The Electron Energy Spectrum from Large Solar Flares

We report on the differential electron spectrum for intense transient events seen at one AU by the EPAM instrument on the Advanced Composition Explorer (ACE) spacecraft. Over an observing period from September 1997 to September 2005, there were 45 major events that could be reliably identified with a source flare on the Sun. In the ∼40 – 300 keV energy range, the electron spectral index was between one and three for all but two of the events. Twenty-five of the events were associated with Geostationary Operational Environmental Satellites (GOES) X-ray class X flares. We compare this result with the spectral index measured from electron pulse events, lasting approx. one hour or less, where the spectral index is typically much softer than three. This suggests that the measured spectral index of near-relativistic electrons at one AU may be a reliable indicator of the source. We also examine the likelihood that fast coronal mass ejections (CMEs) are responsible in themselves for accelerating near-relativistic electrons and conclude that they do not.     

A major sulphur isotope event at c. 510 Ma: a possible anoxia–extinction–volcanism connection during the Early–Middle Cambrian transition?

A new approach to constraining seawater δ³⁴S and sulphate concentration using francolite‐bound sulphate reveals an abrupt increase in δ³⁴S to +50‰ around the Early–Middle Cambrian boundary. Such high δ³⁴S values are best explained by increased rates of pyrite burial due to ocean anoxia coupled with an increased sensitivity of the ocean sulphate reservoir to perturbations due to low sulphate concentrations of 500–700 μgL^?1. We argue that the spread of anoxic waters at this time was partly the result of greenhouse warming related to the eruption of the Kalkarindji Large Igneous Province of northern Australia and that it triggered the collapse of early metazoan reef ecosystems during the latest Early Cambrian. Mass extinctions of the last 260 Myr have all coincided with enhanced volcanic activity, while several are also associated with positive shifts in seawater δ³⁴S. Extending this correlation back in time further implicates volcanically induced climate change as a major determining factor in biosphere evolution. Terra Nova, 18, 257–263, 2006     

Radiative Transfer in Inhomogeneous Atmospheres. III

The approach proposed in the previous parts of this series of papers is used to solve the radiative transfer problem in scattering and absorbing multicomponent atmospheres. Linear recurrence relations are obtained for both the reflectance and transmittance of these kinds of atmospheres, as well as for the emerging intensities when the atmosphere contains energy sources. Spectral line formation in a one-dimensional inhomogeneous atmosphere is examined as an illustration of the possibility of generalizing our approach to the matrix case. It is shown that, in this case as well, the question reduces to solving an initial value problem for linear differential equations. Some numerical calculations are presented.     

On the Nature of the Object HD 209458b: Conclusions Drawn from Comparison of Experimental and Theoretical Data

The experimental data obtained in transit observations of the extrasolar planet HD 209458b and their comparison with theoretical inferences have led to the conclusions that HD 209458b (and other similar hot jupiters) is of a (mainly) hydrogen nature and that these objects probably possess strong magnetic fields. The results of the studies of HD 209458b and prospects for searches for the transits of other extrasolar planets are considered in detail.     

Chemical alteration of tephra in the depositional environment: theoretical stability modelling

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.     

Microtextures and crystal chemistry in P21/c pigeonites

Summary ?A single-crystal X-ray investigation was performed on crystals of P2₁/c natural pigeonite with varying Ca and Fe^* ( = Fe²⁺ + Mn²⁺) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae. The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated. The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples. In particular, it is shown that Ca and Fe^* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and decrease the difference between the M2–O3 distances. Received October 18, 2001; revised version accepted February 15, 2002     

A qualitative and quantitative evaluation of experimental model catchment evolution

Due to the geological time scales required for observation of catchment evolution, surrogates or analogues of field data are necessary to understand long‐term processes. To investigate long‐term catchment behaviour, two experimental model catchments that developed without rigid boundaries under controlled conditions are examined and a qualitative and quantitative analysis of their evolution is presented. Qualitatively, the experimental catchments have the visual appearance of field scale data. Observation demonstrates that changes in catchment shape and network form are conservative. Quantitative analysis suggests that the catchments reach an equilibrium form while a reduction in the channel network occurs. While the catchments are laboratory scale models, the results provide insights into field scale behaviour. Copyright © 2003 John Wiley & Sons, Ltd.