The stable isotope signature of kilometre-scale fracturedominated metamorphic fluid pathways, Mary Kathleen, Australia

Abstract Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 10- to 100-m-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 × 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have δ¹³C_calcite values of –2 to –7% and δ¹⁸O_calcite values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have δ¹⁸O_whole-rock values of 3.5 to 7%. and unaltered banded calc-silicate and marble wallrocks have δ¹³C_calcite of –1.6 to –0.6%, and δ¹⁸O_calcite of 18 to 21%. In the alteration zones adjacent to the pods, the δ¹⁸O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100- to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the δ¹⁸O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of δ¹³C vs. δ¹⁸O is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.     

The middle pleistocene deposits of Waverley Wood Pit,Warwickshire, England

A complex of channels underlying the Baginton-Lillington Gravel (Baginton Formation) at Waverley Wood Quarry, Warwickshire is described. Fossil pollen and plant macrofossils, Coleoptera, Ostracoda, Mollusca and Mammalia are described from the channel-fill deposits. Consideration of all the evidence allows the identification of four separate stages of channel fill which largely occurred under a cool temperate climate. At the top of Channel 2 evidence for a cold, continental climatic episode can be recognised, suggesting that the whole complex was deposited under a fluctuating climate at the end of a temperate stage. At two levels in the channels human artefacts were recovered confirming the presence of Palaeolithic people in Warwickshire during the deposition of the sediments. Amino-acid geochronology suggests an age within the ‘Cromerian Complex’ Stage for the channels. The small vertebrate and molluscan faunas indicate that the deposits are no older than the latter part of the ‘Cromerian Complex’ Stage of East Anglia. The regional stratigraphic significance of the Waverley Wood succession is outlined.     

Fluid infiltration during contact metamorphism of interbedded marble and calc-silicate hornfels, Twin Lakes area, central Sierra Nevada, California

Abstract In the Twin Lakes area, central Sierra Nevada, California, most contact metamorphosed marbles contain calcite + dolomite + forsterite ± diopside ± phlogopite ± tremolite, and most calc-silicate hornfelses contain calcite + diopside + wollastonite + quartz ± anorthite ± K-feldspar ± grossular ± titanite. Mineral-fluid equilibria involving calcite + dolomite + tremolite + diopside + forsterite in two marble samples and wollastonite + anorthite + quartz + grossular in three hornfels samples record P± 3 kbar and T± 630° C. Various isobaric univariant assemblages record CO₂-H₂O fluid compositions of χCO₂= 0.61–0.74 in the marbles and χCO₂= 0.11 in the hornfelses. Assuming a siliceous dolomitic limestone protolith consisting of dolomite + quartz ° Calcite ± K-feldspar ± muscovite ± rutile, all plausible prograde reaction pathways were deduced for marble and hornfels on isobaric T-XCO₂ diagrams in the model system K₂O-CaO-MgO-Al₂O₃-SiO₂-H₂O-CO₂. Progress of the prograde reactions was estimated from measured modes and mass-balance calculations. Time-integrated fluxes of reactive fluid which infiltrated samples were computed for a temperature gradient of 150 °C/km along the fluid flow path, calculated fluid compositions, and estimated reaction progress using the mass-continuity equation. Marbles and hornfelses record values in the range 0.1–3.6 × 10⁴ cm³/cm² and 4.8–12.9 × 10⁴ cm³/cm², respectively. For an estimated duration of metamorphism of 10⁵ years, average in situ metamorphic rock permeabilities, calculated from Darcy's Law, are 0.1–8 × 10^?6 D in the marbles and 10–27 × 10^?6 D in the hornfelses. Reactive metamorphic fluids flowed up-temperature, and were preferentially channellized in hornfelses relative to the marbles. These results appear to give a general characterization of hydrothermal activity during contact metamorphism of small pendants and screens (dimensions ± 1 km or less) associated with emplacement of the Sierra Nevada batholith.     

Prognosis of pool phase state and hydrocarbon fluid composition for the Pre-Caspian OGP

The results of detailed studies and interpretations are presented for composition variations, structural properties and the phase state of hydrocarbon fluids from subsalt pools of the Pre-Caspian depression. These data serve as a basis for substantiating the existence of several types of condensate, and identifying the locations of the main centres of fluid generation. The basic geological-geochemical conditions controlling the composition of condensate and free gases have been determined as well as their present phase state. A set of basic criteria is proposed as well as prognostic maps for the condensate and free gas composition, and the pool phase states.     

