Oxidation of copper(I) in seawater at nanomolar levels

The oxidation and reduction of nanomolar levels of copper in air-saturated seawater and NaCl solutions has been measured as a function of pH (7.17–8.49), temperature (5–35 °C) and ionic strength (0.1–0.7 M). The oxidation rates were fitted to an equation valid at different pH and ionic strength conditions in sodium chloride and seawater solutions:

The reduction of Cu(II) was studied in both media for different initial concentrations of copper(II). When the initial Cu(II) concentration was 200 nM, the copper(I) productions were 20% and 9% for NaCl and seawater, respectively. The effect of speciation of copper(I) reduced from Cu(II) on the rates was studied. The Cu(I) speciation is dominated by the CuCl₂⁻ species. On the other hand, the neutral chloride CuCl species dominates the Cu(I) oxidation in the range of 0.1 M to 0.7 M chloride concentrations.     

Deep-sea reef fish assemblage patterns on the Blake Plateau(Western North Atlantic Ocean)

Deep‐water coral habitats are scattered throughout slope depths (360–800 m) off the Southeastern United States (SEUS, Cape Lookout, North Carolina, to Cape Canaveral, Florida), contributing substantial structure and diversity to bottom habitats. In some areas (e.g. off North Carolina) deep corals form nearly monotypic (Lophelia pertusa) high profile mounds, and in other areas (e.g. off Florida) many species may colonize hard substrata. Deep coral and hard substrata ecosystems off the SEUS support a unique fish assemblage. Using the Johnson‐Sea‐Link submersible (in 2000–2005, 65 dives), and a remotely operated vehicle (in 2003, five dives), fishes were surveyed in nine deep reef study areas along the SEUS slope. Forty‐two benthic reef fish species occurred in deep reef habitats in these study areas. Species richness was greatest on the two coral banks off Cape Lookout, North Carolina (n = 23 and 27 species) and lowest on the two sites off Cape Canaveral, Florida (n = 7 and 8 species). Fish assemblages exhibited significantly (ANOSIM, Global R = 0.69, P = 0.001) different patterns among sites. Stations sampled off North Carolina (three study areas) formed a distinct group that differed from all dives conducted to the south. Although several species defined the fish assemblages at the North Carolina sites, Laemonema barbatulum, Laemonema melanurum, and Helicolenus dactylopterus generally had the most influence on the definition of the North Carolina group. Fish assemblages at three sites within the central survey area on the Blake Plateau were also similar to each other, and were dominated by Nezumia sclerorhynchus and L. melanurum. Synaphobranchus spp. and Neaumia sclerorhynchus differentiated the two southern sites off Cape Canaveral, Florida, from the other station groups. Combinations of depth and habitat type had the most influence on these station groups; however, explicit mechanisms contributing to the organization of these assemblages remain unclear.     

Simulation of the quasi-biennial oscillations of the zonal wind in the equatorial stratosphere: Part II. Atmospheric general circulation models

The problem of simulating quasi-biennial oscillations (QBOs) of zonal velocity in the equatorial stratosphere in atmospheric general circulation models is considered. In accordance with the results from Part I of this study on the basis of the models developed at the Institute of Numerical Mathematics of the Russian Academy of Sciences (INM RAS), the possibility of implementing (in these models) mechanisms of QBO excitation through both the interaction of planetary waves with the mean flow and breaking of short gravity waves is investigated. A new high-resolution 2° × 2.5° × 80 version of the INM RAS model is designed, a climate simulation with the two 2° × 2.5° × 39 and 2° × 2.5° × 80 versions of the INM RAS model is briefly described, results of spectral analysis of equatorial wave activity are presented, and the QBO formation processes in these models are considered in detail. For the new 2° × 2.5° × 80 model, realistic QBOs of zonal wind are obtained as the result of the action of both mechanisms.     

On the energy dissipation of jacket type offshore platforms with different pile–leg interactions

In recent years, considerable amount of effort has been made to design earthquake resistant offshore structures in seismic active areas. In order to achieve this objective, all components of a typical structure should function properly to dissipate seismically-induced energy within the members. Among components of an offshore installation, braces are of significant importance as they contribute substantially to total energy dissipation of the structure. Buckling in compression and yielding in tension assist the process of energy absorption. Nevertheless, the functionality of braces is dependent upon their joints where joint-cans are included to avoid any brittle fracture and unpredicted failure mechanisms.In this paper, special attention is being paid to energy dissipation of jacket type offshore platforms with two different pile–leg interactions. A case study representing an offshore platform is studied both analytically and experimentally. Analytical models are validated step by step based on available experimental tests and observations on individual members. Several parameters such as cyclic behavior, maximum bearing load and most importantly energy dissipation of two different 2D frames are investigated. Results provide promising insights into design and fabrication of fixed platforms with different pile–leg interactions.     

