Nature and origin of the BIF-hosted São Bento gold deposit, Quadrilátero Ferrífero, Brazil, with special emphasis on structural controls

The orogenic banded iron formation (BIF)-hosted Au mineralization at São Bento is a structurally-controlled, hydrothermal deposit hosted by Archean rocks of the Rio das Velhas greenstone belt, Quadrilátero Ferrífero region, Brazil. The deposit has reserves of 14.3 t Au and historical (underground) production of 44.6 t Au between 1987 and 2001. The oxide-facies São Bento BIF is mineralized at its lower portion, where in contact with carbonaceous, pelitic schists, particularly in the proximity of sulfide-bearing quartz veins. Shear-related Au deposition is associated with the pervasive, hydrothermal sulfidation (mainly arsenopyrite) of the Fe-rich bands of the São Bento BIF. Auriferous, sulfide- and quartz-rich zones represent proximal alteration zones. They are enveloped by ankerite-dominated haloes, which reflect progressive substitution of siderite and magnetite within the BIF by ankerite and pyrrhotite, respectively. The São Bento BIF was intensely and extensively deformed, first into open, upright folds that evolved into tight, asymmetric, isoclinal folds. The inverse limb of these folds attenuated and gave way to sheath folds and the establishment of ductile thrusts. Mineralized horizons at São Bento result from early structural modifications imposed by major transcurrent and thrusts faults, comprising the Conceição, Barão de Cocais and São Bento shear zones. Dextral movement on the SW–NE-directed Conceição shear zone may have generated splays at a compressional side-stepping zone, such as the São Bento shear zone, which is the structural locus for the São Bento gold mineralization. Relaxation of the Conceição shear zone under more brittle conditions resulted in the development of dilatational zones where gold–sulfide–quartz veins formed. These structures are considered to have been generated in the Archean. Geochronological data are scarce, with Pb–Pb analyses of refractory arsenopyrite and pyrite from bedded and remobilized ore plotting on a single-stage growth curve at 2.65 Ga. A later compressional, ductile deformation of unknown age overprinted, rotated and flattened the original, N60E-directed structure of the whole rock succession, with development of planar and linear fabrics that appear similar to Proterozoic-aged structures. Fluid inclusion studies indicate low salinity, aqueous fluids, with or without CO₂ and/or CH₄, with extremely variable CO₂/CH₄ ratios, of probable metamorphic origin. Fluid evolution shows a paragenetic decrease in the carbonic phase from 10–15% to 5%, and increase in the H₂O/(CO₂ + CH₄) and CO₂/CH₄ ratios, suggesting important interaction with carbonaceous sediment. Trapping conditions indicate a temperature of 300 °C at 3.2 kbar.     

The influence of lithology on surface water sources

Understanding the temporal and spatial variability of water sources within a basin is vital to our ability to interpret hydrologic controls on biogeochemical processes and to manage water resources. Water stable isotopes can be used as a tool to determine geographic and seasonal sources of water at the basin scale. Previous studies in the Coastal Range of Oregon reported that the variation in the isotopic signatures of surface water did not conform to the commonly observed “elevation effect,” which exhibits a trend of increasing isotopic depletion with rising elevation. The primary purpose of this research is to investigate the mechanisms governing seasonal and spatial variations in the isotopic signature of surface waters within the Marys River Basin, located in the leeward side of the Oregon Coastal Range. Surface water and precipitation samples were collected every 2–3 weeks for isotopic analysis for 1 year. Our results confirmed the lack of elevational variation of surface water isotopes within this leeward basin. Although we find elevational variation in precipitation in the eastern portion of the watershed, this elevation effect is counteracted by rainout with distance from the Pacific coast. In addition, we found significant variation in surface water isotope values between catchments underlain predominantly by basalt or sandstone. The degree of separation was strongest during the summer when low flows reflect deeper groundwater sources. This indicates that baseflow within streams drained by each lithology is being supplied from two distinctly separate water sources. In addition, the flow of the Marys River is dominated by water originating from the sandstone water source, particularly during the low‐flow summer months. We interpreted that the difference in water source results from sandstone catchments having highly fractured geology or locally tipping to the east facilitating cross‐basin water exchange from the windward to the leeward side of the Coast Range. Our results challenge topographic derived watershed boundaries in permeable sedimentary rocks; highlighting the overwhelming importance of underlying geology.     

