Impact of Berm Breaching on Hyperbenthic Macroinvertebrate Communities in Intermittently Closed Estuaries

Berm breaching of intermittently closed estuaries, either naturally or due to management practices, results in a physicochemical disturbance due to the flushing of water, material and biota into the ocean and the subsequent tidal influx. In 2007 and 2008 comparative and controlled studies were employed in three New Zealand estuaries: Sawmill Creek (46°04′ S 170°12′ E), Otokia Creek (45°57′ S 179°20′ E) and Kaikorai Lagoon (45°56′ S 170°23′ E), to investigate the impact of berm breaching on the hyperbenthic macroinvertebrate community in intermittently closed estuaries. Significant changes in community structure occurred in both the weekly comparative and the controlled studies (ANOSIM P < 0.01). Furthermore, the catch per unit effort of both total and key invertebrate taxa significantly increased after breaching (ANOVA P < 0.01). However, substantial numbers of individuals were expelled into the ocean (5,800 individuals, 20-min sample) while new taxa immigrated into the estuaries. Along with migration-related changes to community structure, berm breaches also resulted in the loss of ∼80% of inundated habitat and the concentration of existing populations. Consequently, the management of intermittent estuary connections to the ocean has implications for the ecology of individual, managed estuaries and also for regional coastal populations of epibenthic invertebrates.     

Prediction of phytoavailability of trace metals to plants: Comparison between chemical extractions and soil-grown radish

One of the major routes of human exposure to toxic metals is the consumption of vegetables grown on contaminated soils. Radishes were grown in three different soils (kitchen garden, agricultural and industrial soils), presenting various contamination levels. A sequential extraction procedure was compared with EDTA and HCl simple extractions methods in order to predict the metals phytoavailabilty to radish. The analysis of the results shows that the simple HCl and sequential chemical extractions bring complementary results, since HCl is correlated in the phytoavailability of Cd, Mn and Zn, whereas the sequential extraction is correlated in the phytoavailability of Cr, Fe, Mn, Ni. EDTA simple extraction brings here less interesting results than the two other tested extractions.     

High-resolution subtropical summer precipitation derived from dynamical downscaling of the NCEP/DOE reanalysis: how much small-scale information is added by a regional model?

This study assesses the regional-scale summer precipitation produced by the dynamical downscaling of analyzed large-scale fields. The main goal of this study is to investigate how much the regional model adds smaller scale precipitation information that the large-scale fields do not resolve. The modeling region for this study covers the southeastern United States (Florida, Georgia, Alabama, South Carolina, and North Carolina) where the summer climate is subtropical in nature, with a heavy influence of regional-scale convection. The coarse resolution (2.5° latitude/longitude) large-scale atmospheric variables from the National Center for Environmental Prediction (NCEP)/DOE reanalysis (R2) are downscaled using the NCEP/Environmental Climate Prediction Center regional spectral model (RSM) to produce precipitation at 20?km resolution for 16 summer seasons (1990?C2005). The RSM produces realistic details in the regional summer precipitation at 20?km resolution. Compared to R2, the RSM-produced monthly precipitation shows better agreement with observations. There is a reduced wet bias and a more realistic spatial pattern of the precipitation climatology compared with the interpolated R2 values. The root mean square errors of the monthly R2 precipitation are reduced over 93% (1,697) of all the grid points in the five states (1,821). The temporal correlation also improves over 92% (1,675) of all grid points such that the domain-averaged correlation increases from 0.38 (R2) to 0.55 (RSM). The RSM accurately reproduces the first two observed eigenmodes, compared with the R2 product for which the second mode is not properly reproduced. The spatial patterns for wet versus dry summer years are also successfully simulated in RSM. For shorter time scales, the RSM resolves heavy rainfall events and their frequency better than R2. Correlation and categorical classification (above/near/below average) for the monthly frequency of heavy precipitation days is also significantly improved by the RSM.     

中国日降雨量变化特征分析

将旋转主成分分析和复变量莫莱特小波分析应用于14a中国境内实测与ECMWF再分析日降雨量资料,研究其年际、季际与季节内变化的时空分布特征和再分析日降雨量资料的有效性。结果表明:从实测资料中分析的降水特征,都可以由再分析资料再现出来。除周内振荡大有出入外,其余频率的振荡二者大致相符或基本吻合。因此,周内振荡还不能被再分析数据较好地刻划,但是与旱涝灾害和季风爆发联系密切的周际以上振荡,在再分析日降雨量中基本上能被正确地表现出来。     

The effect of iron on montmorillonite stability. (I) Background and thermodynamic considerations

