Kornerupine in Mg-Al-rich gneisses from Namaqualand,South Africa: mineralogy and evidence for late-metamorphic fluid activity

Three kornerupine occurrences are reported in distinctive SiO₂-poor, MgO- and Al₂O₃-rich paragneisses from the Namaqualand Metamorphic Complex in South Africa. Kornerupine coexists stably with phlogopite, cordierite, orthopyroxene, gedrite, sapphirine, sillimanite and plagioclase and, in sapphirine-free rocks, with spinel and corundum. Tourmaline of a texturally older generation than kornerupine is commonly present in the same samples.Ten analysed kornerupines show a variation in total Fe as FeO from 1.8 to 10.9 weight per cent. B₂O₃ contents are estimated from x-ray data and a few spectrochemical analyses to range from 0.9 to 3.5 weight per cent. There is a strong inverse correlation between B³⁺ and Al³⁺. Total iron content has a strong and systematic effect on refractive index, colour and dispersion. Fe and Mg are systematically partitioned with the other minerals, and Mg/(Mg+Fe) ratios increase as follows: spinel 相似文献   

Reaching critical mass? Theory, politics, and the culture of debate in children's geographies

A small but growing number of voices have begun to raise questions about the current direction of children's geographies as a subfield and its status within the wider discipline. This article intervenes in these emerging discussions to examine the status of debate itself within children's geographies. I argue that children's geographies over the past decade has operated primarily in a consensus-based mode, with a number of potential tensions and differences between practitioners masked as a result. I develop the example of notions of children's competent social agency, a core theoretical assumption that is rarely interrogated in much depth. In closing, I pose questions regarding several contemporary political issues concerning children's agency about which geographers have had surprisingly little to say. I suggest that explicitly addressing some of these vexing issues would contribute to a richer state of debate within children's geographies.     

Ice-sheet growth and high-latitudes sea-surface temperature

The response of the LLN 2-D climate model to the insolation and CO₂ forcings during the Eemian interglacial is compared to reconstructions obtained from deep-sea cores drilled in the Norwegian Sea and in the North Atlantic. Both reconstructions and modeling results show a decrease of sea-surface temperature (SST) in the higher latitudes (70–75 °N zonal belt for the model and the Norwegian Sea for the proxy records), associated with a more moderate cooling at lower latitudes (50–55 °N and North Atlantic), at the middle of isotopic substage 5e, several millenia before the beginning of continental ice-sheet growth. Such a comparison between the simulated SST and ice volume of the Northern Hemisphere has been extended to the whole last glacial-interglacial cycle. The influence of the insolation forcing on SST and the shortcomings of the model due to its zonal character are discussed. Received: 6 July 1995/Accepted: 19 December 1995     

Scope for a small circumsolar annular gravitational contribution to the Pioneer anomaly without affecting planetary orbits

All proposed gravitational explanations of the Pioneer anomaly must crucially face the Equivalence Principle. Thus, if Pioneers 10 and 11 were influenced by anomalous gravitational effects in regions containing other Solar System bodies, then those bodies should likewise be influenced, irrespective of their shape, composition or mass. Although the lack of any observed influence upon planetary orbits severely constrains such explanations, here we aim to construct by computer modeling, hypothetical gravitating annuli having no gravitational impact on planetary orbits from Mercury to Neptune. One model has a central zone, free of radial gravitation in the annular plane, and an ‘onset’ beyond Saturn’s orbit, where sunward annular gravitation increases to match the Pioneer anomaly data. Sharp nulls are included so that Uranus and Neptune escape this influence. Such models can be proportionately reduced in mass: a 1 % contribution to the anomaly requires an annulus of approximately 1 Earth mass. It is thus possible to comply with the JPL assessment of newly recovered data attributing 80 %, or more, of the anomaly to spacecraft heat, which appears to allow small contributions from other causes. Following the possibility of an increasing Kuiper belt density at great ranges, another model makes an outward small anomalous gravitation in the TNO region, tallying with an observed slight indication of such an effect, suggesting that New Horizons may slightly accelerate in this region.     

