A new procedure for separating and measuring radiogenic isotopes (U, Th, Pa, Ra, Sr, Nd, Hf) in ice cores

A new method for the radiogenic isotope (U–Th–Pa–Ra, Sr, Nd, Hf) analysis of the soluble and insoluble components found within ice cores is presented. Melting experiments with rock standards in the presence of EDTA indicate that carbonates, as well as silicates, can be buffered sufficiently to preclude dissolution. The use of EDTA allows adsorbing species, such as Th and Hf, to remain in solution during melting thus fully separating the dust (insoluble) and sea salt (soluble) components of the ice after filtration. A new elemental separation scheme for low sample masses, less than 5 mg solid material, utilizes 4 primary ion exchange columns and two “clean-up” columns to fully isolate U, Th, Pa, Ra, Sr, Nd, and Hf while maintaining high yields. Elution schemes measured for USGS rock standards and a Chinese loess are presented to provide a comparison for variable matrix compositions. Mass spectrometer techniques were modified to measure small aliquots of the standards, equivalent to the amounts found in ice core samples, 10 ng and less. A MC-ICPMS was employed for the measurement of U, Th, Pa, Ra, and Hf; results of the experiments show that with ion yields up to 1%, rock standards have errors for ²³⁴U/²³⁸U of 1%, ²³⁰Th/²³²Th of 1.5%, [²²⁸Ra] of 9%, and ¹⁷⁶Hf/¹⁷⁷Hf of 100 ppm. MC-TIMS measurements of Sr and Nd show similar errors for small sample sizes: ⁸⁷Sr/⁸⁶Sr of 50 ppm and ¹⁴³Nd/¹⁴⁴Nd of 80 ppm. This new analytical method increases the number of possible tracers measured from a single sample, reducing separation times and sample consumption, as well as providing the addition of a radiometric clock, U-series, to the traditional suite of isotopic tracers, Sr, Nd, and Hf.     

Dawn; the Vesta–HED connection; and the geologic context for eucrites,diogenites, and howardites

The Dawn mission has provided new evidence strengthening the identification of asteroid Vesta as the parent body of the howardite, eucrite, and diogenite (HED) meteorites. The evidence includes Vesta's petrologic complexity, detailed spectroscopic characteristics, unique space weathering, diagnostic geochemical abundances and neutron absorption characteristics, chronology of surface units and impact history, occurrence of exogenous carbonaceous chondritic materials in the regolith, and dimensions of the core, all of which are consistent with HED observations and constraints. Global mapping of the distributions of HED lithologies by Dawn cameras and spectrometers provides the missing geologic context for these meteorites, thereby allowing tests of petrogenetic models and increasing their scientific value.     

Towards error‐free hybrid simulation using mixed variables

Two procedures are developed and implemented in a hybrid simulation system (HSS) with the aim of enhancing the accuracy and reliability of the online, i.e. pseudo‐dynamic, test results. The first procedure aims at correcting the experimental systematic error in executing the displacement command signal. The error is calculated as the difference between command and feedback signals and correlated to the actuator velocity using the least‐squares method. A feed‐forward error compensation scheme is devised leading to a more accurate execution of the test. The second procedure employs mixed variables with mode switching between displacement and force controls. The newly derived force control algorithm is evaluated using a parametric study to assess its stability and accuracy. The implementation of the mixed variables procedure is designed to adopt force control for high stiffness states of the structural response and displacement control otherwise, where the resolution of the involved instruments may favour this type of mixed control. A simple pseudo‐dynamic experiment of steel cantilever members is used to validate the HSS. Moreover, two experiments as application examples for the two developed procedures are presented. The two experiments focus on the seismic response of (a) timber shear walls and (b) reinforced concrete frames with and without unreinforced masonry infill wall. Copyright © 2007 John Wiley & Sons, Ltd.     

Particle size dependent response of aerosol counters

During an international workshop at the Institute for Experimental Physics of the University of Vienna, Austria, which was coordinated within the Committee on Nucleation and Atmospheric Aerosols (IAMAS-IUGG), 10 instruments for aerosol number concentration measurement were studied, covering a wide range of methods based on various different measuring principles. In order to investigate the detection limits of the instruments considered with respect to particle size, simultaneous number concentration measurements were performed for monodispersed aerosols with particle sizes ranging from 1.5 to 50 nm diameter and various compositions.The instruments considered show quite different response characteristics, apparently related to the different vapors used in the various counters to enlarge the particles to an optically detectable size. A strong dependence of the 50% cutoff diameter on the particle composition in correlation with the type of vapor used in the specific instrument was found. An enhanced detection efficiency for ultrafine hygroscopic sodium chloride aerosols was observed with water operated systems, an analogous trend was found for n-butanol operated systems with nonhygroscopic silver and tungsten oxide particles.     

西藏羊八井热田地热流体成因及演化的惰性气体制约

地热流体中惰性气体的相对丰度和同位素组成，不仅可以揭露热田的热源性质，而且还能够揭示深，浅层地热流体的内在联系和演化过程等。在西藏羊八井热田的地热气体中，已检测出大量的^4He组分，3He/^4He值是大气的0．087－0．259倍，表明深部地壳物质的局部熔融为热田提供能量，浅层地热流体的3He/4He 值自西北向东南呈降低趋势，与热储温度的变化相一致，反映出侧向运移时补充了更多的壳源氦，热田北区深层地热流体具有稍高的3He/4He值，是浅层地热流体的母源，气体中氪和氙的相对丰度具有大气降水成因的特征，结合现有的实际资料，建立了热田地热流体的概念模型。     

