用β—γ1.46Mev测定含钾样中的铀

在β-γ综合测铀基础上,用大晶体、大道宽,突出~(40)K的11.46MeVγ贡献,使钾的铀当量趋近零值,可以实现含钾样中铀的准确测定。     

钛基柱撑累托石矿物材料的研究

在氮气环境中用TiCI4和HCI制成钛基柱撑液，采用离子交换法，用[Ti20O32(OH)12(OH2)18]^4 Dawson型Ti多核阳离子，交换累托石蒙皂石质晶层中的Na等阳离子，制成钛基柱撑累托石。通过电子探针定量分析、X射线衍射、红外光谱、热分析及魔角旋转核磁共振等方法，对钛基柱撑累托石的成分、结构和热稳定性进行了表征。钛基柱撑累托石具1．6nm的层孔隙，是一种很有应用前途的柱撑粘土矿物材料，有望在催化剂载体及环保材料领域中得到广泛的使用。     

桂中都安-马山煌斑岩成因及其构造意义

为精确厘定桂中地区都安-马山带煌斑岩的形成时代并探讨其源区属性、构造环境及其动力学背景,对其进行了LA?ICP?MS锆石U?Pb定年、40Ar?39Ar金云母定年、Hf同位素分析测试和全岩地球化学研究.结果表明,锆石U?Pb定年未能成功限定煌斑岩的成岩年龄,但煌斑岩中发育大量2578～1650 Ma的捕获锆石,指示其存...     

基于欧拉反褶积法的无人机航磁找矿应用

无人机航磁测量以其高效、安全、低成本等优点逐渐应用到中小面积大比例尺资源勘探领域。本文针对安徽芜湖市三山区22 km²区域构造刻画和找矿前景预测,开展1∶20 000高精度无人机航磁测量工作;推导了欧拉反演求解过程,并分析对比构造指数选取,使用构造指数为0的欧拉反褶积对航磁数据进行反演求解,获得地下磁异常体构造边界解集信息;将其应用到研究区域航磁数据反演,根据反演得到的边界位置和深度信息圈定了18处断裂,并结合异常特征给出了8.7 km²岩浆岩分布区,根据宁芜区域铁矿成矿特点,圈定岩浆分布区及边界为成矿详查区。     

黑龙江省浅覆盖区地物化特征与找矿标志——以黑河市340高地金矿化区为例

黑龙江省黑河市340高地金矿点大地构造上位于兴安地块东北缘,多宝山Cu-Au-Mo-W-Fe成矿亚带内,其地貌为浅覆盖区,找矿较为困难。本文采用浅钻技术取样,对研究区进行基岩填图,圈定出以硅化为中心、青磐岩化为外围的蚀变矿化带。对基岩样品进行岩石地球化学分析,通过主成分分析,确定有6个主成分特征值大于1,其中第二主成分与金元素关系密切,是研究区有效的找矿标志。高精度磁测结果显示区内构造以NNW向为主,且其线性低值异常或与蚀变引起的退磁有关。对区内的地物化异常进行工程查证,发现金矿点1处,圈定预测靶区1处。     

基于新测年资料的蓟县运动和燕山早期运动表现探讨:以深圳西部地区及东部大鹏半岛国家地质公园地区为例

近3年来在深圳西部及东部大鹏半岛国家地质公园等地,笔者等参加了地质路线调查研究和取样工作,先后采集了20组岩石同位素定年样品,采用新方法锆石U-Pb定年激光测试法测试,其中获得7个数据集中在1 007～897 Ma,首次发现中-新元古代蓟县纪-青白口纪,并基本可以证实蓟县运动(1 400～1 000 Ma)的存在;对中...     

Chemical and Strontium Isotopic Compositions of the Hanjiang Basin Rivers in China: Anthropogenic Impacts and Chemical Weathering

The Hanjiang River, the largest tributaries of the Changjiang (Yangtze) River, is the water source area of the Middle Route of China’s South-to-North Water Transfer Project. The chemical and strontium isotopic compositions of the river waters are determined with the main purpose of understanding the contribution of chemical weathering processes and anthropogenic inputs on river solutes, as well as the associated CO₂ consumption in the carbonate-dominated basin. The major ion compositions of the Hanjiang River waters are characterized by the dominance of Ca²⁺ and HCO₃ ⁻, followed by Mg²⁺ and SO₄ ²⁻. The increase in TDS and major anions (Cl⁻, NO₃ ⁻, and SO₄ ²⁻) concentrations from upstream to downstream is ascribed to both extensive influences from agriculture and domestic activities over the Hanjiang basin. The chemical and Sr isotopic analyses indicate that three major weathering sources (dolomite, limestone, and silicates) contribute to the total dissolved loads. The contributions of the different end-members to the dissolved load are calculated with the mass balance approach. The calculated results show that the dissolved load is dominated by carbonates weathering, the contribution of which accounts for about 79.4% for the Hanjiang River. The silicate weathering and anthropogenic contributions are approximately 12.3 and 6.87%, respectively. The total TDS fluxes from chemical weathering calculated for the water source area (the upper Hanjiang basin) and the whole Hanjiang basin are approximately 3.8 × 10⁶ and 6.1 × 10⁶ ton/year, respectively. The total chemical weathering (carbonate and silicate) rate for the Hanjiang basin is approximately 38.5 ton/km²/year or 18.6 mm/k year, which is higher than global mean values. The fluxes of CO₂ consumption by carbonate and silicate weathering are estimated to be 56.4 × 10⁹ and 12.9 × 10⁹ mol/year, respectively.     

