Geochemistry, K–Ar geochronology and Sr–Nd–Pb isotope compositions of pitchstone in Gohado, southwestern Okcheon Belt, South Korea

Abstract Geochemical and Sr–Nd–Pb isotope characteristics, as well as K–Ar geochronology of a massive pitchstone (volcanic glass) stock erupted into Late Cretaceous lapilli tuff and rhyolite in the Gohado area, southwestern Okcheon Belt, South Korea, are reported. The pitchstones are highly evolved with SiO₂ contents ranging from ～72 to 73 wt%, K₂O/Na₂O ratios of 1.04–1.23 and low MgO/FeO^t values (0.17–0.20). The pitchstones are weakly peraluminous and the ASI (molar Al₂O₃/Na₂O + K₂O + CaO) values are significantly lower than 1.1. The pitchstones also display a general calc‐alkaline nature with significant alkali contents. The rare earth elements (REE) compositions show moderately fractionated nature with (La/Yb)_N ranging from 11 to 16. Chondrite normalized REE patterns show relative enrichment of light REE over heavy REE and moderate Eu anomaly (Eu/Eu* ratio varies from 0.53 to 0.57). A distinct negative Nb anomaly is observed for all pitchstones on a primitive mantle normalized trace element diagram, typical of subduction‐related magmatism and crustal‐derived granites. All these features are characteristic of I‐type granites derived from a continental arc. The pitchstones have Zr contents of 98.5–103.5 ppm with zircon thermometry yielding temperatures of 749–755°C (mean 752°C). The K–Ar analyses of representative pitchstone samples yielded ages of 58.7 ± 2.3 and 62.4 ± 2.1 Ma with a mean age of 61 Ma. The rocks show nearly uniform initial ⁸⁷Sr/⁸⁶Sr isotopic ratios of 0.7104–0.7106 and identical ¹⁴³Nd/¹⁴⁴Nd initial ratio of 0.5120. The rocks display negative εNd (61 Ma) values of ?12. The depleted mantle model ages (T_DM) range from 1.54 Ga to 1.57 Ga. The Pb isotope ratios are ²⁰⁶Pb/²⁰⁴Pb = 18.522–18.552, ²⁰⁷Pb/²⁰⁴Pb = 15.642–15.680 and ²⁰⁸Pb/²⁰⁴Pb = 38.794–38.923. These ratios suggest that the Gohado pitchstones were formed in a continental arc environment by partial melting of a 1.54 Ga to 1.57 Ga parental sources of lower crustal rocks probably of mafic or intermediate compositions.     

SLA–chlorophyll-a variability and covariability in the Algero-Provençal Basin (1997–2007) through combined use of EOF and wavelet analysis of satellite data

Data reduction and signal decomposition techniques have been applied to a large bio-physical remotely sensed dataset covering the decade 1997–2007. The aim was the estimation of the spatial (basin and sub-basin scales) and temporal (seasonal and interannual) variability of sea level anomalies and chlorophyll-a concentration in the Algero-Provençal Basin, as well as the study of their covariability. Empirical orthogonal functions, wavelet analysis, singular value decomposition and correlation maps have been successfully used to individuate the patterns of (co)variability of the investigated fields. The seasonal variability of the phytoplanktonic biomass is divided in two distinct modes, timewise and spacewise separated. Positive interannual events are related to anomalies in 1999 and 2005, while the main (negative) anomaly is that of summer 2003, associated to the European 2003 heatwave. The analysis of the sea level anomalies shows a minimum in the formation of anticyclonic Algerian eddies during that period. The largest anticorrelation between sea level anomalies and phytoplanktonic biomass is found in the central zone of the basin, suggesting a clear biological response to the shoaling/deepening of the isopycnae and so to the nutrient injection into the euphotic layer. The analysis suggests that the driver of the variability of the nutricline depth in this central area is the displacement (seasonal) of the North Balearic Front and the formation/action of the frontal eddies.     

