Evolution of 2:1 layered silicates in low-grade metamorphosed Liassic shales of Central Switzerland

White mica from the Liassic black shales and slates in Central Switzerland was analysed by transmission electron microscopy (TEM) and electron microprobe to determine its textural and compositional evolution during very low-grade prograde metamorphism. Samples were studied from the diagenetic zone, anchizone and epizone (T ≈100°–450 °C). Phyllosilicate minerals analysed include illite/smectite (I/S), phengite, muscovite, brammallite, paragonite, margarite and glauconite. Textural evolution primarily is towards larger, more defect-free grains with compositions that approach those of their respective end-members. The smectite-to-illite transformation reduced the amounts of the exchange components SiK_?1Al_?1, MgSiAl_?2, and Fe³⁺Al_?1. These trends continue to a lesser degree in the anchizone and epizone. Correlations between the proportion of smectite in I/S and the composition of I/S indicate that smectite layers may contain a high layer charge. Illite in I/S bears a compositional resemblance to macrocrystalline phengite in some samples, but is different in others. Paragonite first appears in the upper diagenetic zone or lower anchizone as an interlayer-deficient brammallite, and it may be mixed with muscovite on the nanometre scale. Owing to the small calculated structure factor for paragonite-muscovite superstructures, conventional X-ray powder diffraction cannot distinguish between mixed-layer structures and a homogeneous compositionally intermediate solid solutions. However, indirect TEM evidence shows that irregularly shaped domains of Na- and K-rich mica exist below 10 nm. Subsequent coarsening of domains at higher grades produced discrete paragonite grains at the margins of muscovite crystals or in laths parallel to the basal plane of the host muscovite. Margarite appears in the epizone and follows a textural evolution similar to paragonite in that mixtures of margarite, paragonite, and muscovite may initially occur on the nanometre scale. However, no evidence of interlayer-poor margarite has been found.     

Simulations of deep pencil-beam redshift surveys

We create mock pencil-beam redshift surveys from very large cosmological N -body simulations of two cold dark matter (CDM) cosmogonies, an Einstein–de Sitter model ( τ CDM) and a flat model with Ω₀=0.3 and a cosmological constant (ΛCDM). We use these to assess the significance of the apparent periodicity discovered by Broadhurst et al. Simulation particles are tagged as 'galaxies' so as to reproduce observed present-day correlations. They are then identified along the past light-cones of hypothetical observers to create mock catalogues with the geometry and the distance distribution of the Broadhurst et al. data. We produce 1936 (2625) quasi-independent catalogues from our τ CDM (ΛCDM) simulation. A couple of large clumps in a catalogue can produce a high peak at low wavenumbers in the corresponding one-dimensional power spectrum, without any apparent large-scale periodicity in the original redshift histogram. Although the simulated redshift histograms frequently display regularly spaced clumps, the spacing of these clumps varies between catalogues and there is no 'preferred' period over our many realizations. We find only a 0.72 (0.49) per cent chance that the highest peak in the power spectrum of a τ CDM (ΛCDM) catalogue has a peak-to-noise ratio higher than that in the Broadhurst et al. data. None of the simulated catalogues with such high peaks shows coherently spaced clumps with a significance as high as that of the real data. We conclude that in CDM universes, the regularity on a scale of ∼130  h ⁻¹ Mpc observed by Broadhurst et al. has a priori probability well below 10⁻³.     

Dynamical and compositional assessment of near‐Earth object mission targets

Abstract— Using an H‐plot analysis, we identify 234 currently known near‐Earth objects that are accessible for rendezvous with a “best case” delta‐V of less than 7 km/s. We provide a preliminary compositional interpretation and assessment of these potential targets by summarizing the taxonomic properties for 44 objects. Results for one‐half (22) of this sample are based on new spectroscopic measurements presented here. Our approach provides an easy‐to‐update method for giving guidelines to both observers and mission analysts for focusing on objects for which actual mission opportunities are most likely to be found. Observing prospects are presented for categorizing the taxonomic properties of the most accessible targets that are not yet measured.     

Depositional and post‐depositional history of warm stage deposits at Knocknacran,Co. Monaghan,Ireland: implications for preservation of Irish last interglacial deposits

Organic‐rich deposits, uncovered during overburden removal from mantled gypsum karst at Knocknacran opencast gypsum mine, Co. Monaghan, are the best candidate to date for a last interglacial record in Ireland. The two till and organic‐rich deposits (preserved at different quarry elevations) were emplaced on to a Tertiary dolerite surface during high‐energy flood events and subsequently folded and faulted by movement towards sinkholes in underlying gypsum. Uranium–thorium disequilibrium dating suggests that the organic‐rich deposits in the upper section were hydrologically isolated at ca. 41 ka and those in the lower section at ca. 86 ka. Interpretation of the pollen content, although tentative because of the depositional and post‐depositional history of the material, suggests that the organic material originated in a warm stage possibly warmer than the post‐Eemian interstadials. The unusual setting of preservation may indicate that in situ, last interglacial deposits have generally been removed by erosion in Ireland. Copyright © 2004 John Wiley & Sons, Ltd.     

Is the Kolmogoroff model applicable to large-scale turbulence?

We discuss the difficulties encountered when the Heisenberg-Kolmogoroff model for turbulence is applied to the large-scale turbulence in: (A) molecular clouds (specifically the velocity vs size relationship) and (B) stars (specifically, the estimate of convective fluxes).A new model for large-scale turbulence is, therefore, needed.     

The apparent copper complexing capacity of seawater and the interaction of copper with humic matter

The anodic stripping voltammetry with physically-coating mercury film electrode was used to investigate the complexing action of trace heavy metals in seawater with organic ligands. The apparent copper complexing capacity of seawater was determined by titrating the organic ligands in natural seawater with standard ionic copper solution. The complexing actions of copper in seawater with humic acid (HA) or fulvic acid (FA) were investigated by titrating copper in seawater with HA or FA solution. The equilibrium time, electrodeposition potential, and effect of pH etc. were investigated respectively. The results show that the interaction of copper in seawater with organic matter is a fast process. At natural pH, HA or FA tend to act with copper in seawater to form nonlabile complexes. During experimental electrode process, these complexes did not significantly dissociate. The experimental results were calculated according to 1∶1 complex formation.     

Gravitational collapse of a dust ball — The external observer's point of view

The problem of collapse of a dust ball has been studied in detail from the point of view of an external observer (O). It is seen that although there is no material pressure from the point of view of the comoving observer, there is a non-vanishing material pressure in the ball from the point of view of O. In the early stages of collapse (w.r.t. O), this pressure is positive everywhere inside the ball, while during the later stages, if one goes outwards from the centre towards the surface of the ball, this pressure is negative up to a certain value of the radial coordinate, and then changes its sign thereafter. On the basis of this pressure, one can understand the physics of the whole scenario of collapse w.r.t. O; in particular, the important feature is that in the ultimate stages an event horizon is formed asymptotically and there is no collapse to a point (as takes place from the point of view of the comoving observer).