Correlation of trace elements with hydrocarbon microseepage

Direct correlation have been observed between certain trace element and hydrocarbon anomalies in the near subsurface soils of Vindhyan basin, India. This relationship with hydrocarbon is very useful in hydrocarbon exploration. 52 soil samples from Vindhyan basin were collected from a depth of 2.5m. All the soil samples were analyzed for light hydrocarbon, isotope and trace element concentrations. The adsorbed light gaseous hydrocarbon analyses show the presence of methane (8–328 ppb), ethane (0–27 ppb) and propane (0–11 ppb) respectively and these values indicate the presence of hydrocarbon micro-seepage in the study area. The carbon isotopic values determined for methane and ethane for these soil samples are (?26.41 to ?47.70 ‰ PDB) and (?20.07 to ?35.30 ‰ PDB) respectively and they are thermogenic in nature. The trace element concentrations of nickel (33–220 ppm), vanadium (72–226 ppm), copper (20–131 ppm), chromium (94–205 ppm), zinc (66–561 ppm) and cobalt (9–39 ppm) have higher than the normal concentrations in soils. Trace element concentrations are used to plot with the data obtained from light gaseous hydrocarbon concentrations and carbon isotopic values of soil samples of the Vindhyan basin. Trace element anomalies have been observed around the hydrocarbon anomalies in the study area.     

Electrization and spatial charge separation at the air bubbles exhalation that occurs during the coagulation growth of hail particles in a cloud. Part 1. Kinetics of the bubbles exhalation process caused by increasing temperature of overcooled cloud drops

Kinetics of the air bubbles exhalation process, which occurs in overcooled cloud drops when they hit the hail or graupel particles surface. Analytical relationship between a number of bubbles generated in a drop and their size depending on the degree of overcooling of cloud drops is revealed. It is shown that the air bubbles exhalation, which accompanies the coagulation growth of hail particles, occurs on the principle of “ebullition” of the liquid on the surface of a hail particle.     

In-vitro metabolism of benzo[a]pyrene and benzo[a]pyrene-7,8-dihydrodiol by liver and intestinal mucosa homogenates from the winter flounder (Pseudopleuronectes americanus)

Freshly prepared homogenates were used to assess the relative ability of winter flounder (Pseudopleuronectes americanus) liver and intestinal mucosal cells to metabolize the polycyclic aromatic hydrocarbon (PAH) benzo[a]pyrene (BaP) and its proximate carcinogenic metabolite, BaP-7,8-dihydrodiol (7,8-Diol). Data obtained from homogenates prepared from fish previously fed β-naphthoflavone (BNF) indicated that both tissues had similar abilities to metabolize either BaP or 7,8-Diol on a per gram of protein basis. Metabolite profiles produced indicate that water-soluble metabolite formation is favored at low doses. These findings support the hypothesis that the intestine plays an important role in first-pass metabolism of dietary carcinogens in the winter flounder.     

Pacific decadal oscillation and European climatic anomalies

By using the NCEP/NCAR reanalysis data sets for 1951–2001, we study the characteristics of Pacific cyclones. It is shown that the northeast-southwest direction is predominant in the displacements of cyclones in the North Pacific. We study the variability of the field of surface atmospheric pressure in different phases of the Pacific decadal oscillation characterizing the temperature anomalies on the surface of the ocean in the region bounded by 20 and 60°N. It is shown that the decadal variations of the North Atlantic Oscillation supported by the large-scale anomalies of the Pacific decadal oscillation is the most important cause of natural decadal oscillations in the European region. We study and evaluate the regional response to the Pacific decadal oscillation by using, as an example, the analysis of variations of the discharge of European rivers. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 4, pp. 13–23, July–August, 2007.     

High-energy particle acceleration and production of ultra-high-energy cosmic rays in the giant lobes of Centaurus A