Mathematical modeling of nighttime enhanced electron density regions in the Earth’s ionospheric <Emphasis Type="Italic">F</Emphasis>2 layer and plasmasphere

A mathematical modeling method and the global numerical model of the Earth’s upper atmosphere were used to study nighttime enhanced electron density regions (EEDRs) in the ionospheric F2 layer and their possible manifestations at altitudes of the Earth’s plasmasphere. It has been established that EEDRs are formed owing to latitudinally nonuniform longitudinal (along the magnetic field) plasma flows from the plasmasphere into the nighttime ionosphere and the wind transport of ions along geomagnetic field lines. The specific features of the effect of ionospheric-plasmaspheric plasma transport processes, related to their three-dimensional character, on EEDRs have been revealed.     

Some methods of interpretation of the magnetic fields

Summary The author compares some methods of prospection which are based on the telluric measurements: 1) old method of elliptic representation of the telluric current and constants of conductibility; 2) methods ofKato, Kikuchi, Rikitake, Tikhonov, Cagniard and 3) method proposed by the author in 1952.The theory of «Dreiblätter» developed by the author in 1952 is applied to obtain a simple relation between the telluric values, the magnetic values and the tensor of conductibility. It is shown that in many cases this relation can be a simple algebraic one. The problem of «three» layers is developed with details and the possibility of generatlisation to the case of more than the three layers mentioned.The direct method developed in this paper is not the only possible one. The indirect means values (tensor means) can be also introduced: see our articles C.R. de l'Acad. des Scinces, t. 239, p. 1457, 1954 (Paris) and C.R. de l'Académie des Sciences, t. 239, p. 1766, 1954 (Paris). From the abstract point of view the utilisation of the indirect (tensor) means is simpler, but in order to visualize the pratical applications we have chosen here the direct method of computation.     

Removal of heavy metal ions from drinking water by alginate-immobilised <Emphasis Type="Italic">Chlorella sorokiniana</Emphasis>

This paper investigates the potential of alginate-immobilised Chlorella sorokiniana for removing Cu²⁺, Ni²⁺ and Cd²⁺ ions from drinking water solutions. The effects of initial metal concentrations, contact times and temperatures on the biosorptions and removal efficiencies of the tested metals were investigated at initial pH values of 5, and pH effects were studied within the range of 3–7. When studying the effects of initial metal concentrations, the highest experimental removal yields achieved for Cu²⁺, Ni²⁺ and Cd²⁺ ions were 97.10, 50.94 and 64.61 %, respectively. The maximum biosorption capacities obtained by the Langmuir isotherm model for the biosorptions of Cu²⁺, Ni²⁺ and Cd²⁺ ions by alginate-immobilised C. sorokiniana were found to be 179.90, 86.49 and 164.50 mg/g biosorbent, respectively. The experimental data followed pseudo-second-order kinetics. At an initial metal concentration of 25 mg/L, immobilised algae could be used in at least 5 successive biosorption–desorption cycles. SEM and EDS analyses revealed that the metals bonded to the biosorbent. Bi- and multi-metal systems of Cu²⁺, Ni²⁺ and Cd²⁺ were investigated at initial metal concentrations of 30, 50 and 100 mg/L. The removal of Cd²⁺ as well as Ni²⁺ in such systems was negatively affected by the presence of Cu²⁺. The removal efficiency for Cu²⁺ in multi-metal systems decreased by 5–7 %, whilst in the cases of Cd²⁺ and Ni²⁺ the efficiencies decreased by up to 30 %. Nevertheless, the results obtained show that alginate-immobilised C. sorokiniana can efficiently remove the metals tested from polluted drinking water sources.     

The Derivation and Validation of TBM Disc Cutter Wear Prediction Model

The problem of disc cutter wear is inevitable when shield or TBM excavating hard rock for a long distance, thus, the study of disc cutter wear model has an important project value on predicting its service life and replacement opportunity. It is put forward by analyzing disc cutter wear mechanism that the main wear form is abrasive wear, which is based on plastic removal mechanism. Then, disc cutter wear rate and linear wear rate prediction models are obtained by approximate calculation and mathematical deduction, which are based on Rabinowicz equation and CSM model. At last, the two models are verified through field test data from three projects, and the results show that the prediction model can accurately reflect the real wear situation of disc cutter.     

