Unique isoprene oxidation products demonstrate chlorine atom chemistry occurs in the Houston,Texas urban area

As part of the 2000 Texas Air Quality Study (TexAQS), we studied the isoprene oxidation process under ambient conditions to discern the presence of chlorine atom (Cl) chemistry in the Houston, Texas urban area. By measuring chloromethylbutenone (CMBO) and an isomer of chloromethylbutenal (CMBA), we clearly observed sixteen episodes of active Cl chemistry during the 24-day experiment. Estimated median Cl concentration during each of these episodes was between the detection limit of ~10² atoms cm⁻³ and 50 _{- 30} ^{+ 70} ×10⁴ 50_{ - 30}^{ + 70} \times {10^4} atoms cm⁻³. Cl concentration during all the episodes averaged 7.6 _{- 2.0} ^{+ 4.7} ×10⁴ 7.6_{ - 2.0}^{ + 4.7} \times {10^4} atoms cm⁻³ and thus amounted to less than 3% of the OH concentration during the same periods. During the episodes, the fraction of oxidation chemistry initiated by Cl ranged from 3–43% and was strongly dependent on the quantity and type of hydrocarbons present in the atmosphere. Because of its intermittent presence and low concentration, Cl is not a broadly influential oxidant in the Houston, Texas urban area.     

Theoretical meteorology and the operational meteorologist

Abstract

Values of incoming solar and long‐wave radiation measured at the vessel Quadra during the three phases of GATE are used to assess the daily performance of three models, one for solar and two for long‐wave radiation. The solar radiation model, which uses data on precipitable water and cloud amount at three levels in the atmosphere performed satisfactorily during the first phase but gave poor results in the other two phases when cumulonimbus became more dominant. Both the flux‐emissivity approach using measured and interpolated Upper air data and Paltridge's empirical procedure produced estimates of long‐wave radiation which compared very closely with the measurements.     

Stability functions based upon shear functions

The stability functions for momentum and heat under a Richardson number formulation are derived from the nondimensional shear functions under a Monin-Obukhov formulation. The Prandtl number is also derived as a function of the Richardson number. Previously, this has been done only in a limited sense. Because the Richardson number formulation is expressed in closed form, iterative techniques are no longer needed in numerical models that use Monin-Obukhov similarity theory. This time-saving approach is made possible by deriving expressions for the friction velocity and temperature in terms of the Richardson-number-dependent stability functions. In addition, the Richardson number approximation in the lowest layer is made to depend explicitly upon the surface roughness.     

Assessment of hydrological alterations on wandering beetle assemblages (coleoptera: Carabidae and Tenebrionidae) in coastal wetlands of arid Mediterranean systems

Changes in wandering beetle assemblages (Carabidae and Tenebrionidae) of different habitats situated in coastal wetlands of a Mediterranean arid area (Mar Menor, SE Spain) were analysed in 1984, 1992 and 2003 by pitfall trapping. Over two decades, the increase in irrigated lands at watershed scale led to rising water tables in the Mar Menor wetlands, which affected their beetle communities. These hydrological changes caused an increase in the carabid population, particularly in the sites most affected by flooding, where halobionts and halophiles, which were practically absent in 1984 and 1992, had become dominant by 2003. In contrast, tenebrionid assemblages simplified with time and by 2003 were dominated by one or two generalist species.     

Simulating the 1999 Capbreton canyon turbidity current with a Cellular Automata model

A numerical model has been developed for the simulation of turbidity currents driven by nonuniform, non cohesive sediment and flowing over a complex three dimensional submarine topography. The model is based on an alternative approach known as Cellular Automata paradigm. The model is validated by comparing a simulation with a reported field-scale event. The chosen case is a turbidity current which occurred in Capbreton Canyon and was initiated by a storm in December 1999. Using data from recent oceanographic cruises, the deposit of the event has been precisely described, which constrain values of model parameters. The model simulates the 1999 turbidity current over the actual canyon topography and related turbidite using three different types of particle. The model successfully simulates areas of erosion and deposition in the canyon. It predicts the vertical and longitudinal grain size evolution, and shows that the fining-up sequence can be deposited by several phases of deposition and erosion related to the current energetic variation during its evolution. This result could explain the presence of intrabed contacts or the frequent lack of facies in Bouma sequences.     

A new interpretation of terraces in the Taranto Gulf: the role of extensional faulting

The Taranto Gulf of southern Italy provides an excellent case where it is possible to document the importance of normal faults in displacing terraced deposits. The study area is located at the front of the southern Apennines, that is a fold-and-thrust belt developed following the closure of the Mesozoic Tethys Ocean, and the deformation of the Adriatic passive margin during Tertiary and Quaternary times. The outer, eastern parts of the belt were structured in Quaternary, i.e. up to Middle Pleistocene times.The front of the chain is partially sealed by Pliocene–Pleistocene foredeep deposits, which represent the infill of the Bradanic Trough. The upper portion of the middle Pleistocene succession consists of marine sands and conglomerates that in the previous literature have been arranged in several orders of terraces. Analysis of aerial photographs and geomorphological mapping has shown the occurrence of prominent geomorphic lineaments, which appear to control the local drainage pattern. Some of these structures coincide with the map trace of normal faults that produce vertical offsets of the marine terrace surfaces in the order of ca. 10 m each. Many of the fault escarpments reduce their elevation and terminate laterally. In other cases fault escarpments are laterally continuous and can be traced for up to 3–4 km. Scarp height is between 2 and 10 m. Their mean trend ranges from NNE–SSW to ENE–WSW and defines an arcuate pattern that mimics the present coastline.An accurate geomorphological, sedimentological and stratigraphic analysis has been carried out in a selected area of the Bradanic Trough (Pisticci transect) to investigate in detail the relationships between normal faults and the development of the terraces. This analysis allowed us to recognise five facies associations related to the upper and lower beachface and to the neritic clays which represent the substratum of the terraces. More importantly, we observed that all the terraced deposits in the Pisticci transect could be referred to a single sedimentary body displaced by faults. The terraced deposits are related to an event of beach progradation, of Middle Pleistocene age, which has been documented in other areas of the Italian peninsula. These results outline an intimate relationship between the arcuate trend of the recognised fault set and the present coastline pattern. The development of the normal faults can be related to large-scale gravitational processes developed after the general tilting towards the SE of the Bradanic Trough.