Biogeochemical Modelling of a Seasonally Anoxic Lake: Calibration of Successive and Competitive Pathways and Processes in Lake Aydat,France

A reactive transport model was developed to describe seasonal variations of biogeochemical and physical processes in Lake Aydat. The model includes physical processes such as vertical mixing, sedimentation and advection related to inflows into the lake and biogeochemical conversion processes in the water column and in the sediment surface layer. The reactions described in the model include primary redox reactions such as primary production, aerobic and anaerobic respiration, methanogenesis and secondary reactions established between oxidants and reducers produced by the primary reactions. After adjusting various kinetic constants, the model reasonably reproduced the main features of seasonal variations of dissolved oxygen and nitrate depth profiles and pH. The reactive transport model was also used to quantify the relative importance of different biogeochemical pathways. For instance, ferrous denitrification seems to play an important role when stratification is increasing.     

Experimental investigation of the harmonic generation by waves over a submerged plate

Experiments in a wave flume have been performed to analyse the nonlinear interaction between regular gravity waves and a submerged horizontal plate used as breakwater. A new method, based on the Doppler shift generated by a moving probes, has been used to discriminate the incident fundamental mode and the reflected fundamental mode. The relationships of the reflection and transmission coefficients to the wave number at different submergence depth ratios are presented. The accurate discrimination, by this method, of the phase-locked and free modes allows the quantification of the higher harmonics generated by the breakwater and the analysis of the nonlinear interaction between the waves and the submerged plate. The transfer of energy from the fundamental mode to higher harmonics is very large in the cases of small submergence depth ratios. The vortices produced at the edges take part in the production of higher harmonics by interaction with the free surface but involve, at the same time, a dissipation process that increases the efficiency of the breakwater.     

Species, tissue and gender-related organochlorine bioaccumulation in white-sided dolphins, pilot whales and their common prey in the northwest Atlantic

Organochlorine concentrations were measured in white-sided dolphins, pilot whales, and their prey from the Gulf of Maine and used to identify species, tissue, and gender differences, and trophic transfer trends, in bioaccumulation. Polychlorinated biphenyl concentrations ([PCB]) in dolphin blubber (13 +/- 7.1 micrograms/g fresh wt.) were twice those in pilot whales, but pesticide concentrations (20 +/- 13 micrograms/g fresh) were similar between species. 4,4'-DDE, trans-non-achlor, Cl6(153) and Cl6(138) concentrations were highest. Skin tissues had more recalcitrant organochlorines than the internal organs. Male dolphins bioaccumulated higher concentrations of nonmetabolizable PCBs and hexachlorocyclohexane (HCH) isomers, whereas pilot whales had no gender-related differences in bioaccumulation. Pilot whales, mackerel, and herring had proportionately higher concentrations of DDTs, whereas [PCB] were higher in dolphins and squid. Although these odontocetes feed at the same trophic level and store a similar suite of contaminants, dolphins bioaccumulated higher and potentially hazardous 4,4'-DDE and PCB concentrations from food in their more geographically restricted range.     

Interannual and decadal variability in zooplankton communities of the southeast Bering Sea shelf

The southeastern Bering Sea shelf ecosystem is an important fishing ground for fin- and shellfish, and is the summer foraging grounds for many planktivorous seabirds and marine mammals. In 1997 and 1998, Northern Hemisphere climate anomalies affected the physical and biological environment of the southeastern Bering Sea shelf. The resulting anomalous conditions provided a valuable opportunity to examine how longer-term climate change might affect this productive ecosystem. We compared historical and recent zooplankton biomass and species composition data for the southeastern Bering Sea shelf to examine whether or not there was a response to the atmosphere–ocean–ice anomalies of 1997 and 1998. Summer zooplankton biomass (1954–1994) over the southeastern shelf did not exhibit a decline as previously reported for oceanic stations. In addition, zooplankton biomass in 1997 and 1998 was not appreciably different from other years in the time series. Spring concentrations of numerically abundant copepods (Acartia spp., Calanus marshallae, and Pseudocalanus spp.), however, were significantly higher during 1994–1998 than 1980–1981; spring concentrations of Metridia pacifica and Neocalanus spp. were not consistently different between the two time periods. Neocalanus spp. was the only taxon to have consistent differences in stage composition between the two time periods—CV copepodites were much more prevalent in May of the 1990s than early 1980s. Since relatively high zooplankton concentrations were observed prior to 1997, we do not attribute the high concentrations observed in the summers of 1997 and 1998 directly to the acute climate anomalies. With the present data it is not possible to distinguish between increased production (control from below) and decreased predation (control from above) to explain the recent increase in concentrations of the species examined.     

