Petroleum composition in the Cuu Long Basin (Mekong Basin) offshore southern Vietnam

The Cuu Long Basin (Mekong Basin) is a rift basin off southern Vietnam, and the most important petroleum producing basin in the country. However, information on petroleum type and characteristics has hitherto been largely unavailable to the public. This paper presents petroleum geochemical data on nine oil samples from four different producing fields in the Cuu Long Basin: the Dragon (Rong), Black Lion (Sutu-Den), Sunrise (Rang ?ong) and White Tiger (Bach Ho) Fields. The oils are highly paraffinic with bimodal normal alkane distributions and show moderate pristane to phytane ratios and a conspicuous hyperbolic decrease in abundance with increasing carbon number of hopane homologues from C₃₀ to C₃₅. The TPP-index of Holba et al. (Holba, A.G., Dzou, L.I., Wood, G.D., Ellis, L., Adam, P., Schaeffer, P., Albrecht, P., Greene, T., Hughes, W.B., 2003. Application of tetracyclic polyprenoids as indicators of input from fresh–brackish water environments. Organic Geochemistry 34, 441–469) is equal to 1 in all samples which in combination with tricyclic triperpane T26/T25 ratios >1 and the n-alkane and hopane distributions mentioned above provide a strong indication of an origin from lacustrine source rocks. This is supported by the absence of marine C₃₀ desmethyl steranes (i.e. 24-n-propylcholestanes) and marine diatom-derived norcholestanes. Based on the overall biological marker distributions, the lakes probably belonged to the overfilled or balanced-fill types defined by Bohacs et al. (Bohacs, K.M., Carroll, A.R., Neal, J.E., Mankiewicz, P.J., 2000. Lake-basin type, source potential, and hydrocarbon character. An integrated sequence-stratigraphic–geochemical framework. AAPG Studies in Geology 46, 3–34). The oils were generated from source rocks at early- to mid-oil-window maturity, presumably Oligocene lacustrine shales that are present in the syn-rift succession. Oils from individual fields may, however, be distinguished by a combination of biological marker parameters, such as the oleanane index, the gammacerane index, the relative abundance of tricyclic terpanes, the proportions of diasteranes and 28-norspergulane, complemented by other parameters. The oils of the Cuu Long Basin show an overall similarity to the B-10 oil from the Song Hong Basin off northern Vietnam, but are markedly different from the seepage oils known from Dam Thi Nai on the coast of central Vietnam.     

Mining spatial associations between daily activities and health using EMA–GPS data

The geographical explicit ecological momentary assessment (GEMA) data collection platform provides extremely rich geospatial datasets and is very promising to gain behavior insights linking mobility, activities, and health. However, the task of analyzing these large datasets effectively is not straightforward, because they often involve a large multivariable dimension and rich qualitative data formats. Responding to the call for innovative analytic approaches in GIScience, this article advocates the use of spatial association rule mining (SARM) to extract frequent associations among daily activities, daily mobility, and health, including both physical health (e.g. pain) and mental health (e.g. happiness). This inductive mining approach works robustly with large datasets and is suitable for both qualitative and quantitative studies. A novel visualization technique to analyze the mined rules is also developed and presented.     

Search for H2 Emission from Disks around T Tauri and Herbig AE Stars

Preliminary results are presented of observations of the pure rotational lines of H2 toward T Tauri and Herbig Ae stars using the Short Wavelength Spectrometer (SWS) on the Infrared Space Observatory (ISO). The sources are selected to be isolated low- and intermediate-mass young stellar objects, for which the presence of a circumstellar disk has been established by millimeter interferometry. The lowest H2 S(0) and S(1) lines are detected in 3 out of 5 objects. The measured intensities indicate ∼ 0.01 M⊙ of warm (T ≈ 150 K) gas in the ISO beam. It is argued that for at least one case (HD 163296), the emission is probably dominated by the warm gas in the circumstellar disk rather than by shocked- or photon-heated gas in the surrounding envelope. Such observations can provide important constraints on the radial and vertical temperature profiles in circumstellar disks. This revised version was published online in August 2006 with corrections to the Cover Date.     

