Crystal-Mush Compaction and the Origin of Pegmatitic Segregation Sheets in a Thick Flood-Basalt Flow in the Mesozoic Hartford Basin, Connecticut

Where the Holyoke flood-basalt flow in the Mesozoic HartfordBasin in Connecticut is thick and contains coarse-grained, horizontalsegregation sheets in its central part, the lower part of theflow is strongly depleted in incompatible elements; where theflow is thin and contains no segregation sheets it is homogeneousthroughout. This chemical variation can be explained only throughcompaction of the partly crystallized basalt. The compositionof the segregation sheets shows that they separated from thebasalt following only 33% crystallization. The segregation sheets,however, are clearly intrusive into the basalt, which must thereforehave already formed a crystal mush with finite strength at thislow degree of crystallinity. The incompatible element concentrationsindicate that the partly crystallized basalt underwent as muchas 28% compaction in the lowest 60 m of the flow. Between 60and 130 m above the base of the flow, the crystal mush becamedilated, and eventually ruptured with formation of the segregationsheets. No segregation sheet has a composition indicating separationafter more than 33% crystallization of the basalt. This is interpretedto indicate that compaction ceased at this stage because ofthe increasing strength of the mush and the increasing densityof the fractionating interstitial liquid KEY WORDS: crystal-mush compaction; segregation shtets; flood basalt; tholeiitie; Connecticut ^*e-mail: philpotts{at}geol.uconn.edu     

Winter severity in Europe: The fourteenth century

The fourteenth century is known to include a period of winter cooling in Central and Western Europe, but its timing and magnitude are not clearly established. An attempt to obtain a coherent picture from verified documentary evidence yielded 2133 records from a region covering Central Europe and Northern Italy, mostly originating from the Monumenta Germaniae Historica. Temperatures were assessed using semi-quantitative indices on the basis of proxy information on snow-cover, ice and untimely activity of vegetation. Results: A run of cold winters from 1303 to 1328 was followed by a run of average winters up to 1354. Then winter temperatures were extremely variable up to 1375. For the rest of the century they fluctuated somewhat below the average of the twentieth century. The pattern in the first five decades is compared to that in the Late Maunder Minimum (1675–1715). The possible role of forcing factors (variations in solar output, North Atlantic Deep Water formation) is briefly discussed.     

Italian zeolitized rocks of technological interest

Large areas of Italian territory are covered by thick and widespread deposits of zeolite-bearing volcaniclastic products. The main zeolites are phillipsite and chabazite spread over the whole peninsula, and clinoptilolite recorded only in Sardinia. A trachytic to phonolitic glassy precursor accounts for the formation of the former zeolites characterized by low Si/Al ratios (3.00), while clinoptilolite is related to more acidic volcanism. The genesis of most of these zeolitized deposits is linked to pyroclastic flow emplacement mechanisms characterized by quite high temperatures and by the presence of abundant fluids. The main utilization of these materials has been and still is as dimension stones in the building industry. Currently, limited amounts are also employed in animal farming (dietary supplement, pet litter and manure deodorizer) and in agriculture as soil improvement and slow-release fertilizers. New fields of application have been proposed for these products on account of their easy availability, very low cost, their high-grade zeolites (50–70%), and good technological features such as high cation exchange capacities and adsorption properties.     

Natural zeolites as cation exchangers for environmental protection

This study describes the state-of-the-art with regard to the use of natural zeolites in the protection of the environment. The review is made up of four main sections. The first introduces the possible cation exchange procedures that can be operated at an industrial level, together with the principles on which they are based. The second deals with removal of NH ₄ ⁺ from municipal and industrial wastewater, reporting operational results from the main industrial-scale plants, together with the most significant and recent laboratory data. The third points out the possibilities for use of natural zeolites for removal of heavy metals from water after laboratory experiments. The fourth shows how chemical and structural features make zeolites a very powerful tool for the decontamination of waters containing radionuclides.     

Trace metals in suspended particulate matter and in sediment trap material from a permanently anoxic fjord — Framvaren, South Norway

Geochemical studies of the trace metal concentrations in suspended particulate matter (SPM) and sediment trap material from a permanently anoxic fjord, Framvaren, South Norway in 1989 and 1993 indicate that extremely high concentrations of zinc (max = 183920 mg/kg), copper (max = 4130 mg/kg), lead (max = 2752 mg/kg), and cadmium (max= 8.1 mg/kg) sometimes (1993) occur in the SPM collected in the anoxic water layer. The highest concentrations of Zn occur just below the redoxcline at 22 m water depth (in 1993), and copper, lead and cadmium have maximum concentrations between 30 and 80 m depth, where the amount of total SPM is at a minimum (about 0.3 mg/L). On a mass per volume (g/L) basis, the maximum concentrations of Cd, Cu and Fe occur at the interface (21m) and those of Zn occur just below the redoxcline (22 m depth). The SPM and sediment trap data suggest that the metals are precipitated as sulfide minerals in the anoxic water. The presence of particulate sulfides was confirmed by SEM studies that show the occurrence of discrete metal (Cu, Fe, Pb, and Zn) sulfide particles in size from 10–20 m as well as framboidal pyrites (1–5 m in size). Higher levels of metal sulfides at intermediate depths rather than in the deep water of Framvaren (> 100 m), may be due to input of trace metals by water exchange over the sill in the upper part of the water column. In the deep water, less metal sulfide precipitation takes place due to depletion of trace metals, and the dilution of particulate metal concentrations by organic matter and by the chemogenic formation of calcite.     