A high‐resolution pollen and geochemical analysis of late Holocene human impact and vegetation history in southern Cumbria,England

The historic era, which in Cumbria begins with the Roman invasion of AD 71, is a frequently neglected period in palaeoecological research, but its study can bring benefits in improving knowledge of landscape history and in understanding the significance and limitations of palaeoecological records. Pollen and geochemical data are presented for late Holocene records from Deer Dyke and Hulleter Mosses in southern Cumbria. The records show initially low levels of anthropogenic impact, followed by a phase of forest clearance and mixed agriculture from the 7th to 11th centuries AD. The timing of these clearances suggests that they were initially Anglo‐Saxon in origin, rather than Norse. Further clearances in the 16th century AD are interpreted as a response to monastic dissolution and late Tudor population pressures; the landscapes reached their contemporary form following extensive clearances in the 17th century AD. Silicon and titanium concentrations at Deer Dyke Moss were used to reconstruct past levels of atmospheric dust loading, which is broadly related to soil erosion. Geochemical influx was found to peak during periods of landscape transition rather than from established land use. This relationship with pollen data is thought to reflect the predominantly low levels of anthropogenic impact in the region, which changes as substantial woodland clearances during the 16th century AD and continuous land use pressure since then have greatly increased the supply of airborne dust. Copyright © 2008 John Wiley & Sons, Ltd.     

Postglacial vegetation and climate dynamics in the Seymour‐Belize Inlet Complex,central coastal British Columbia,Canada: palynological evidence from Tiny Lake

A pollen‐based study from Tiny Lake in the Seymour‐Belize Inlet Complex of central coastal British Columbia, Canada, permits an evaluation of the dynamic response of coastal temperate rainforests to postglacial climate change. Open Pinus parklands grew at the site during the early Lateglacial when the climate was cool and dry, but more humid conditions in the later phases of the Lateglacial permitted mesophytic conifers to colonise the region. Early Holocene conditions were warmer than present and a successional mosaic of Tsuga heterophylla and Alnus occurred at Tiny Lake. Climate cooling and moistening at 8740 ± 70 ¹⁴C a BP initiated the development of closed, late successional T. heterophylla–Cupressaceae forests, which achieved modern character after 6860 ± 50 ¹⁴C a BP, when a temperate and very wet climate became established. The onset of early Holocene climate cooling and moistening at Tiny Lake may have preceded change at more southern locations, including within the Seymour‐Belize Inlet Complex, on a meso‐ to synoptic scale. This would suggest that an early Holocene intensification of the Aleutian Low pressure system was an important influence on forest dynamics in the Seymour‐Belize Inlet Complex and that the study region was located near the southern extent of immediate influence of this semi‐permanent air mass. Copyright © 2008 John Wiley & Sons, Ltd.     

Late Quaternary landscapes in Central Australia: sedimentary history and palaeoecology of Puritjarra rock shelter

Puritjarra rock shelter provides a long record of late Quaternary vegetation in the Australian arid zone. Analysis of the sedimentary history of this rock shelter is combined with reanalysis of charcoal and phytolith records to provide a first‐order picture of changing landscapes in western Central Australia. These show a landscape responding to increasing aridity from 45 ka with deflation of clay‐rich red palaeosols (<45 ka) and sharp declines in grassland and other vegetation at 40–36 ka, and at the beginning of the Last Glacial Maximum (LGM) (24 ka). Vegetation in the catchment of the rock shelter recovered after 15 ka with expansion of both acacia woodland and spinifex grasslands, registering stronger summer rainfall in the interior of the continent. By 8.3 ka re‐vegetation of local palaeosols and dunes had choked off sediment supply to the rock shelter and the character of the sediments changed abruptly. Poaceae values peaked at 5.8 ka, suggesting the early–mid Holocene climatic optimum in Central Australia is bracketed between 8.3 and 5.8 ka. Local vegetation was disrupted in the late Holocene with a sharp decline in Poaceae at 3.8 ka, coinciding with an abrupt intensification of ENSO. Local grasslands recovered over the next two millennia and by 1.5 ka the modern vegetation appears to have become established. Copyright © 2009 John Wiley & Sons, Ltd.     

Late Quaternary vegetation changes around Lake Rutundu,Mount Kenya,East Africa: evidence from grass cuticles,pollen and stable carbon isotopes

Woody, subalpine shrubs and grasses currently surround Lake Rutundu, Mount Kenya. Multiple proxies, including carbon isotopes, pollen and grass cuticles, from a 755‐cm‐long core were used to reconstruct the vegetation over the past 38 300 calendar years. Stable carbon‐isotope ratios of total organic carbon and terrestrial biomarkers from the lake sediments imply that the proportion of terrestrial plants using the C₄ photosynthetic pathway was greater during the Late Pleistocene than in the Holocene. Pollen data show that grasses were a major constituent of the vegetation throughout the Late Pleistocene and Holocene. The proportion of grass pollen relative to the pollen from other plants was greatest at the last glacial maximum (LGM). Grass cuticles confirm evidence that C₄ grass taxa were present at the LGM and that the majority followed the cold‐tolerant NADP‐MEC₄ subpathway. Copyright © 2003 John Wiley & Sons, Ltd.     

RXTE observations of the transient sources IGR J17091-3624 and IGR J18539+0727

We present the results of our analysis of the RXTE observations for two transient sources, IGR J17091-3624 and IGR J18539+0727, in April 2003. The derived energy spectra of the sources and the power-density spectra of their light curves make it possible to classify them as low/hard-state X-ray binaries. The parameters of the power spectrum for IGR J18539+0727 lead us to tentatively conclude that the compact object in this binary is a black hole.