temporary decline of atmospheric CO₂; and (iii) an increase in the GRIP ¹⁰Be flux. The close correspondence with excursions of cosmogenic nuclides points to a decline in solar activity, which may have forced the changes in climate and vegetation at around 11 250 cal. yr BP. Copyright © 2004 John Wiley & Sons, Ltd.     

Paleostress-tensor analysis of late deformation events in the Odenwald Crystalline Complex and comparison with other units of the Mid-German Crystalline Rise, Germany

Summary Geometric data of fault planes and fault plane lineations, together with the observed sense of shear on the slip planes, were used to calculate paleostress tensors and fields responsible for the post metamorphic peak D3 and D4 deformation events in the four Odenwald units sensu Krohe (1991). The paleostress fields were calculated using the method of Will and Powell (1991). As inferred from the paleostress analysis, the D3 strike-slip deformation west of the Otzberg fault zone was caused by a, ± N-S directed, compressional regional stress field, with shallowly plunging σ₁ axes and σ₃ directions that plunge at shallow to moderate angles to the E or W; the calculated mean orientations are: σ₁ 06 → 350, σ₂ 77 → 234 and σ₃ 12 → 085. The B?llsteiner Odenwald east of the Otzberg fault zone was not affected by this stress field. This implies that the Bergstr?sser and B?llsteiner Odenwald were spatially separated and formed independent crustal blocks during D3. The D4 faulting event is recognised in all areas investigated, even though most prominently in units III and IV, and juxtaposed the Bergstr?sser and B?llsteiner Odenwald. This faulting episode was caused by a paleostress field with a steeply westerly plunging σ₁ axis and a shallowly southsoutheasterly plunging σ₃ axis. The orientations of the principal stresses are: σ₁ 52 → 270, σ₂ 38 → 085 and σ₃ 06 → 174. With continued deformation from D3 to D4, there was a progressive change in the orientation of the stress field indicating a change from a N-S compressional to extensional stress field, accompanied by the progressive development of strike-slip faults and late normal faults. Paleostress field orientations in the Pfalz Forest, SW of the Odenwald, determined by Fl?ttmann and Oncken (1992) are very similar to those obtained for the Odenwald region and indicate a regionally consistent stress pattern in the southwestern part of the Mid-German Crystalline Rise (MGCR) during strike-slip and normal faulting deformations.

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Zusammenfassung Paleostress-Tensor Analyse sp?ter Deformationsereignisse im Odenwald-Kristallin und ein Vergleich mit anderen Einheiten der Mitteldeutschen Kristallinzone, Deutschland Für die vier Odenwald-Einheiten im Sinne von Krohe (1991) wurden Pal?ostressfelder für die Blattverschiebungs- und Abschiebungsereignisse D3 und D4 mit der Methode von Will und Powell (1991) berechnet. Die Analyse ergibt, da? das regionale Spannungsfeld, das westlich der Otzberg-Zone im Bergstr?sser Odenwald zum D3-Ereignis führte, ein ± N-S gerichtetes kompressives Stresssfeld war. Die σ₁-Achse f?llt flach nach N bzw. S ein, die σ₃-Achse mit kleinen bis moderaten Winkeln nach E bzw. W; die berechneten Orientierungen der Hauptspannungsrichtungen sind: σ₁ 08 → 350, σ₂ 77 → 234 and σ₃ 12 → 085. Der B?llsteiner Odenwald, ?stlich der Otzberg-Zone, wurde von diesem Spannungsfeld nicht erfa?t. Dies impliziert, da? Bergstr?sser und B?llsteiner Odenwald w?hrend des D3-Ereignisses voneinander getrennt waren und separate Krusteneinheiten darstellten. Auswirkungen der D4-Deformation k?nnen im gesamten Untersuchungsgebiet erkannt werden, am st?rksten jedoch in den Einheiten III und IV. Dieses Ereignis wurde von einem Pal?ostressfeld mit einer steil nach W einfallenden σ₁- und einer flach nach SSE einfallenden σ₃-Achse verursacht und führte zum Zusammenschlu? von Bergstr?sser und B?llsteiner Odenwald. Die berechneten Orientierungen der Hauptspannungsrichtungen sind: σ₁ 52 → 270, σ₂ 38 → 085 und σ₃ 06 → 174. Die Rotation der Hauptspannungsrichtungen war mit einer ?nderung von einem kompressionalen N-S gerichteten (D3) hin zu einem extensionalen (D4) Stressfeld verbunden. Die erzielten Ergebnisse sind sehr ?hnlich mit Resultaten, die Fl?ttmann und Oncken (1992) im Pf?lzer Wald ermittelten. Dies weist auf ein regional übereinstimmendes Spannungsfeld im SW-Teil der Mitteldeutschen Kristallinzone hin.

