Molecular distribution, 13C‐isotope,and enantiomeric compositions of carbonaceous chondrite monocarboxylic acids

The water‐soluble organic compounds in carbonaceous chondrite meteorites constitute a record of the synthetic reactions occurring at the birth of the solar system and those taking place during parent body alteration and may have been important for the later origins and development of life on Earth. In this present work, we have developed a novel methodology for the simultaneous analysis of the molecular distribution, compound‐specific δ¹³C, and enantiomeric compositions of aliphatic monocarboxylic acids (MCA) extracted from the hot‐water extracts of 16 carbonaceous chondrites from CM, CR, CO, CV, and CK groups. We observed high concentrations of meteoritic MCAs, with total carbon weight percentages which in some cases approached those of carbonates and insoluble organic matter. Moreover, we found that the concentration of MCAs in CR chondrites is higher than in the other meteorite groups, with acetic acid exhibiting the highest concentration in all samples. The abundance of MCAs decreased with increasing molecular weight and with increasing aqueous and/or thermal alteration experienced by the meteorite sample. The δ¹³C isotopic values of MCAs ranged from ?52 to +27‰, and aside from an inverse relationship between δ¹³C value and carbon straight‐chain length for C₃–C₆ MCAs in Murchison, the ¹³C‐isotopic values did not correlate with the number of carbon atoms per molecule. We also observed racemic compositions of 2‐methylbutanoic acid in CM and CR chondrites. We used this novel analytical protocol and collective data to shed new light on the prebiotic origins of chondritic MCAs.     

(U‐Th)/He zircon dating of Chesapeake Bay distal impact ejecta from ODP site 1073

Single crystal (U‐Th)/He dating has been undertaken on 21 detrital zircon grains extracted from a core sample from Ocean Drilling Project (ODP) site 1073, which is located ~390 km northeast of the center of the Chesapeake Bay impact structure. Optical and electron imaging in combination with energy dispersive X‐ray microanalysis (EDS) of zircon grains from this late Eocene sediment shows clear evidence of shock metamorphism in some zircon grains, which suggests that these shocked zircon crystals are distal ejecta from the formation of the ~40 km diameter Chesapeake Bay impact structure. (U‐Th/He) dates for zircon crystals from this sediment range from 33.49 ± 0.94 to 305.1 ± 8.6 Ma (2σ), implying crystal‐to‐crystal variability in the degree of impact‐related resetting of (U‐Th)/He systematics and a range of different possible sources. The two youngest zircon grains yield an inverse‐variance weighted mean (U‐Th)/He age of 33.99 ± 0.71 Ma (2σ uncertainties n = 2; mean square weighted deviation = 2.6; probability [P] = 11%), which is interpreted to be the (U‐Th)/He age of formation of the Chesapeake Bay impact structure. This age is in agreement with K/Ar, ⁴⁰Ar/³⁹Ar, and fission track dates for tektites from the North American strewn field, which have been interpreted as associated with the Chesapeake Bay impact event.     

Analysis of the morphological structures of comet 1P/Halley in the perihelion passages in 1910 and 1986

This work is based on a systematic analysis of images of comet 1P/Halley collected during its penultimate and ultimate approaches, i.e., in 1910 and 1986. This research has identified, characterized, classified, and compared tail structures of comet 1P/Halley, namely disconnection events (DEs), wavy structures, and solitons. The images of the comet during its 1910 passage, as illustrated in the Atlas of Comet Halley 1910 II (Donn et al. 1986), were compared with those of its approach in 1986 as illustrated in The International Halley Watch Atlas of Large‐Scale Phenomena (Brandt et al. 1992). Two onsets of DEs were discovered after the perihelion passage in 1910 with an average value of the corrected cometocentric velocity (Vc) of 57 ± 15 km s^?1. Ten onsets of DEs were discovered after the perihelion passage in 1986 with an average Vc equal to 130 ± 37 km s^?1. The mean value of the corrected wavelength λc of wavy structures in 1910 is equal to 1.7 ± 0.1 × 10⁶ km, as compared to 2.2 ± 0.2 × 10⁶ km in 1986. The mean value of the amplitude A of the wave in 1910 is equal to 1.4 ± 0.1 × 10⁵ km and 2.8 ± 0.5 × 10⁵ km in 1986. The goals of this research were to report the results obtained from the analysis of the P/Halley's images from 1910 and 1986, to provide empirical data for comparison, and to form the input for future physical/theoretical work.     