Ecological limits to terrestrial biological carbon dioxide removal

Terrestrial biological atmospheric carbon dioxide removal (BCDR) through bioenergy with carbon capture and storage (BECS), afforestation/reforestation, and forest and soil management is a family of proposed climate change mitigation strategies. Very high sequestration potentials for these strategies have been reported, but there has been no systematic analysis of the potential ecological limits to and environmental impacts of implementation at the scale relevant to climate change mitigation. In this analysis, we identified site-specific aspects of land, water, nutrients, and habitat that will affect local project-scale carbon sequestration and ecological impacts. Using this framework, we estimated global-scale land and resource requirements for BCDR, implemented at a rate of 1 Pg C y^?1. We estimate that removing 1 Pg C y^?1 via tropical afforestation would require at least 7?×?10⁶ ha y^?1 of land, 0.09 Tg y^?1 of nitrogen, and 0.2 Tg y^?1 of phosphorous, and would increase evapotranspiration from those lands by almost 50 %. Switchgrass BECS would require at least 2?×?10⁸ ha of land (20 times U.S. area currently under bioethanol production) and 20 Tg y^?1 of nitrogen (20 % of global fertilizer nitrogen production), consuming 4?×?10¹²?m³ y^?1 of water. While BCDR promises some direct (climate) and ancillary (restoration, habitat protection) benefits, Pg C-scale implementation may be constrained by ecological factors, and may compromise the ultimate goals of climate change mitigation.     

Use of sedimentary diatoms from multiple lakes to distinguish between past changes in trophic state and climate: evidence for climate change in northern Germany during the past 5,000 years

Fossil diatoms from lake sediments have been used to infer both past trophic state and climate conditions. In Europe, climate reconstructions focused on northern and alpine regions because these areas are climatically sensitive and anthropogenic impact was low. In contrast, anthropogenic impact was often high in the central European lowlands, such as northern Germany, beginning in the Neolithic Age, ~3700 BC. Since that time, trophic state change was the main factor that affected diatom assemblages in central European lowland lakes. Therefore, it was considered difficult or impossible to identify climate changes in the region using sedimented diatoms. We used diatom assemblage changes, diatom-inferred total phosphorus concentrations and the relative abundance of planktonic diatoms from sediments of three lakes that differ in their location, size, morphology, catchment area and current trophic state to test whether we could distinguish between trophic state and climate signals over the past 5,000 years in northern Germany. In this study, changes in trophic state and climate were well differentiated. In the study lakes, relative abundance of planktonic diatoms seems to be linked to the length of lake mixing phases. Planktonic diatom abundance decreased during years with shorter mixing duration, and these shorter mixing times probably reflect colder winters. The diatom-inferred periods of short mixing phases from 1000 BC to AD 500 and from AD 1300 to 1800 coincide well with two known cooling phases in Europe and the North Atlantic region.     

Atmospheric models of He-peculiar stars: synthetic He I line profiles and absolute visual magnitudes

We analyze the influence of magnetic pressure effects on the atmospheric structure of B peculiar type stars, as well as, on the emergent He?I line profiles and absolute visual magnitudes. We consider a photosphere in local thermodynamic and hydrostatic equilibrium. The hydrostatic equilibrium equation is modified to include the Lorentz force. Atomic occupational numbers are computed in LTE considering non-ideal effects in the gas equation of state. We depict the influence of a magnetic field on local He?I line profiles and discuss the effects of the helium abundance in magnetic B-type stars. The Lorentz force might explain local variations up to 7 % in the equivalent width of helium lines, while local enhancements of He chemical abundances would produce larger changes. To analyze the line variations in real stars we computed the net contribution of a bipolar magnetic field over the stellar disk. The resulting disk-averaged magnetic field predicts variations with the rotation phase up to 2–3 % in the line EWs for a dipolar magnetic field of 1000 G.     

