Microtextures and crystal chemistry in P21/c pigeonites

Summary ?A single-crystal X-ray investigation was performed on crystals of P2₁/c natural pigeonite with varying Ca and Fe^* ( = Fe²⁺ + Mn²⁺) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae. The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated. The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples. In particular, it is shown that Ca and Fe^* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and decrease the difference between the M2–O3 distances. Received October 18, 2001; revised version accepted February 15, 2002     

Ionprobe U-Pb zircon ages from the high-pressure/low-temperature mélange of Syros, Greece: age diversity and the importance of pre-Eocene subduction

The Cycladic blueschist belt in the central Aegean Sea has experienced high‐pressure (HP) metamorphism during collisional processes between the Apulian microplate and Eurasia. The general geological and tectonometamorphic framework is well documented, but one aspect which is yet not sufficiently explored is the importance of HP mélanges which occur within volcano‐sedimentary successions. Unresolved issues concern the range in magmatic and metamorphic ages recorded by mélange blocks and the significance of eventual pre‐Eocene HP metamorphism. These aspects are here addressed in a U‐Pb zircon study focusing on the block–matrix association exposed on the island of Syros. Two gneisses from a tectonic slab of this mélange, consisting of an interlayered felsic gneiss‐glaucophanite sequence, yielded zircon ²⁰⁶Pb/²³⁸U ages of 240.1 ± 4.1 and 245.3 ± 4.9 Ma, respectively, similar to Triassic ages determined on zircon in meta‐volcanic rocks from structurally coherent sequences elsewhere in the Cyclades. This strongly suggests that parts of these successions have been incorporated in the mélanges and provides the first geochronological evidence that the provenance of mélange blocks/slabs is neither restricted to a single source nor confined to fragments of oceanic lithosphere. Zircon from a jadeitite and associated alteration zones (omphacitite, glaucophanite and chlorite‐actinolite rock) all yielded identical ²⁰⁶Pb/²³⁸U ages of c. 80 Ma. Similar Cretaceous U‐Pb zircon ages previously reported for mélange blocks have been interpreted by different authors to reflect magmatic or metamorphic ages. The present study adds a further argument in favour of the view that zircon formed newly in some rock types at c. 80 Ma, due to hydrothermal or metasomatic processes in a subduction zone environment, and supports the interpretation that the Cycladic blueschist belt records both Cretaceous and Eocene HP episodes and not only a single Tertiary HP event.     

Size and shape evolution of pores in a viscoplastic matrix under compression

The frequent use of soils and earth materials for hydraulic capping and for geo‐environmental waste containment motivated our interest in detailed modelling of changes in size and shape of macro‐pores to establish links between soil mechanical behaviour and concurrent changes in hydraulic and transport properties. The objective of this study was to use finite element analysis (FEA) to test and extend previous analytical solutions proposed by the authors describing deformation of a single macro‐pore embedded in linear viscoplastic soil material subjected to anisotropic remote stress. The FEA enables to consider more complex pore geometries and provides a detailed picture of matrix yield behaviour to explain shortcomings of approximate analytical solutions. Finite element and analytical calculations agreed very well for linear viscous as well as for viscoplastic materials, only limited for the case of isotropic remote stress due to the simplifications of the analytical model related to patterns and onset of matrix‐yielding behaviour. FEA calculations were compared with experimental data obtained from a compaction experiment in which pore deformation within a uniform modelling clay sample was monitored using CAT scanning. FEA predictions based on independently measured material properties and initial pore geometry provided an excellent match with experimentally determined evolution of pore size and shape hence lending credence to the potential use of FEA for more complex pore geometries and eventually connect macro‐pore deformation with hydraulic properties. Copyright © 2006 John Wiley & Sons, Ltd.     

Ocean-floor hydrothermal metamorphism in the Limousin ophiolites (western French Massif Central): evidence of a rare preserved Variscan oceanic marker

The Limousin ophiolite is located at the suture zone between two major thrust sheets in the western French Massif Central. This ophiolitic section comprises mantle‐harzburgite, mantle‐dunite, wehrlites, troctolites and layered gabbros. It has recorded a static metamorphic event transforming the gabbros into undeformed amphibolites and the magmatic ultramafites into serpentinites and/or pargasite‐bearing chloritites. With various thermobarometric methods, it is possible to show that the different varieties of amphibole have registered low‐P (c. 0.2 GPa) conditions with temperature ranging from high‐T, late‐magmatic conditions to greenschist–zeolite metamorphic facies. The abundance of undeformed metamorphic rocks (which is typical of the lower oceanic crust), the occurrence of Ca–Al (–Mg) metasomatism illustrated by the growth of Ca–Al silicates in veins or replacing the primary magmatic minerals, the P–T conditions of the metamorphism and the numerous similarities with oceanic crustal rocks from Ocean Drilling Program and worldwide ophiolites are the main arguments for an ocean‐floor hydrothermal metamorphism in the vicinity of a palaeo‐ridge. Among the West‐European Variscan ophiolites, the Limousin ophiolites constitute an extremely rare occurrence that has not been involved in any HP (subduction‐related) or MP (orogenic) metamorphism as observed in other ophiolite occurrences (i.e. France, Spain and Germany).     