Siderite dissolution in the presence of chromate

Siderite (FeCO₃) is an important reduced phase iron mineral and end product of bacteria anaerobic respiration. This study addresses its dissolution behavior in the presence of the oxidant chromate, which is a common environmental contaminant. Macroscopic dissolution experiments combined with microscopic observations by atomic force microscopy show that at pH < 4.5 the dissolution rate with chromate is slower than that in control solution without chromate. Isolated deep dissolution pits and clustered shallow pits occur simultaneously with surface precipitation. The implication is that the surface precipitate inhibits further dissolution. For 5 < pH < 9.5, the slowest dissolution and the fastest precipitation rates are observed, both at edge steps and on terraces. For pH > 10, the dissolution rate in the presence of chromate exceeds that of the control, plausibly due to electron transfer facilitated by [Fe³⁺(OH)₄]^-. Dissolution and re-precipitation of round hillocks are observed. X-ray photoelectron spectroscopy indicates the presence of Cr(III) as well as reaction products in a hydroxide form. Based on the redox reaction mechanism, macroscopic dissolution behavior, and previous studies on the reaction products of Fe(II) with Cr(VI), we propose the formation of a low solubility nano-sized Cr(III)-Fe(III)-hydroxide as the surface precipitate. Results from this study provide a basis for understanding and quantifying the interactions between reduced-iron minerals and aqueous-phase oxidants.     

论株洲—湘潭地区的新构造运动

通过对广泛存在于株洲一湘潭地区的新构造的野外调查,依据获取的新构造变形,地貌、水系,现代沉积物等大量实际资料,划分了八个新构造次级单元——构造亚块体及五个新构造活动带。构造亚块体有五次较明显的由早到晚幅度递减的间歇性抬升,新构造活动带变形强度与基底断裂规模成正比,同位素测年获其主要构造变形时间为3.9—5.5万年。     

Adsorption of rare earth elements onto Carrizo sand: Experimental investigations and modeling with surface complexation

Rare earth element (REE) adsorption onto sand from a well characterized aquifer, the Carrizo Sand aquifer of Texas, has been investigated in the laboratory using a batch method. The aim was to improve our understanding of REE adsorption behavior across the REE series and to develop a surface complexation model for the REEs, which can be applied to real aquifer-groundwater systems. Our batch experiments show that REE adsorption onto Carrizo sand increases with increasing atomic number across the REE series. For each REE, adsorption increases with increasing pH, such that when pH >6.0, >98% of each REE is adsorbed onto Carrizo sand for all experimental solutions, including when actual groundwaters from the Carrizo Sand aquifer are used in the experiments. Rare earth element adsorption was not sensitive to ionic strength and total initial REE concentrations in our batch experiments. It is possible that the differences in experimental ionic strength conditions (i.e., 0.002-0.01 M NaCl) chosen were insufficient to affect REE adsorption behavior. However, cation competition (e.g., Ca, Mg, and Zn) did affect REE adsorption onto Carrizo sand, especially for light rare earth elements (LREEs) at low pH. Rare earth element adsorption onto Carrizo sand can be successfully modeled using a generalized two-layer surface complexation model. Our model calculations suggest that REE complexation with strong surface sites of Carrizo sand exceeds the stability of the aqueous complexes LnOH²⁺, LnSO₄⁺, and LnCO₃⁺, but not that of Ln(CO₃)₂^- or LnPO₄^o in Carrizo groundwaters. Thus, at low pH (<7.3), where major inorganic ligands did not effectively compete with surface sites for dissolved REEs, free metal ion (Ln³⁺) adsorption was sufficient to describe REE adsorption behavior. However, at higher pH (>7.3) where solution complexation of the dissolved REEs was strong, REEs were adsorbed not only as free metal ion (Ln³⁺) but also as aqueous complexes (e.g., as Ln(CO₃)₂^- in Carrizo groundwaters). Because heavy rare earth elements (HREEs) were preferentially adsorbed onto Carrizo sand compared to LREEs, original HREE-enriched fractionation patterns in Carrizo groundwaters from the recharge area flattened along the groundwater flow path in the Carrizo Sand aquifer due to adsorption of free- and solution-complexed REEs.