Rock Mass Deformation Characteristics in High-Steep Slopes Influenced by Open-Pit to Underground Mining

In Daye Iron Mine, the open-pit mining has ended and the underground mining started in 2003. The present pit slopes are as high as 430 m and the slope angle is up to 43°. During the process of open-pit to underground mining, the high-steep pit slopes would be affected by both open-pit mining and underground mining, and its deformation characteristics would become more complex. So in this paper, the trinity method of numerical simulation, model experiment and field test was adopted to analyze the displacement and stress fields systematically. The results show that: (1) Prominent rebound deformation occurs near the slope foot, which is induced by the unloading in open-pit mining. When it is backfilled to 0 m level, the rebound deformation decreases, which indicate that backfilling mass can restrict the deformation and improve the slope stability; (2) Subsidence dominates the slope deformation in open-pit to underground mining and it increases with an increasing elevation of monitoring point; the maximum horizontal displacement occurs in the lower part of the slopes, because the backfilled part is squeezed by both the north slope and the south slope, and it has a lower elastic modulus than the previous orebody; (3) The stress and its variability near the slope foot are much larger than other places, indicating that the slope foot is most affected by stress redistribution and stress concentration may occur here; the stress at other stress monitoring points changes little, indicating that the influence of open-pit to underground mining is local; (4) The effect of underground mining on the deformation of the faults is not prominent; (5) Mining operations in near-ground part affect more on the variation of deformation and stress of pit slopes than that in deeper part.     

Magnetic Anisotropy as an Aid to Identifying CRM and DRM in Red Sedimentary Rocks

To further evaluate the potential of magnetic anisotropy techniques for determining the origin of the natural remanent magnetization (NRM) in sedimentary rocks, several new remanence anisotropy measurement techniques were explored. An accurate separation of the remanence anisotropy of magnetite and hematite in the same sedimentary rock sample was the goal.In one technique, Tertiary red and grey sedimentary rock samples from the Orera section (Spain) were exposed to 13 T fields in 9 different orientations. In each orientation, alternating field (af) demagnetization was used to separate the magnetite and hematite contributions of the high field isothermal remanent magnetization (IRM). Tensor subtraction was used to calculate the magnetite and hematite anisotropy tensors. Geologically interpretable fabrics did not result, probably because of the presence of goethite which contributes to the IRM. In the second technique, also applied to samples from Orera, an anisotropy of anhysteretic remanence (AAR) was applied in af fields up to 240 mT to directly measure the fabric of the magnetite in the sample. IRMs applied in 2 T fields followed by 240 mT af demagnetization, and thermal demagnetization at 90°C to remove the goethite contribution, were used to independently measure the hematite fabric in the same samples. This approach gave geologically interpretable results with minimum principal axes perpendicular to bedding, suggesting that the hematite and magnetite grains in the Orera samples both carry a depositional remanent magnetization (DRM). In a third experiment, IRMs applied in 13 T fields were used to measure the magnetic fabric of samples from the Dome de Barrot area (France). These samples had been demonstrated to have hematite as their only magnetic mineral. The fabrics that resulted were geologically interpretable, showing a strong NW-SE horizontal lineation consistent with AMS fabrics measured in the same samples. These fabrics suggest that the rock's remanence may have been affected by strain and could have originated as a DRM or a CRM.Our work shows that it is important to account for the presence of goethite when using high field IRMs to measure the remanence anisotropy of hematite-bearing sedimentary rocks. It also shows that very high magnetic fields (>10 T) may be used to measure the magnetic fabric of sedimentary rocks with highly coercive magnetic minerals without complete demagnetization between each position, provided that the field magnetically saturates the rock.     

A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.     

Haynesville Shale Well Performance and Development Potential

Louisiana’s Haynesville Shale is one of several unconventional gas plays that have been discovered in the U.S. in recent years and promise to dramatically change the course of future domestic energy development. The Haynesville Shale is the deepest, hottest, and highest pressured shale among the big four plays in the U.S. with drilling and completion cost ranging between 7 and7 and 10 million per well. The average Haynesville well has an initial production rate of 10 MMcfd and declines rapidly, producing 80% of its expected recovery during the first 2 years of production. The purpose of this article is to describe the productivity characteristics of Haynesville wells, project future production from the inventory of active wells, and assess production potential based on drilling scenarios. We offer statistical analysis of the wells drilled to date and construct type profiles to characterize the play. We estimate that the current inventory of Haynesville wells will produce 3 Tcf over their lifecycles, and within the next 3 years, cumulative build-out in the region will range between 3 and 9 Tcf. To maintain current gas production levels in the state, we estimate that about 550 shale gas wells per year will need to be brought online over the next 3 years.