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Received July 8, 1999; revised version accepted March 28, 2000     

A model for the constant-head pumping test conducted in vertically fractured media

An analytical model for the constant-head pumping test is developed for a partially penetrating well that has a finite thickness skin, and intersects a single vertical fracture. In the model, the fracture is fully confined and flow occurs only in the fracture. The model is developed using Laplace transform and finite Fourier transform methods. The model is to be used for analysing well test data from vertically fractured media and for verifying numerical models. Dimensionless curves are used to study the effects of a finite thickness skin and a partially penetrating wellbore. In the presence of a finite thickness skin, or a partially penetrating wellbore, a typical flow response for the constant-head pumping test has three distinct periods of flow corresponding to small-, intermediate- and large-time. Small- and large-time approximations are presented for the model. For tests where the wellbore is fully penetrating, or the partial penetration ratio is known, these approximations can be used to analyse field data.     

Cation ordering of orthopyroxenes from the Skaergaard Intrusion: implications for the subsolidus cooling rates and permeabilities

 We have determined the quenched cation ordering states of five orthopyroxene crystals collected from the marginal border group and the lower zone a and b of the Skaergaard intrusion, and modeled these data to retrieve their closure temperatures (T _c) of Fe–Mg ordering and cooling rates. According to existing thermal models for the Skaergaard pluton, conductive cooling dominated the high and low temperature regimes, which were separated by an intermediate temperature regime in which the cooling was controlled primarily by convective fluid circulation. The cooling rates retrieved from the quenched cation ordering states of the orthopyroxene crystals strictly apply to temperatures around the closure temperatures of the ordering states, ∼340–400^° C, which fall at the transition from convective to the lower temperature conductive cooling. The cooling rates obtained from the cation ordering states of orthopyroxene vary from ∼1 to 270 K/ka. These results agree well with a thermal model calculated using an assumed average permeability of 10^-12 cm² for the pluton, but not completely with a model calculated on the basis of an average permeability of 10^-13 cm², although both values produced shifts of δ¹⁸O that are comparable to those observed in the pluton. Received: 27 February 1995/Accepted: 20 July 1995     

X-ray transient sources

The galactic distribution and physical nature of X-ray transient sources is investigated. Two types of transients are considered. The observational data on 41 X-ray transient sources are given, and the average parameters of hard and soft X-ray transients are estimated.     

Sedimentation on the Ionian active margin (Hellenic arc) — Provenance of sediments and mechanisms of deposition

Lithological, sedimentological, mineralogical and faunal analyses of twenty cores from the western Peloponnesus margin and adjacent Matapan Trench permit the origin of the sediments and the processes of sedimentation to be defined in some detail.Except for the ash layers derived from the Ischian Province, the major part of the sediment is local in origin (Peloponnesus). Analyses of heavy, light and clay minerals enable three main provinces to be distinguished. Each of these provinces includes one or more slope basins and a portion of trench, without lateral connection between them and mixing of inputs.The diversity and complexity of sedimentary structures, the granulometric characters, the mixed fauna (molluscs and ostracods) and the variability of rates of sedimentation all testify to the prevalence of reworking phenomena and gravitative processes.These data confirm and elaborate on the model of sedimentation deduced from seismic studies in which sediments are successively trapped, released by the slope basins and transferred via channels and canyons towards the underlying trench basins. This “cascade feeding” appears characteristics of this subductive sedimentary environment.     

Thermodynamic controls on element partitioning between titanomagnetite and andesitic–dacitic silicate melts

Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO₂) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg²⁺, Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺) and Cu²⁺/Cu⁺ with increasing fO₂ between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO₂ implies a reciprocal relationship between a(Fe²⁺O) and a(Fe³⁺O_1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO₂ in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO₂ in silicic, but less so in mafic bulk systems.     

Stratospheric methane and nitrogen dioxide from infrared spectra

Values of the mixing ratio by volume of stratospheric NO₂ and CH₄ deduced from infrared spectra taken by means of balloon-borne spectrometers are presented. Possible evidence for the presence of formaldehyde in the stratosphere is also given.     

Chemical composition of Russian Arctic precipitation in 2007-2015

The results of observations of the chemical composition of precipitation in the Russian Arctic in 2007-2015 are summarized including the data from NP-35 drifting ice station obtained in 2007-2008 in the framework of the joint program of Arctic and Antarctic Research Institute and Voeikov Main Geophysical Observatory. The qualitative and quantitative difference in the chemical composition of precipitation in the Atlantic, Siberian, and Pacific sectors of the Russian Arctic is revealed. It is found that the concentration of microelements (heavy metals) in precipitation at NP-35 ice station did not exceed 12% of total ions at the lowest mineralization. The comparative analysis is presented of the concentration of sulfate ions in precipitation in Norilsk and at NP-35 ice stations.     

The acute aquatic toxicity of some substances carried by ships

At the request of the International Maritime Organization (IMO), our laboratory has performed acute toxicity testing with 43 substances, for which insufficient or no data had been available for hazard rating concerning damage to marine living resources.