On the nature of the calcareous substrate of a ferromanganese crust from the Vityaz Fracture Zone, Central Indian Ridge: inferences on paleoceanography

A 15-cm-thick carbonate substrate encrusted with ferromanganese oxides from the Vityaz Fracture Zone, Central Indian Ridge was analyzed to reconstruct the paleoceanography of the region. Based on the calcareous nannoplankton assemblage, an early Pliocene age has been assigned to the calcareous substrate. Among the nannoplankton, discoasters outnumber coccoliths and show signs of dissolution. The presence of certain species of benthic Foraminifera such as Uvigerina, Lenticulina, Bulimina and Bolivina, indicates the infringement of the oxygen minimum zone during the deposition of the carbonates. The occurrence of a Reticulofenestra pseudoumbilica zone of early Pliocene age suggests a change in depositional conditions coinciding with the time of formation of the large depositional hiatuses documented in sediment cores from adjacent basins of the western Indian Ocean. These hiatuses resulted from the prevalence of intermediate subsurface currents such as the Somali Current or the Western Boundary Current.     

High-resolution sediment echosounding off Peru: Late Quaternary depositional sequences and sedimentary structures of a current-dominated shelf

About 6000 km of both bathymetric and high-resolution acoustic profiles were acquired on the shelf and upper slope offshore Peru between 9° S and 14° S. Two new sediment echosounder systems – SEL-96 and SES-2000DS – provided details of the sedimentary structures of the Quaternary sequences within the Sechura-Salaverry, Huacho and Pisco Basins. To a great extent, the poleward undercurrent determines the distribution of sediments. The undercurrent has generated numerous erosional unconformities, it has winnowed hardgrounds and has created mudwaves common between 250 m and 400 m water depth. Distinct subbottom reflectors within sedimentary units represent hiatuses due to periods of intensified winnowing or non-deposition. Erosional unconformities usually marked by pronounced reflectors suggest shifts of the undercurrent system related to climatic changes and eustatic variations of sea level. On a larger scale, the stacked prograding depositional sequences reflect the sea-level cycles of the Middle Pleistocene to the Holocene. Based on the stratigraphy of our piston cores and that of Ocean Drilling Program (ODP) Site 680, the depositional sequences limited by extended unconformities were assigned to oxygen isotope stages 1 to 7. Other sedimentary structures are small straight channels that were conduits for downslope sediment transport. Deformed sediments associated with synsedimentary normal faults result from creep movements indicating beginning slope failure.     

Distribution of nonlinear wave crests

The distribution of nonlinear wave crests is examined on the basis of a theoretical probability density previously given elsewhere (J. Eng. Mech. 120 (1994) 1009). Certain errors contained in the original theoretical density are corrected, and the corresponding exceedance distribution is derived. The resulting theoretical forms of the probability density and exceedance distribution are then slightly simplified and compared with nonlinear wave data gathered under hurricane conditions. The results indicate that the proposed theoretical forms describe the observed distributions of large wave crests better than the Rayleigh law. However, the quantitative accuracy of the predictions is somewhat poor, as is typical of approximate theories based on Gram–Charlier-type expansions.     

Breaking wave impact on vertical and sloping coastal structures

The results of laboratory experiments on the maximum and bottom impact pressures from waves breaking directly on vertical and sloping faced coastal structures are presented. Direct wave breaking on a wall is classified as early, late, and perfect breaking. Although the present study is aimed at dealing with the type of impact resulting from the perfect breaking, to some extent the occurrence of early and late breaking are unavoidable. The wave impact pressures, therefore, have a random nature of variation from impact-to-impact under the same conditions. The maximum and bottom impact pressures on walls are treated statistically. The effects of the wall angle and foreshore slope on these two quantities are examined. The results show that for practical applications, the still-water level can be taken as the acting place for the maximum impact pressure on the wall. Simultaneous impact pressure distribution below and above still-water level may be approximated as parabolic and linear, respectively. Finally, using a wall deflection criterion, a water depth region in front of the wall is defined, where the breaking wave forces may reach a critical level.