The transient response mechanism and Pi2 pulsations at substorm onset—Review and outlook

Pi2 pulsations are nowadays thought to be transient hydromagnetic signals associated with the build-up of a new stationary magnetosphere-ionosphere coupling system after the sudden formation of the substorm current wedge. To illustrate this transient response mechanism, we will first briefly describe the substorm current circuit. Subsequently, we will demonstrate that the gross characteristics of high-latitude Pi2 can be explained by the sudden switch-on of this current wedge during substorm onset if its westward expansion is taken into account. We will conclude by discussing some additional phenomena and processes (like conductivity and electron density gradients, kinetic Alfvén waves, ionospheric polarization electric fields, and mode coupling) which have to be included into a realistic model for Pi2 pulsations and thus timedependent magnetosphere-ionosphere coupling.     

Consistent estimation of geodetic parameters from SLR satellite constellation measurements

In this paper, we consistently estimate geodetic parameters such as weekly 3-D station coordinates, Earth orientation parameters (EOP) including daily x/y-pole coordinates and the excess length of day \(\Delta \hbox {LOD}\), and selected weekly Earth’s gravitational field (Stokes) coefficients up to degree and order 6 from Satellite Laser Ranging measurements to up to 11 geodetic satellites. The SLR constellation consists of LAGEOS-1/2, Etalon-1/2, Stella, Starlette, Ajisai, Larets, LARES, BLITS and WESTPAC, and its observations cover a time span of 38 years ranging from February 16, 1979, to April 30, 2017. If multiple satellites with various altitudes and orbit inclinations are combined, correlations between estimated parameters are significantly reduced. This allows us (i) to investigate the ability of satellite constellations to reduce existing correlations and (ii) to estimate reliable parameters with higher precision compared to the standard 4-satellite constellation (LAGEOS-1/2, Etalon-1/2) which is currently used by the International Laser Ranging Service for the determination of the Terrestrial Reference Frame (TRF) and EOP products. In particular, the Stokes coefficients, EOP and TRF datum parameters (three translations, three rotations, one scale factor), which are highly correlated with satellite-specific orbit parameters, are improved. From our investigations, we found for an 11-satellite solution compared to the above-mentioned 4-satellite solution a decrease in the scatter of the TRF datum parameters of up to 37%, the transformation residuals are decreased by up to 22%, the scatter of the EOP is decreased by up to 22%, and their mean values are decreased by up to 84% w.r.t. the reference solutions. The largest improvement is obtained for the Stokes coefficients which significantly benefit from a combination of multiple satellites (inclinations and orbit altitudes). In total, single coefficients are improved by up to 93% and the overall improvement is up to 74%. Moreover, it could be clearly identified that Ajisai significantly disturbs the TRF solution due to an erroneous center-of-mass correction. We further quantify the impact of specific satellites on the determination of different geodetic parameters and finally evaluate the potential of the existing SLR-tracked spherical satellite constellation to support the goals of GGOS.     

A geoprivacy manifesto

As location‐enabled technologies are becoming ubiquitous, our location is being shared with an ever‐growing number of external services. Issues revolving around location privacy—or geoprivacy—therefore concern the vast majority of the population, largely without knowing how the underlying technologies work and what can be inferred from an individual's location (especially if recorded over longer periods of time). Research, on the other hand, has largely treated this topic from isolated standpoints, most prominently from the technological and ethical points of view. This article therefore reflects upon the current state of geoprivacy from a broader perspective. It integrates technological, ethical, legal, and educational aspects and clarifies how they interact and shape how we deal with the corresponding technology, both individually and as a society. It does so in the form of a manifesto, consisting of 21 theses that summarize the main arguments made in the article. These theses argue that location information is different from other kinds of personal information and, in combination, show why geoprivacy (and privacy in general) needs to be protected and should not become a mere illusion. The fictional couple of Jane and Tom is used as a running example to illustrate how common it has become to share our location information, and how it can be used—both for good and for worse.