Dynamic subsidence of Eastern Australia during the Cretaceous

During the Early Cretaceous Australia's eastward passage over sinking subducted slabs induced widespread dynamic subsidence and formation of a large epeiric sea in the eastern interior. Despite evidence for convergence between Australia and the paleo-Pacific, the subduction zone location has been poorly constrained. Using coupled plate tectonic–mantle convection models, we test two end-member scenarios, one with subduction directly east of Australia's reconstructed continental margin, and a second with subduction translated ~ 1000 km east, implying the existence of a back-arc basin. Our models incorporate a rheological model for the mantle and lithosphere, plate motions since 140 Ma and evolving plate boundaries. While mantle rheology affects the magnitude of surface vertical motions, timing of uplift and subsidence depends on plate boundary geometries and kinematics. Computations with a proximal subduction zone result in accelerated basin subsidence occurring 20 Myr too early compared with tectonic subsidence calculated from well data. This timing offset is reconciled when subduction is shifted eastward. Comparisons between seismic tomography and model temperature cross-sections, and an absence of subduction zone volcanism in eastern Australia in the Early Cretaceous provide support for the back-arc basin scenario.     

Environmental variability in Lake Naivasha,Kenya, over the last two centuries

Lake Naivasha, Kenya, is one of a number of freshwater lakes in the East African Rift System. Since the beginning of the twentieth century, it has experienced greater anthropogenic influence as a result of increasingly intensive farming of coffee, tea, flowers, and other horticultural crops within its catchment. The water-level history of Lake Naivasha over the past 200 years was derived from a combination of instrumental records and sediment data. In this study, we analysed diatoms in a lake sediment core to infer past lacustrine conductivity and total phosphorus concentrations. We also measured total nitrogen and carbon concentrations in the sediments. Core chronology was established by ²¹⁰Pb dating and covered a ~186-year history of natural (climatic) and human-induced environmental changes. Three stratigraphic zones in the core were identified using diatom assemblages. There was a change from littoral/epiphytic diatoms such as Gomphonema gracile and Cymbella muelleri, which occurred during a prolonged dry period from ca. 1820 to 1896 AD, through a transition period, to the present planktonic Aulacoseira sp. that favors nutrient-rich waters. This marked change in the diatom assemblage was caused by climate change, and later a strong anthropogenic overprint on the lake system. Increases in sediment accumulation rates since 1928, from 0.01 to 0.08 g cm⁻² year⁻¹ correlate with an increase in diatom-inferred total phosphorus concentrations since the beginning of the twentieth century. The increase in phosphorus accumulation suggests increasing eutrophication of freshwater Lake Naivasha. This study identified two major periods in the lake’s history: (1) the period from 1820 to 1950 AD, during which the lake was affected mainly by natural climate variations, and (2) the period since 1950, during which the effects of anthropogenic activity overprinted those of natural climate variation.     

Aquifer heat storage: sulphate reduction with acetate at increased temperatures

Aquifer thermal energy storage in urban and industrial areas can lead to an increase in subsurface temperature to 70 °C and more. Besides its impacts on mineral and sorption equilibria and chemical reaction kinetics in an aquifer, temperature sensitively influences microbial activity and thus redox processes, such as sulphate reduction. Microorganism species can only operate within limited temperature ranges and their adaptability to temperature is a crucial point for the assessment of the environmental consequences of subsurface heat storage. Column experiments with aquifer sediment and tap water at 10, 25, 40, and 70 °C showed that under the constant addition of acetate sulphate reduction could be initiated after 26–63 pore volumes exchanged at all temperatures. Fastest initiation of sulphate reduction with the highest reduction rates was found at 40 °C. Maximum rate constants during experimental run-time were 0.56 h^?1 at 40 °C and 0.33, 0.36, and 0.25 h^?1 at 10 and, 25, and 70 °C, respectively. Hence, microbial activity was enhanced by a temperature increase to 40 °C but was significantly lowered at 70 °C. At 25 °C methane was found in solution, indicating the presence of fermenting organisms; at 10, 40, and 70 °C no methane production was observed. It could be shown that redox processes in an aquifer generally can adapt to temperatures significantly higher than in situ temperature and that the efficiency of the reduction process can be enhanced by temperature increase to a certain limit. Enhancement of sulphate reduction in an aquifer due to temperature increase could also allow enhanced degradation of organic ground water contaminants such as BTEX, where sulphate is an important electron acceptor.     

Full waveform inversion in the time lapse mode applied to CO2 storage at Sleipner

Carbon capture and storage is a viable greenhouse gas mitigation technology and the Sleipner CO₂ sequestration site in the North Sea is an excellent example. Storage of CO₂ at the Sleipner site requires monitoring over large areas, which can successfully be accomplished with time lapse seismic imaging. One of the main goals of CO₂ storage monitoring is to be able to estimate the volume of the stored CO₂ in the reservoir. This requires a parametrization of the subsurface as exact as possible. Here we use elastic 2D time‐domain full waveform inversion in a time lapse manner to obtain a P‐wave velocity constrain directly in the depth domain for a base line survey in 1994 and two post‐injection surveys in 1999 and 2006. By relating velocity change to free CO₂ saturation, using a rock physics model, we find that at the considered location the aquifer may have been fully saturated in some places in 1999 and 2006.     

The influence of housing oversupply on residential segregation: exploring the post-socialist city of Leipzig†

In this article, we contribute to a better understanding of contextual differences related to residential segregation. We illuminate one specific contextual factor—housing oversupply—and how it intersects with historically inherited patterns of socio-spatial differentiation and other drivers of residential segregation. The study is based on an analysis of how segregation has developed over the last 20 years in the city of Leipzig, Germany. This case offers the rare possibility of studying the impact of city-wide housing oversupply on residential segregation, rather than concentrating on decline or decay in specific areas. We examine how oversupply emerged at the meeting point of changes in market structures, housing preferences, welfare state interventions, and migration trends in the post-socialist transition. Using existing statistical data, we demonstrate how oversupply has fostered a fast and thorough reshuffling of residential patterns. After a period of resolving segregation patterns from the socialist era, oversupply acts as a catalyst for recently emerging residential segregation patterns.