New observations on high‐pressure phases in a shock melt vein in the Villalbeto de la Peña meteorite: Insights into the shock behavior of diopside

The petrology and mineralogy of shock melt veins in the L6 ordinary chondrite host of Villalbeto de la Peña, a highly shocked, L chondrite polymict breccia, have been investigated in detail using scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and electron probe microanalysis. Entrained olivine, enstatite, diopside, and plagioclase are transformed into ringwoodite, low‐Ca majorite, high‐Ca majorite, and an assemblage of jadeite‐lingunite, respectively, in several shock melt veins and pockets. We have focused on the shock behavior of diopside in a particularly large shock melt vein (10 mm long and up to 4 mm wide) in order to provide additional insights into its high‐pressure polymorphic phase transformation mechanisms. We report the first evidence of diopside undergoing shock‐induced melting, and the occurrence of natural Ca‐majorite formed by solid‐state transformation from diopside. Magnesiowüstite has also been found as veins injected into diopside in the form of nanocrystalline grains that crystallized from a melt and also occurs interstitially between majorite‐pyrope grains in the melt‐vein matrix. In addition, we have observed compositional zoning in majorite‐pyrope grains in the matrix of the shock‐melt vein, which has not been described previously in any shocked meteorite. Collectively, all these different lines of evidence are suggestive of a major shock event with high cooling rates. The minimum peak shock conditions are difficult to constrain, because of the uncertainties in applying experimentally determined high‐pressure phase equilibria to complex natural systems. However, our results suggest that conditions between 16 and 28 GPa and 2000–2200 °C were reached.     

Upgrading of Oil Shale by Flotation Without Collector

Natural Resources Research - Oil shale impurities prevent its direct usage as a source of energy. Removing or reducing of these impurities before retorting can reduce the cost of oil shale...     

Three-Dimensional Petrophysical Modelling and Volumetric Analysis to Model the Reservoir Potential of the Kupe Field,Taranaki Basin,New Zealand

Natural Resources Research - This study addresses the three-dimensional (3D) petrophysical modelling and volumetric analysis of the Farewell Reservoir in the Kupe Field in the southern Taranaki...     

Subpollen Particles as Atmospheric Cloud Condensation Nuclei

Izvestiya, Atmospheric and Oceanic Physics - Bioparticles constitute a significant fraction of atmospheric aerosol. Their size range varies from nanometers (macromolecules) to hundreds of...     

Modeling the Seasonal Dynamics of the Diurnal Variation of the Global Electric Circuit

Izvestiya, Atmospheric and Oceanic Physics - On the basis of a parametrization of the ionospheric potential (IP), the seasonal dynamics of the diurnal IP variation for 2016–2017 is simulated...     

Note on the age and fauna of the Lynton Beds (Lower Devonian) of north Devon

The Lynton Beds represent shallow marine sediments with a restricted fauna dominated by brachiopods. The age indicated by the brachiopod fauna is late Emsian, although the possibility of a younger date for the uppermost horizons cannot be discounted.     

S 10830 Trianguli – ein interessanter kataklymischer Veränderlicher

With the aid of silt spectrograms gained at the 6 meter telescope Selenchukskaja and at the 2 meter telescope Tautenburg a brightness outburst (the only one so far observed) could be followed up spectroscopically. The spectral behaviour resembles SS Cygni, but the presence of CIII and NIII emission is not typical of dwarf novae. Possibly the object is related to the anomalous recurrent nova WZ Sge. The definite determination of its belonging to a known subclass of cataclysmic variables will be possible only after obtainment of extensive photometric material.