Anticlockwise evolution of ultrahigh-temperature granulites within continental collision zone in southern India

We report three new localities of corundum and sapphirine-bearing hyper aluminous Mg-rich and silica-poor ultrahigh-temperature granulites formed during Late Neoproterozoic-Cambrian times within the Palghat–Cauvery Shear Zone system in southern India. From petrologic characteristics, mineral chemistry and petrogenetic grid considerations, the peak metamorphic conditions of these rocks are inferred to lie around 950–1000 °C (as suggested by Al in orthopyroxene thermometer) at pressures above 10 kbar (as indicated by the equilibrium orthopyroxene–sillimanite–gedrite ± quartz assemblage). These rocks preserve several remarkable reaction textures, the most prominent among which is the triple corona of spinel–sapphirine–cordierite on corundum, with the whole textural assembly embedded within the matrix of gedrite, suggesting the reaction: Ged + Crn = Spl + Spr + Crd. The formation of sapphirine–sillimanite assemblage/symplectite associated with relict corundum and porphyroblasitc cordierite is explained by the reaction: Crd + Crn = Spr + Sil. The association of sapphirine cordierite symplectite with gedrite–sillimanite assemblage as well as with aluminosilicate boundaries indicates the gedrite consuming reaction: Ged + Sil = Spr + Crd. Extensive growth of sapphirine–cordierite observed on the rim of gedrite porphyroblasts with spinel occurring as relict inclusions within the sapphirine indicates the reaction: Ged + Spl = Spr + Crd. The pressure–temperature (P–T) path defined from the observed mineral assemblages and reaction texture is characterized by anticlockwise trajectory, with a prograde segment of initial heating and subsequent deep burial, followed by retrograde near-isothermal decompression. Such an anticlockwise trajectory is being reported for the first time from southern India and has important tectonic implications since these rocks were developed at the leading edge of the crustal block that was involved in collisional orogeny and subsequent extension during the final phase of assembly of the Gondwana supercontinent. We propose that the rocks were subjected to deep subduction and rapid exhumation, and the extreme thermal conditions were attained either through input from underplated mantle-derived magmas, or convective thinning or detachment of the lithospheric thermal boundary layer during or after crustal thickening.     

Marymia: an Archean, amphibolite facies-hosted, orogenic lode-gold deposit overprinted by Palaeoproterozoic orogenesis and base metal mineralisation, Western Australia

The Marymia gold deposit, comprising two orebodies, Keillor 1 and Keillor 2, is at the northern end of the Plutonic Well greenstone belt in the Marymia Inlier, in the southern Capricorn Orogen, just north of the Yilgarn craton. The Marymia Inlier is a discrete fault-bounded Archean gneiss-granitoid-greenstone domain surrounded by sedimentary basins that were formed and variably metamorphosed and deformed during several Palaeoproterozoic orogenic cycles. The greenstone sequence at Marymia is stratigraphically and geochemically similar to greenstone sequences in the Yilgarn craton, but was subjected to further deformation and metamorphism in the Palaeoproterozoic. Late Archean deformation (D1-D2) was ductile to brittle-ductile in style, whereas Palaeoproterozoic deformation was predominantly brittle. Equilibrium mineral assemblages indicate that peak amphibolite-facies metamorphism (540-575 °C, <3 kb) was overprinted by greenschist-facies metamorphism (300-360 °C). Petrographic textures indicate that prograde metamorphism was coeval with D1-D2, with peak metamorphism early to syn D2. Gold mineralisation at Marymia is hosted in metamorphosed tholeiitic basalts and banded iron formation. On a gross scale, the distribution of gold is controlled by D2 folds and shear zones. Lithological contacts with strong rheological or chemical contrasts provide local controls. Gold-related alteration comprises subtle millimetre- to centimetre-wide zones of silicification with variable amounts of quartz, hornblende, biotite, K-feldspar, plagioclase, calcite/siderite, scheelite, titanite, epidote, sulfide and telluride minerals. Quartz veins are generally narrow and discontinuous with low total volume of quartz. Gold is sited in the wall rock, at vein salvedges or within stringers of wall rock within veins. There are two distinct opaque-mineral assemblages: pyrite-pyrrhotite-chalcopyrite-galena and hessite-petzite-altaite-Bi-telluride-galena. Ore samples are variably enriched in Ag, Te, Pb, W, Cu, S and Fe reflecting heterogeneity of the ore mineralogy. Structural timing and temperature of formation of alteration and ore minerals support deposition of gold during late peak amphibolite-facies metamorphism from neutral to alkaline (pH=5-6), moderately oxidising (log P_O2,-21-22) and CO₂-bearing (X_CO2 Ƹ.2) fluids. The total sulfur content of the fluid is estimated at 1mDS. Lead isotope compositions support derivation of lead from within the local greenstone sequence. Gold lodes were deformed by faults and shear zones in the Palaeoproterozoic, with only limited remobilisation. Subeconomic, carbonate vein- and breccia-hosted base metal mineralisation is locally hosted within Palaeoproterozoic fault zones, which clearly cut gold lodes. Base-metal-related alteration is characterised by intense carbonatisation, chloritisation, and albitisation of the mafic host rocks. Mineral assemblages are consistent with formation at greenschist facies conditions. Lead isotope compositions support crystallisation at ca. 1.7 Ga from lead that is similar in composition to earlier gold-related galena.     