Organohalogen contaminants and trace metals in North-East Atlantic porbeagle shark (Lamna nasus)

The North-East Atlantic porbeagle (Lamna nasus) population has declined dramatically over the last few decades and is currently classified as ‘Critically Endangered’. As long-lived, apex predators, they may be vulnerable to bioaccumulation of contaminants. In this study organohalogen compounds and trace elements were analysed in 12 specimens caught as incidental bycatch in commercial gillnet fisheries in the Celtic Sea in 2011. Levels of organohalogen contaminants were low or undetectable (summed CB and BDE concentrations 0.04–0.85 mg kg⁻¹ wet weight). A notably high Cd concentration (7.2 mg kg⁻¹ wet weight) was observed in one mature male, whereas the range observed in the other samples was much lower (0.04–0.26 mg kg⁻¹ wet weight). Hg and Pb concentrations were detected only in single animals, at 0.34 and 0.08 mg kg⁻¹ wet weight, respectively. These contaminant levels were low in comparison to other published studies for shark species.     

Population of the Scattered Kuiper Belt

We study how the internal structure of dark halos is affected if cold dark matter particles are assumed to have a large cross section for elastic collisions. We identify a cluster halo in a large cosmological N-body simulation and resimulate its formation with progressively increasing resolution. We compare the structure found in the two cases in which dark matter is treated as collisionless or as a fluid. For the collisionless case, the overall ellipticity of the cluster, the central density cusp, and the amount of surviving substructure are all similar to those found in earlier high-resolution simulations. Collisional dark matter results in a cluster that is more nearly spherical at all radii, has a steeper central density cusp, and has less-but still substantial-surviving substructure. As in the collisionless case, these results for a "fluid" cluster halo are expected to carry over approximately to smaller mass systems. The observed rotation curves of dwarf galaxies then argue that self-interacting dark matter can only be viable if intermediate cross sections produce structure that does not lie between the extremes we have simulated.     

MAXIPOL: a balloon-borne experiment for measuring the polarization anisotropy of the cosmic microwave background radiation

We discuss MAXIPOL, a bolometric balloon-borne experiment designed to measure the E-mode polarization anisotropy of the cosmic microwave background radiation (CMB) on angular scales of 10^′ to 2°. MAXIPOL is the first CMB experiment to collect data with a polarimeter that utilizes a rotating half-wave plate and fixed wire-grid polarizer. We present the instrument design, elaborate on the polarimeter strategy and show the instrument performance during flight with some time domain data. Our primary dataset was collected during a 26 h turnaround flight that was launched from the National Scientific Ballooning Facility in Ft. Sumner, New Mexico in May 2003. During this flight five regions of the sky were mapped. Data analysis is in progress.     

Simulation of Titan haze formation using a photochemical flow reactor: The optical constants of the polymer

Solar UV is the principal energy source impinging the atmosphere of Titan while the energy from the electrons in Saturn's magnetosphere is less than 0.5% of the UV light. Titan haze analogs were prepared by the photolysis of a mixture of gases that simulate the composition of its atmosphere (nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene). The real (n) and imaginary (k) parts of the complex refractive index of haze analogs formed from four different gas mixtures were calculated from the spectral properties of the solid polymer in UV-visible, near infrared and infrared wavelength spectral regions. The value of n was constant at 1.6±0.1 throughout the 0.2-2.5 μm region. The variation of k with wavelength for the values derived for Titan has a lower error than the absolute values of k so the more significant comparisons are with the slopes of the k(λ) plots in the UV-VIS region. Three of the photochemical Titan haze analogs had slopes comparable to those derived for Titan from the Voyager data (Rages and Pollack, 1980, Icarus 41, 119-130; McKay and Toon, 1992, in: Proceedings of the Symposium on Titan, in: ESA SP, Vol. 338, pp. 185-190). The slopes of the k(λ) plots for haze analogs prepared by spark discharge (Khare et al., 1984, Icarus 60, 127-137) and plasma discharge (Ramirez et al., 2002, Icarus 156, 515-529) were also comparable to Titan's. These finding show that the k(λ) plots do not differentiate between different laboratory simulations of atmospheric chemistry on Titan in the UV-VIS near IR region (0.2-2.5 microns). There is a large difference between the k(λ) in the infrared between the haze analogs prepared photochemically and analogs prepared using a plasma discharges (Khare et al., 1984, Icarus 60, 127-137; Coll et al., 1999, Planet. Space Sci. 47, 1331-1340; Khare et al., 2002, Icarus 160, 172-182). The C/N ratio in the haze analog prepared by discharges is in the 2-11 range while that of the photochemical analogs is in the 18-24 range. The use of discharges and UV light for initiating the chemistry in Titan's atmosphere is discussed.     