GIS and Volcanic Risk Management

Volcanic catastrophes constitute a majorproblem in many developing and developed countries. Inrecent years population growth and the expansion ofsettlements and basic supply lines (e.g., water, gas,etc.) have greatly increased the impact of volcanicdisasters. Correct land-use planning is fundamental inminimising both loss of life and damage to property.In this contribution Geographical Information Systems(GIS), linked with remote sensing technology andtelecommunications/warning systems, have emerged asone of the most promising tools to support thedecision-making process. Some GIS are presented fortwo volcanic areas in Italy, Mt. Etna and Vesuvius.GIS role in risk management is then discussed, keepingin mind the different volcanic scenarios of effusiveand explosive phenomena. Mt. Etna system covers alarge area (more than 1,000 km²) potentiallyaffected by effusive phenomena (lava flows) whichcause damage to both houses and properties in general.No risk to life is expected. The time-scales of lavaflows allow, at least in principle, modification ofthe lava path by the building of artificial barriers.Vesuvius shows typically an explosive behaviour. Inthe case of a medium size explosive eruption, 600,000people would potentially have to be evacuated from anarea of about 200 km² around the Volcano, sincethey are exposed to ruinous, very fast phenomena likepyroclastic surges and flows, lahars, ash fallout,etc. Ash fallout and floods/lahars are also expectedin distal areas, between Vesuvius and Avellino,downwind of the volcano. GIS include digital elevationmodels, satellite images, volcanic hazard maps andvector data on natural and artificial features (energysupply lines, strategic buildings, roads, railways,etc.). The nature and the level of detail in the twodata bases are different, on the basis of thedifferent expected volcanic phenomena. The GIS havebeen planned: (a) for volcanic risk mitigation (hazard,value, vulnerability and risk map assessing), (b) toprovide suitable tools during an impending crisis, (c)to provide a basis for emergency plans.     

Petrological evidence for shock‐induced high‐P metamorphism in a gabbro

Microlites (minute spherulitic, dendritic, skeletal, acicular and poikilitic crystals) diagnostic of crystallization in quenched melt or glass in fault rocks have been used to infer fossil earthquakes. High‐P microlites and crystallites are described here in a variably eclogitized gabbro, the wallrock to the coesite‐bearing eclogite breccia at Yangkou in the Chinese Su‐Lu high‐P metamorphic belt. The studied hand specimens are free of discernible shear deformation, although microfractures are not uncommon under the microscope. In the least eclogitized gabbro, the metagabbro, stellate growths of high‐P minerals on the relict igneous minerals are common. Dendritic garnet crystals (<1?5 μm) grew around rutile and/or phengite replacing ilmenite and biotite, respectively. Skeletal garnet also rims broken flakes of igneous biotite and mechanically twinned augite. Radial intergrowths of omphacite and quartz developed around relict igneous orthopyroxene and are rimmed by skeletal or poikilitic garnet where a Ti‐bearing mineral relict is present. Acicular epidote, kyanite and phengite crystallites are randomly distributed in a matrix of Na‐rich plagioclase, forming the pseudomorphs after igneous plagioclase. In the more eclogitized gabbro, the coronitic eclogite located closer to the eclogite breccia, all the igneous minerals broke down into high‐P assemblages. Thick coronas of poikilitic garnet grew between the pseudomorphs after igneous plagioclase and ferromagnesian minerals. The igneous plagioclase is replaced by omphacite crystallites, with minor amounts of phengite and kyanite. Thermodynamic modelling of the plagioclase pseudomorphs shows an increase in P–T in the wallrock from the metagabbro to the coronitic eclogite, and the P–T variation is unrelated to H₂O content. The fluid‐poor pressure overstepping scenario is unsupported both by phase diagram modelling and by whole‐rock chemical data, which show that the various types of eclogitized gabbro are all fairly dry. A large pressure difference of >2 GPa between the metagabbro and the coesite‐bearing eclogites ~20 m apart cannot be explained by the subduction hypothesis because this would require a depth difference of >60 km. The microlites and crystallites are evidence for dynamic crystallization due to rapid cooling because constitutional supercooling was unlikely for the plagioclase pseudomorphs. The lack of annealing of the broken biotite and augite overgrown by strain free skeletal garnet is consistent with a transient high‐P–T event at a low ambient temperature (<300 °C), probably in the crust. Therefore, the eclogitization of the wallrock to the eclogite breccia was also coseismic, as proposed earlier for the eclogite facies fault rocks. The outcrop‐scale P–T variation and the transient nature of the high‐P–T event are inconsistent with the other existing tectonic models for high‐P metamorphism. The fact that the less refractory but denser biotite is largely preserved while the more refractory but less dense plagioclase broke down completely into high‐P microlite assemblages in the metagabbro indicates a significant rise in pressure rather than temperature. Given that the metamorphic temperatures are far below the melting temperatures of most of the gabbroic minerals under fluid‐absent conditions, stress‐induced amorphization appears to be the more likely mechanism of the coseismic high‐P metamorphism.     

Chromite growth,dissolution and deformation from a morphological view point: SEM investigations

The SEM investigations on some chromite crystals show significant morphological differences between cumulate chromites (from stratiform complexes and from ophiolites) and chromites from podiform deposits (ophiolites). The later exhibit a rounded habit and abundant pits which are both the result of dissolution processes. Accordingly, the interpretation of the silicate inclusions within these chromites and the interpretration of the trace-elements distribution need great care. The nodules, a typical structure of the podiform chromites, are explained by a magmatic growth followed by a progressive recrystallization. The accessory chromites which define the mineral lineation in the tectonite peridotites from ophiolites have been deformed by processes of intracrystalline gliding, stretching and dissolution. In the harzburgites, the orthopyroxene has progressively exsolved at sub-solidus (symplektites) vermicular to massive chromite displaying euhedral forms. In the dunitic lenses, the idiomorphic chromites which are aligned parallel to the lineation may have also recrystallized in a solid state.