On water ice formation in interstellar clouds

A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The formation of the first monolayer requires a minimum extinction of interstellar radiation, sufficient to lower the grain temperature to the point where thermal evaporation of monomers is just offset by monomer accretion from the gas. This threshold is mainly determined by the adsorption energy of water molecules on the grain material; for hydrocarbon material, chemical simulation places this energy between 0.5 and 2 kcal mol⁻¹, which sets the (true) visible extinction threshold at a few magnitudes. However, realistic distributions of matter in a cloud will usually add to this an unrelated amount of cloud core extinction, which can explain the large dispersion of observed (apparent) thresholds. Once the threshold is crossed, all available water molecules in the gas are quickly adsorbed, because the grain cools down and the adsorption energy on ice is higher than on bare grain. The relative thickness of the mantle, and, hence, the slope of  τ₃( A _v)  depend only on the available water vapour, which is a small fraction of the oxygen abundance. Chemical simulation was also used to determine the adsorption sites and energies of O and OH on hydrocarbons and study the dynamics of formation of water molecules by surface reactions with gaseous H atoms, as well as their chances to stick in situ.     

Average velocity components in a rotating infinitely flattened self-gravitating system near an equilibrium state

The average radial and angular velocity components are obtained for a rotating two-dimensional self-gravitating system near an equilibrium state. First-order perturbation configurations of flaring straight bars emanating from the center provide examples of such systems. In these systems the average velocity field to first order is incompressible and irrotational. The second-order effects on the product of the average velocity components with the spatial density are essentially independent of the angular coordinate.     

Roughness of the lunar soil

In situ measurements at the lunar surface at millimeter resolution by the Apollo astronauts have been analyzed. Several statistical parameters have been determined for the landing site. The surface roughness has been found to be very nearly gaussian. The root-mean-square slopes have been obtained over scales between 0.5 mm and 5 cm. They steadily decrease with increasing scale length from 58° to 2° and are in reasonable agreement with radar-measured values. The autocorrelation coefficient of the height distribution has also been obtained. It has a scale-length of 0.7 mm.Adjunct Professor at the University of Massachusetts.Visiting Scholar at the University of Massachusetts.     

A new class of periodic solutions in the Kovalevskaya case of a rigid body in rotation about a fixed point

The equation of motion of a rigid body in Kovaleveskaya case is reduced to a plane motion. By using the method of small parameters introduced by Poincaré, the existence of a periodic solution is established.     

Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Spatial and temporal variations of solar coronal loops

Skylab EUV observations of an active region near the solar limb were analyzed. Both cool (T < 10⁶ K) and hot (T > 10⁶ K) loops were observed in this region. For the hot loops the observed intensity variations were small, typically a few percent over a period of 30 min. The cool loops exhibited stronger variations, sometimes appearing and disappearing in 5 to 10 min. Most of the cool material observed in the loops appeared to be caused by the downward flow of coronal rain and by the upward ejection of chromospheric material in surges. The frequent EUV brightenings observed near the loop footpoints appear to have been produced by both in situ transient energy releases (e.g. subflares) and the infall/impact of coronal rain. The physical conditions in the loops (temperatures, densities, radiative and conducting cooling rates, cooling times) were determined. The mean energy required to balance the radiative and conductive cooling of the hot loops is approximately 3 × 10^–3 erg cm^–3 s^–1. One coronal heating mechanism that can account for the observed behavior of the EUV emission from McMath region 12634 is heating by the dissipation of fast mode MHD waves.     

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

Magneto-gravitational instability of a rotating and finitely-conducting fluid

The gravitational instability of an infinite homogeneous finitely conducting viscid fluid through porous medium is studied in the presence of a uniform vertical magnetic field and finite ion Larmor radius (FLR) effects. The medium is considered uniformly rotating along and perpendicular to the direction of the prevalent magnetic field. A general dispersion relation is obtained from the relevant linearized perturbation equations of the problem. Furthermore, the wave propagation along and perpendicular to the direction of existing magnetic field has been discussed for each direction of the rotation. It is found that the simultaneous presence of viscosity finite conductivity, rotation, medium porosity, and FLR corrections does not essentially change the Jeans's instability condition. The stabilizing influence of FLR in the case of transverse propagation is reasserted for a non-rotating and inviscid porous medium. It is shown that the finite conductivity has destabilizing influence on the transverse wave propagation whereas for longitudinal propagation finite conductivity does not affect the Jean's criterion.