High-resolution sequence stratigraphy of the Lower Triassic ‘Buntsandstein’ in the Netherlands and northwestern Germany

Detailed log correlations of the largely fluvio-lacustrine Lower Triassic Buntsandstein (Late Permian-Early Anisian), carried out on 80 wells in the Dutch onshore and offshore areas, can be linked to northwest-German high-resolution sequence stratigraphy. The correlations show that cyclic sedimentation occurred in large parts of the basin. Seven 1st-order sequences are recognised, namely the Main Claystone, Rogenstein, Volpriehausen, Detfurth, Hardegsen, Solling and Lower Röt Sequences. They are overlain by the lower part of the Upper Röt–Lower Muschelkalk Sequence. Distinct sequence boundaries have been identified at the bases of four sequences: Volpriehausen, Detfurth, Solling and Upper Röt. The higher-order sequences consist of fining-upwards cycles with a thickness of up to tens of metres. The sequences are laterally persistent and have a characteristic expression on gamma-ray and sonic logs. In the Lower Buntsandstein, they display a uniform character throughout most of the area, with only minor differences in thickness or lithology. NNE-oriented lows and swells were formed during deposition of the Volpriehausen, Detfurth and Hardegsen Sequences. Uplift prior to the deposition of the Solling Sequence caused deep erosion on the swells in the basin and minor erosion in the lows. The high-resolution sequences probably represent alternating, relatively wet and dry climatic periods, with a periodicity of about 100 000 years. An analysis of the sequences suggests that their reduced thickness on the swells is mainly the effect of erosion. This is supported by analyses of the accumulation patterns and rates.     

The effect of naturally acidified irrigation water on agricultural volcanic soils. The case of Asembagus, Java, Indonesia

Acid water from the Banyuputih river (pH  3.5) is used for the irrigation of agricultural land in the Asembagus coastal area (East Java, Indonesia), with harmful consequences for rice yields. The river water has an unusual composition which is caused by seepage from the acidic Kawah Ijen crater lake into the river. This unique irrigation setting allows the study of soil acidification in situ. This paper assesses the effects of volcanogenically contaminated irrigation water on the chemical properties of the agricultural soils.The changes in soil properties were evaluated by comparing samples taken from the topsoil and sub-soil (1–3 m depth) from areas irrigated with acid water and areas irrigated with neutral water. The field survey thus resulted in four soil categories. Bulk soil composition, organic matter content, moisture content and particle size distribution were determined. Reactive phases were quantified with the selective extractions 1 M KCl, 0.1 M Na-pyrophosphate and 0.2 M acid ammonium oxalate (AAO).By comparing the four soil categories it is shown that the use of the naturally polluted irrigation water has had a large influence on the chemical composition of the topsoil. The composition of the soil solution has changed over the entire investigated soil profile. Furthermore the acid irrigation water has strongly modified the composition of the reactive phases, extracted as KCl, pyrophosphate, and AAO extractable elements, and also the bulk soil composition has been significantly modified. Overall this has resulted in the net dissolution of some elements and the net precipitation of others. The changes in the reactive phases and bulk soil composition are only apparent in the topsoil (0–20 cm) but not in the deeper soil.