Linear dichroism in ALD layers of TiO2

We prepare TiO₂ film by ALD and study their electronic properties by soft X-ray absorption spectroscopy (XAS) and photoelectron spectroscopy. We focus on XAS and X-ray linear dichroism to indentify band onset and learn about local distortion of the Ti–O octahedral atomic and about defects which cause Ti-based electronic states within the band gap.     

Ambient pressure thermal desorption spectroscopy (AP-TDS) of NiO/SiO2 catalysts

The Sabatier reaction is a key process in the “power-to-gas” application which is considered to contribute to future chemical energy storage systems. In this contribution we focus on the catalytic active sites of a NiO catalyst supported on SiO₂ (NiO/SiO₂) which is commonly used in the Sabatier reaction. A novel technique for the characterization of the active sites is presented and discussed using thermal desorption spectroscopy at ambient pressure. This analytical tool is operated under reaction conditions and allows element specific measurements during the catalytic process of CO₂ reforming towards methane. Beside the desorption experiments, XPS and XAS measurements of pristine and catalytically used samples are performed to determine the influence of the Sabatier reaction conditions on the surface structure of the catalyst.     

中国日降雨量变化特征分析

将旋转主成分分析和复变量莫莱特小波分析应用于14a中国境内实测与ECMWF再分析日降雨量资料,研究其年际、季际与季节内变化的时空分布特征和再分析日降雨量资料的有效性。结果表明:从实测资料中分析的降水特征,都可以由再分析资料再现出来。除周内振荡大有出入外,其余频率的振荡二者大致相符或基本吻合。因此,周内振荡还不能被再分析数据较好地刻划,但是与旱涝灾害和季风爆发联系密切的周际以上振荡,在再分析日降雨量中基本上能被正确地表现出来。     

Evaluation of daily precipitation in China from ECMWF and NCEP reanalyses

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Comparisons of the four Miller Range nakhlites,MIL 03346, 090030, 090032 and 090136: Textural and compositional observations of primary and secondary mineral assemblages

Abstract– Petrological and geochemical analyses of Miller Range (MIL) 03346 indicate that this meteorite originated from the same augitic cumulate layer(s) as the nakhlite Martian meteorites, but underwent rapid cooling prior to complete crystallization. As with the other nakhlites, MIL 03346 contains a secondary alteration assemblage, in this case consisting of iddingsite‐like alteration veins in olivine phenocrysts, Fe‐oxide alteration veins associated with the mesostasis, and Ca‐ and K,Fe‐sulfate veins. We compared the textural and mineralogical compositions of MIL 090030, 090032, and 090136 with MIL 03346, focusing on the composition and Raman spectra of the alteration assemblages. These observations indicate that the meteorites are paired, and that the preterrestrial olivine‐bound alteration assemblages were produced by weakly acidic brine. Although these alteration assemblages resemble similar assemblages in Nakhla, the absence of siderite and halite in the Miller Range nakhlites indicates that the parental alteration brine was comparatively HCO₃^? depleted, and less concentrated, than that which altered Nakhla. This indicates that the Miller Range nakhlite alteration brine experienced a separate evolutionary pathway to that which altered Nakhla, and therefore represents a separate branch of the Lafayette‐Nakhla evaporation sequence. Thin‐sections cut from the internal portions of these meteorites (away from any fusion crust or terrestrially exposed edge), contain little Ca‐sulfate (identified as gypsum), and no jarosite, whereas thin‐sections with terrestrially exposed edges have much higher sulfate abundances. These observations suggest that at least the majority of sulfate within the Miller Range nakhlites is terrestrially derived.     

Pi 2 pulsations and the eastward electrojet: A case study

We report the results of a case study of two Pi 2 pulsations observed near the eastward electrojet by the Scandinavian Magnetometer Array. The power of the two Pi 2 pulsations, calculated using a standard Fast Fourier Transform method, peaks near the centre of the eastward electrojet. For both events there is a strong latitudinal gradient in the power poleward of the equatorward border of the electrojet. The sense of polarisation is predominantly clockwise at the northern stations and anticlockwise at the southern stations although the reversal from clockwise to anticlockwise does not occur at a constant latitude. For the first event the polarisation reversal occurs at higher latitudes in the western half of the array; for the second the polarisation reversal occurs at higher latitudes at the edges of the array. The polarisation reversal does not appear to be related to the location of the eastward electrojet. Equivalent current vectors of the Pi 2 pulsations, obtained by rotating the band pass filtered data through 90°, exhibit clear vortex structures in both events. The vortices change sense of direction at half the period of the Pi 2 pulsation. A simple model for the ionospheric electric field in accord with the field line resonance theory reconstructs the basic features of the observed Pi 2 equivalent current system. We thus conclude that Pi 2 signatures in the region of the eastward electrojet and far away from the auroral break-up region are governed by the field line resonance mechanism.     

Auckland and the creative industries: the spatial distribution of the design subsector

Auckland is New Zealand’s largest city with the largest concentration of creative sector employment and businesses in the country. This paper examines the spatial distribution of firms in the design creative subsector across the Auckland Region and in inner Auckland and ascertains the key determinants of firm location. The macrolevel findings indicate that the architectural and specialized design firms have similar spatial distribution patterns across the Auckland Region, while the advertising subsector demonstrates an extreme tendency toward spatial concentration only in inner Auckland. All three subsectors have a strong propensity to clustering within inner Auckland; however, one CBD (Central Business District) fringe area, Parnell outperforms the rest. The microlevel findings reveal hybridized creative clusters of uneven density. Parnell’s unique brand and place-specific characteristics were the key determinants of firm location which led to the spontaneous collocation of firms. These location decisions had the unintended consequence of creating agglomeration economies.