The contact binary system YY Eri

Relatively new and unanalysed photometric data-sets of the contact binary system YY Eri are presented. The light curves have been analysed using information limit optimization techniques, and the Binary Maker program of Bradstreet (1992).Comparison of the results allows insight into determinacy questions affecting the W UMa type of light curve, which relates to our general understanding of contact binaries. A limiting contact configuration cannot be ruled out on the basis of empirical data-analysis alone.Very careful analysis of the photospheric flux distribution over the surface of the Sun may help establish appropriate values of the gravity brightening parameter for cool dwarf stars. At present, however, empirical photometric information on contact binaries is non-discriminatory: i.e. alternative cosmogonies can find alternative support from available evidence. The implication is then for more and better observational data to allow better real independent parameter determination.     

Motion of test particles in parabolic density distributions

A detailed study of the motion of test-particles [either having a nonzero rest-mass or zero rest-mass] has been carried out for Tolman's type VII solution with vanishing surface density, which is one of the few physically relevant exact solutions of Einstein's field equations for static and spherically symmetric mass distributions.The trapping angles, 0, at which the test-particles escape these configurations are calculated and the trajectories of test-particles are studied in detail. The types of trajectories found for this spacetime geometry are: (1) arc-like trajectories, (2) spiral-like trajectories ending into a circle of constant radius, (3) trajectories with a cusp at the minimum distance, (4) double-bounded trajectories, and (5) double-bounded trajectories with a cusp at the minimum distance. The test-particles following the trajectories of type (1) and type (3) escape the configuration while others are trapped within the structure. Besides the advancement of periastron of the orbits the retrogradation of periastrons are also observed.The stability of the structures is considered by using the variational method (Chandrasekhar, 1964a,b), and its is seen that the structures remain stable at least for a central redshift,z0, as large as 5.09.These studies may distinguish relativistic cluster from a Newtonian one and may find application to the local models of quasi-stellar objects (QSOs).     

A quantitative analysis of the prototype [WCL] star CPD-56° 8032

We present a detailed, quantitative study of the standard [WC10] Wolf-Rayet central star CPD-56^o 8032 based on new high resolution AAT UCLES observations and the Hillier (1990) WR standard model. Our analysis of CPD-56^o 8032 gives the wind properties (T _*=34500K, lg (L/L )=3.8, lg (M/M a^–1)=–5.4,v =225 km s^–1) and chemistry (C/He=0.5, O/He=0.1, by number), the latter suggesting an intimate relationship with the Ovi PN central stars and the PG 1159-035 objects. A comparison between the wind properties of CPD-56^o 8032 and Sk-66^o 40 (WN 10) indicates that low excitation, low wind velocity WR winds are common to both low mass PN central stars (WC sequence) and high mass post-LBV's (WN sequence).     

A model of an exploding,radiating star in general relativity

In a previous paper Adams, Cary and Cohen (1994) presented a model of a supernova. In that paper the equations of General Relativity describing the evolution of a spherically symmetric, radiating star were solved analytically. The evolution of the star was determined by the application of boundary conditions at the center and at the edge. Due to lmitations in the presupernova model, only the very slow inward motion of an unstable, degenerate core could be considered. The solution was also limited by the need to exclude a runaway term, one that increased exponentially with time. Without the exclusion of the runaway, the luminosity would have increased without bound and the mass would have become negative.This paper presents a completely analytic solution to the equations of General Relativity describing the evolution of a Type II supernova. Professor S.E. Woosley kindly gave us data on the physical variables of a 12M ₀ presupernova star. In our model the core collapses within 1 s, leaving a 1.3M ₀ remnant. Shortly afterward 10.6M ₀ is ejected to infinity, and 0.17M ₀ is radiated away in the form of neutrinos. The distance of the edge from the center increases proportionally to the two-thirds power of the time. The luminosity decreases proportionally to the inverse four-thirds power.Although the runaway solution was modified by the exploding rather than a static envelope, it must still be excluded by adjusting initial conditions. Its character is changed from an exponential to a very large power (55) of time. The removal of a degree of freedom by this exclusion leads to physically non-sensical results such as negative luminosity. The inclusion of a term describing motion of the mantle due to neutrino interactions provides the additional degree of freedom necessary for physically reasonable results.     

Wound magnetostatics and flaring

We discuss the winding of a force-free axisymmetric magnetic field rooted on a heavy conductor onz=0. In quadrupolar symmetry the field expands in the half-spacez>0 and the toroidal flux concentrates on a conical surface. After a mean twist of 208°, the conical layer hosts large toroidal current loops with reversal of the magnetic flux on either side. The evolution of the field structure is described by scale-free static solutionsBr ^–(p+2), withp taking values between 0 and 2. The large expansion factor of the field structure is suggestive of flaring originating on the solar photosphere.