Estimation of dispersion in estuaries by a self-consistent method

Longitudinal and transverse dispersion in estuaries may be determined in principle by measuring the change in time of the concentration field of a water soluble dye. In practice, measurements may take the form of several sampling runs crossing the dye patch. The coefficients of dispersion are usually estimated from the second moments of the concentration field; the use of second moments, in particular, introduces errors because measurements at long times or distance are unduly emphasized.A self-consistent method, free of the disadvantages inherent in the use of higher moments, is described in which the distribution of concentration in space is related to the zeroth spatial moment of concentration. In this formulation, based upon sampling runs across the dye patch, the concentration field in the estuary may be directly and simply related to the dispersion coefficients in both the intercept and gradient of a linear graph.The methods are illustrated by the characterization of a series of experiments in the Inner Estuary of Milford Haven.     

Seasonal variations in prey selection by estuarine black-headed gulls (Larus ridibundus)

The number of black-headed gulls (Larus ridibundus) in the Clyde Estuary is large. In summer the average density has reached 1350 gulls km^?2 and in winter 180 gulls km^?2. This paper compares prey selection and feeding efficiency in gulls during summer and winter on tidal flats, and considers how seasonal differences may be adaptations to cope with seasonal changes in prey availability.Gross and net rates of energy intake were highest in summer because gulls captured more of the polychaete N. diversicolor than the amphipod C. volutator. In winter, gulls selected for C. volutator and therefore an energetically less profitable diet. Throughout the year gulls selected more C. volutator relative to N. diversicolor than expected on energetic grounds and so apparently did not maximize potential net rate of energy intake.Gulls used three techniques to capture prey and made most intensive use of the ‘crouch’ technique. Crouching gulls attained a much higher net rate of energy intake than ‘upright’ or ‘paddling’ gulls.A log-linear model showed that (a) season, water depth and gull density determined feeding technique and (b) feeding technique and season independently determined foraging success and prey selection. Thus gull density and water depth acted on prey selection through imposed variations in feeding technique.Reasons for gulls selecting energetically unprofitable C. volutator and for the use of several distinct feeding techniques are discussed.     

Deep-ocean piezometer probe technology for geotechnical investigations

Two single-sensor piezometer probes, 8 mm in diameter, were developed for deep-ocean geotechnical investigations. These probes were tested in a hyperbaric chamber pressurized to 55 MPa (8000 psi). Testing was performed for a period of five weeks under high hydrostatic pressure with the probes inserted in reconstituted illitic marine sediment. Small differential pore-water pressures were generated in response to both mechanically and thermally generated forcing functions. During deep-ocean simulated pressure tests, the sensors exhibited excellent sensitivity and stability. These developments in piezometer-probe technology provide a quantitative means of assessing important geotechnical parameters of fine-grained seabed deposits.     

Generalized strain probing of constitutive models

Advanced material constitutive models are used to describe complex soil behaviour. These models are often used in the solution of boundary value problems under general loading conditions. Users and developers of constitutive models need to methodically investigate the represented soil response under a wide range of loading conditions. This paper presents a systematic procedure for probing constitutive models. A general incremental strain probe, 6D hyperspherical strain probe (HSP), is introduced to examine rate‐independent model response under all possible strain loading conditions. Two special cases of HSP, the true triaxial strain probe (TTSP) and the plane‐strain strain probe (PSSP), are used to generate 3‐D objects that represent model stress response to probing. The TTSP, PSSP and general HSP procedures are demonstrated using elasto‐plastic models. The objects resulting from the probing procedure readily highlight important model characteristics including anisotropy, yielding, hardening, softening and failure. The PSSP procedure is applied to a Neural Network (NN) based constitutive model. It shows that this probing is especially useful in understanding NN constitutive models, which do not contain explicit functions for yield surface, hardening, or anisotropy. Copyright © 2004 John Wiley & Sons, Ltd.     

Methods of array element localization for a towed underwateracoustic array

The location of the hydrophones on a towed underwater acoustic array as a function of time (array element localization) is needed for signal processing. Methods to perform this localization using least squares polynomial fitting to data from depth sensors, heading sensors, and sensors detecting a ping from a single source are discussed. Arc distance along the array is used as the independent parameter so that all solutions are constrained to be space curves. Examples of application to real data are presented, and techniques to discriminate against bad sensor data are discussed