Describing and generating facies models for reservoir characterisation: 2D map view

This paper documents a new method for describing channel-related sedimentary deposits based on formal language theory. Using this method an analogue model of a sedimentary deposit can be encoded as a grammar. A program, called a parser, has been developed which can generate stochastic maps of these sedimentary deposits based on information in a specified grammar. The maps of sedimentary deposits generated by the parser have the same type, spatial arrangement, shape and size distribution as the analogue model. The successful generation of depositional maps represents a crucial step in the ongoing development of a new technique designed to generate 3D static geological models of sedimentary successions. The maps can be conditioned to match sparse hard data in the form of channel segments interpreted from seismic horizon maps.     

A predictive numerical model for potential mapping of the gas hydrate stability zone in the Gulf of Cadiz

This paper presents a computational model for mapping the regional 3D distribution in which seafloor gas hydrates would be stable, that is carried out in a Geographical Information System (GIS) environment. The construction of the model is comprised of three primary steps, namely: (1) the construction of surfaces for the various variables based on available 3D data (seafloor temperature, geothermal gradient and depth-pressure); (2) the calculation of the gas function equilibrium functions for the various hydrocarbon compositions reported from hydrate and sediment samples; and (3) the calculation of the thickness of the hydrate stability zone. The solution is based on a transcendental function, which is solved iteratively in a GIS environment.The model has been applied in the northernmost continental slope of the Gulf of Cadiz, an area where an abundant supply for hydrate formation, such as extensive hydrocarbon seeps, diapirs and fault structures, is combined with deep undercurrents and a complex seafloor morphology. In the Gulf of Cadiz, the model depicts the distribution of the base of the gas hydrate stability zone for both biogenic and thermogenic gas compositions, and explains the geometry and distribution of geological structures derived from gas venting in the Tasyo Field (Gulf of Cadiz) and the generation of BSR levels on the upper continental slope.     

Hazard assessment in rock cliffs at Central Algarve (Portugal): A tool for coastal management

Coastal hazards are in the interface of human activities with natural coastal processes. The conflicts arising from this relationship require new approaches suitable for coastal management that consider the dynamic of coastal areas. A method to assess hazard in rock cliffs is presented, combining cliff evolution forcing mechanisms along with protection factors, according to a weighted factors system. This method provides a rapid evaluation of vulnerability for cliffed areas, supporting coastal management and hazard mitigation. The method was applied to the rocky cliffs of the densely populated coastal zone between Galé and Olhos de Água (Southern Portugal), where high and very high hazard values were found to be dominant. A method validation was made using the vulnerability areas and the recorded mass movements over a 45 year period in the same area.     

Application of a nonlinear frequency domain wave–current interaction model to shallow water recurrence effects in random waves

The effect of ambient currents on nearshore nonlinear wave–wave energy transfer in random waves is studied with the use of a nonlinear frequency domain wave–current interaction model. We focus on the phenomenon of wave recurrence as a classical nonlinear phenomenon whose characteristics are well established for systems truncated to small numbers of frequency modes. The model used for this study is first extended to enhance accuracy; comparisons of permanent form solutions to analytical forms confirm the model accuracy. Application of the model to a highly truncated system confirmed the model’s consistency with published results for both positive (following) and negative (adverse) currents. Propagation of random wave spectra over a flat bottom was performed with the model, with the intent of determining the prevalence of recurrence between the spectral peak and its harmonics. For spectra of moderate Ursell number, it was found that positive currents extended the length scale of recurrence relative to the case with no currents; conversely, negative currents reduced the recurrence lengths. However, beyond a propagation distance of ≈40 wavelengths of the spectral peak, recurrence becomes almost completely damped as the spectra becomes broad and the spectral energies equilibrate. For spectra of high Ursell number, in contrast, recurrence is almost immediately damped, suggesting that the nonlinearity is sufficient to allow immediate spectral broadening and equilibration and overwhelming any preferential interactions among the spectral peak and its harmonics, regardless of current magnitude or direction.     

Large Eddy Simulation on Interaction Between in-Line and Cross-Flow Oscillation of A Circular Cylinder

This paper discusses numerical results from three-dimensional large eddy simulations of an oscillating cylinder under prescribed movements in uniform flow. Six cases,namely pure in-line,pure cross-flow and two groups of 'Figure of Eight' oscillation patterns are under investigation at Reynolds number Re=24000. The 'Figure of Eight' pattern in each group is with identical shape but opposite orbital directions. The numerical results on hydrodynamic forces,higher order force components,and vortex shedding mode...