Effects of riverbed incision on the hydrology of the Vietnamese Mekong Delta

The hydrogeomorphology of the Vietnamese Mekong Delta (VMD) has been significantly altered by natural and anthropogenic drivers. In this study, the spatiotemporal changes of the flow regime were examined by analysing the long-term daily, monthly, annual and extreme discharges and water levels from 1980 to 2018, supported by further investigation of the long-term annual sediment load (from the 1960s to 2015), river bathymetric data (in 1998, 2014 and 2017) and daily salinity concentration (from the 1990s to 2015) using various statistical methods and a coupled numerical model. Then, the effects of riverbed incision on the hydrology were investigated. The results show that the dry season discharge (i.e., in March–June) of the Tien River increased by up to 23% from the predam period (1980–1992) to the postdam period (1993–2018) but that the dry season water level at My Thuan decreased by up to −46%. The annual mean and monthly water levels in June at Tan Chau and in January and June–October at My Thuan in the Tien River decreased statistically, even though the respective discharges increased significantly. These decreased water levels instead of the increased discharges were attributed to the accelerated riverbed incision upstream from My Thuan, which increased by more than three times, from a mean rate of −0.16 m/year (−16.7 Mm³/year) in 1998–2014 to −0.5 m/year (−52.5 Mm³/year) in 2014–2017. This accelerated riverbed incision was likely caused by the reduction in the sediment load of the VMD (from 166.7 Mt/year in the predam period to 57.6 Mt/year in the postdam period) and increase in sand mining (from 3.9 Mm³ in 2012 to 13.43 Mm³ in 2018). Collectively, the decreased dry season water level in the Tien River is likely one of the main causes of the enhanced salinity intrusion.     

Synchronous Transformations of Mineral and Organic Constituents of Sedimentary Rocks in Geological Structure with an Initial Extension and Subsequent Compression Tectonic Regime

Sedimentary rocks of the section in the Red River fold zone of northern Viet Nam are considered. It is shown that secondary mineral parageneses formed in two stages. The first stage (35–17 Ma ago) corresponded to the period of structure extension and sediment subsidence to a depth of about 6 km. This period and subsequent 10 Ma were marked by the formation of a usual dia- and catagenetic zoning of metasedimentary rocks. The second stage (5–7 Ma ago) corresponded to processes of compression that were responsible for the deformation of rocks into gentle folds and 1.5 to 2.2 times contraction of the section thickness in different places. The sequential–mineralogical zoning was disturbed at this stage. Smectites and mixed-layer minerals were replaced by chlorites and hydromicas. Organic material also responded to compression simultaneously with inorganic components. The bituminous component was released from humic matter and rocks became enriched in hydrocarbons.     

Petrology of the tin-bearing granite-leucogranites of the Piaoak Massif, Northern Vietnam

The Piaoak tin-bearing granite-leucogranites located in the Caobang Province of Northern Vietnam compose a stock-like hypabyssal body. Host rocks are represented by Early Devonian carbonate sequences and Early Triassic ??black?? shales. The geochronological age of the Piaoak granite-leucogranites corresponds to the Late Cretaceous: T = 83.5 ± 6.2 Ma, ⁸⁷Rb/⁸⁶Sr method; T = 89.7 ± 1.0 Ma, ³⁹Ar/⁴⁰Ar method. The massif has a simple basic to acid order: two-mica and muscovite granite-leucogranite ?? raremetal aplites, pegmatites ?? tin-bearing greisens and hydrothermal veins. The petrographic and microstructural studies revealed a sharp change in crystallization conditions of the granite-leucogranite magma at the late magmatic stage and formation of muscovite via incongruent melting of protolithionite. The study of melt and coexisting fluid inclusions showed that solidus crystallization occurred under fluid-saturated conditions at 635?C600°C. In composition, the granite-leucogranites of the Piaoak Massif correspond to the raremetal-plumasite geochemical type (according to L.V. Tauson), and reach Li-F facies in terms of their rare-element composition. The composition of aplites and pegmatites demonstrates that granite-leucogranite magma did not accumulate lithophile and volatile components in the residual melt during differentiation, but was initially enriched in rare-metals. It is most probable that the melt was generated from Proterozoic lithotectonic complexes and overlaying Lower Triassic ??black?? shales.