The nearby radio galaxy Centaurus A is poorly studied at high frequencies with conventional radio telescopes because of its very large angular size, but is one of a very few extragalactic objects to be detected and resolved by the Wilkinson Microwave Anisotropy Probe ( WMAP ). We have used the five-year WMAP data for Cen A to constrain the high-frequency radio spectra of the 10° giant lobes and to search for spectral changes as a function of position along the lobes. We show that the high-frequency radio spectra of the northern and southern giant lobes are significantly different: the spectrum of the southern lobe steepens monotonically (and is steeper further from the active nucleus) whereas the spectrum of the northern lobe remains consistent with a power law. The inferred differences in the northern and southern giant lobes may be the result of real differences in their high-energy particle acceleration histories, perhaps due to the influence of the northern middle lobe, an intermediate-scale feature which has no detectable southern counterpart. In light of these results, we discuss the prospects for Fermi Gamma-ray Space Telescope detections of inverse-Compton emission from the giant lobes and the lobes' possible role in the production of the ultra-high-energy cosmic rays (UHECR) detected by the Pierre Auger Observatory. We show that the possibility of a Fermi detection depends sensitively on the physical conditions in the giant lobes, with the northern lobe more likely to be detected, and that any emission observed by Fermi is likely to be dominated by photons at the soft end of the Fermi energy band. On the other hand, we argue that the estimated conditions in the giant lobes imply that UHECRs can be accelerated there, with a potentially detectable γ-ray signature at TeV energies.     

Short-period Jupiter family comets after Stardust

The NASA Stardust mission has provided for laboratory study an extensive data set of cometary dust of known provenance (from comet 81P/Wild 2) yielding detailed insights into the composition of the comet. Combined with the results of data from other missions to short-period Jupiter family comets (JFC), this has greatly deepened the understanding of such objects. If depressions on the surface of comet 81P/Wild 2 are all taken as evidence of impact cratering, their number suggests a long occupancy in the outer region of the Solar System. The dust from comet 81P/Wild 2 has been shown to be heavily deficient in pre-Solar grains and rich in materials formed at high temperatures in the inner Solar System. Although it is too early to know if this is typical of JFC, it does argue for rapid and thorough mixing of materials in the disk on timescales related to comet formation, and may also suggest outward migration of small icy bodies after their formation. Thus, instead of providing mainly new knowledge of the pre-Solar materials expected to be rich in comets, Stardust and comet 81P/Wild 2 have instead focussed attention on large-scale transport processes during the critical period when cometary parent bodies were forming in the early Solar System.     

Linking Remote-Sensing and <Emphasis Type="Italic">In Situ</Emphasis> Observations of Coronal Mass Ejections Using STEREO

The twin STEREO spacecraft have been observing the Sun since 2006. Even though STEREO has only been active during solar minimum conditions so far, an important number of coronal mass ejections (CMEs) and their interplanetary counterparts (ICMEs) have been observed. Many of the ICMEs can be linked back to the corresponding CMEs on the Sun through the combination of remote-sensing and in situ observations. This paper aims to answer the question whether a CME observed by a coronagraph will be detected in situ by a spacecraft in a specific location in the heliosphere. We use a flux-rope-like model fit to the STEREO SECCHI/COR2 data to obtain the direction of CME propagation and its geometrical configuration in three dimensions. Based on model parameters, we then calculate their angular widths and determine whether they should have been detected by STEREO-A, STEREO-B, Wind or ACE. We compare the results with corresponding in situ observations of ICMEs. We find that predictions of ICME detections on the base of COR2 data generally match well the actual in situ observations.     

Influence of m-cresol purple indicator additions on the pH of seawater samples: correction factors evaluated from a chemical speciation model

The perturbation of the indicator m-cresol purple on the pH in seawater is illustrated in diagrams, representing measurements in 1-cm and 5-cm cells. The diagrams apply to a measured pH interval of 7.4–8.4 using a 2-mM stock solution of m-cresol purple sodium salt dissolved in seawater. The magnitude of the perturbation is described as correction values, i.e., the change in seawater pH caused by the indicator. The diagrams are based on calculations made by using the equilibrium speciation programme, MARINHALT. From these calculations, and least squares fitting methods, pH correction values are described in terms of the pH difference between each seawater sample and the pH of an indicator stock solution. Calculations are performed for a typical high latitude water and a north Pacific deep water. Diagrams are presented for a salinity of 35 and a temperature of 15°C. Responses to salinities between 32 and 36 and temperatures 15–25°C are illustrated as well. A ±0.05 pH difference between a seawater sample and an indicator stock solution gives a correction of less than 0.001 pH unit for a 1-cm cell. For a 5-cm cell, pH differences between the indicator stock solution and a seawater sample as large as ±0.3 cause corrections smaller than ±0.001 pH unit. Calculations demonstrate that the five-fold lower indicator concentration used with 5-cm cells decreases the perturbation effect by approximately a factor of five relative to 1-cm cells.