It is envisaged that high-level nuclear waste (HLW) will be disposed of in underground repositories. Many proposed repository designs include steel waste canisters and bentonite backfill. Natural analogues and experimental data indicate that the montmorillonite component of the backfill could react with steel corrosion products to produce non-swelling Fe-rich phyllosilicates such as chamosite, berthierine, or Fe-rich smectite. In K-bearing systems, the alteration of montmorillonite to illite/glauconite could also be envisaged. If montmorillonite were altered to non-swelling minerals, the swelling capacity and self-healing properties of the bentonite backfill could be reduced, thereby diminishing backfill performance. The main aim of this paper was to investigate Fe-rich phyllosilicate mineral stability at the canister-backfill interface using thermodynamic modelling. Estimates of thermodynamic properties were made for Fe-rich clay minerals in order to construct approximate phase-relations for end-member/simplified mineral compositions in logarithmic activity space. Logarithmic activity diagrams (for the system Al₂O₃-FeO-Fe₂O₃-MgO-Na₂O-SiO₂-H₂O) suggest that if pore waters are supersaturated with respect to magnetite in HLW repositories, Fe(II)-rich saponite is the most likely montmorillonite alteration product (if f_O2(g) values are significantly lower than magnetite-hematite equilibrium). Therefore, the alteration of montmorillonite may not be detrimental to nuclear waste repositories that include Fe, as long as the swelling behaviour of the Fe-rich smectite produced is maintained. If f_O2(g) exceeds magnetite-hematite equilibrium, and solutions are saturated with respect to magnetite in HLW repositories, berthierine is likely to be more stable than smectite minerals. The alteration of montmorillonite to berthierine could be detrimental to the performance of HLW repositories.     

A comparative study of the modelling of cement hydration and cement-rock laboratory experiments

The use of cement and concrete as fracture grouting or as tunnel seals in a geological disposal facility for radioactive wastes creates potential issues concerning chemical reactivity. From a long-term safety perspective, it is desirable to be able model these interactions and changes quantitatively. The ‘Long-term Cement Studies’ (LCS) project was formulated with an emphasis on in situ field experiments with more realistic boundary conditions and longer time scales compared with former experiments. As part of the project programme, a modelling inter-comparison has been conducted, involving the modelling of two experiments describing cement hydration on one hand and cement-rock reaction on the other, with teams representing the NDA (UK), Posiva (Finland), and JAEA (Japan).This modelling exercise showed that the dominant reaction pathways in the two experiments are fairly well understood and are consistent between the different modelling teams, although significant differences existed amongst the precise parameterisation (e.g. reactive surface areas, dependences of rate upon pH, types of secondary minerals), and in some instances, processes (e.g. partition of alkali elements between solids and liquid during cement hydration; kinetic models of cement hydration). It was not conclusive if certain processes such as surface complexation (preferred by some modellers, but not by others) played a role in the cement-rock experiment or not. These processes appear to be more relevant at early times in the experiment and the evolution at longer timescales was not affected. The observed permeability profile with time could not be matched. The fact that no secondary minerals could be observed and that the precipitated mass calculated during the simulations is minor might suggest that the permeability reduction does not have a chemical origin, although a small amount of precipitates at pore throats could have a large impact on permeability.The modelling exercises showed that there is an interest in keeping the numerical models as simple as possible and trying to obtain a reasonable fit with a minimum of processes, minerals and parameters. However, up-scaling processes and model parameterisation to the timescales appropriate to repository safety assessment are of considerable concern. Future modelling exercises of this type should focus on a suitable natural or industrial analogue that might aid assessing mineral-fluid reactions at these longer timescales.     

Lithospheric structure beneath the Kenya Dome

Summary. The existence of an anomalously low-velocity, low-density zone within the upper mantle beneath the Kenya Dome has been deduced on the basis of previous gravity and seismic studies. This paper describes an experiment to measure teleseismic delay times across the Gregory Rift near the equator and along a SE radius of the Kenya Dome. The delay times have been determined with good relative accuracy and provide further independent evidence for the existence of the anomalous zone. The pattern of delay times along the two profiles and at other stations indicates that the zone thins rapidly to the SE away from the rift axis, mirroring the attenuation observed, from Kaptagat, for the same zone to the NW. The trend is for the thinning to become very much less rapid with distance, but there is also clear evidence for localized thickening of the zone under the Kilimanjaro–Chyulu volcanic area.
Significantly smaller delay times are measured at the centre of the rift than at the edges. This is shown to indicate that the anomalous zone penetrates the crust to form an intrusion of relatively high-velocity material along the rift axis. The clear correlation of the delay time low with the axial Bouguer high indicates that they are both manifestations of the same underlying structure. Thus the delay time results provide independent confirmation of the existence of the axial intrusion previously inferred from gravity data. The width of this intrusion at the normal base of the crust is well defined by the data as 30 km.