The ichnology of carbonate drifts

Carbonate drifts have so far not been as intensely investigated as their siliciclastic equivalents, especially from an ichnological perspective. The aim of this work is therefore to provide an overview of the different bioturbation styles in carbonate drifts for ichnologists and sedimentologists working in such deposits. Different types of carbonate drifts from the Maldives were studied to address this objective. The cores recovered during International Ocean Discovery Program Expedition 359 were examined to provide the sedimentological and ichnological data for a detailed analysis of the ichnology of carbonate drifts. The ichnological characteristics of the Maldives drifts are compared to other carbonate drifts in order to discuss similarities and differences, and thus provide an overview of the general characteristics of carbonate drift ichnology. These drifts are located in the Santaren Channel which lines Great Bahama Bank, along the Marion Plateau in Australia, in the Limassol and Larnaca basins in Cyprus and in the Danish Basin in Denmark. The common characteristics of bioturbation in carbonate drifts are: (i) the complete bioturbation of the sediment with bioturbation indexes between four and six; (ii) the occurrence of distinctive trace fossils limited to facies contacts or condensed intervals; (iii) a typical ichnoassemblage consisting of Thalassinoides, Scolicia, Planolites, Zoophycos, Chondrites, Phycosiphon and Palaeophycus; (iv) the contiguous occurrence of ichnogenera from different tiers, with only Zoophycos and Chondrites as deep tiers; and (v) distinct infills of the traces including particulate organic matter, pyrite, silica and celestine. In addition, the main ichnofacies of carbonate drifts is the Zoophycos ichnofacies. Ichnofabrics grade from coarse‐grained and completely bioturbated to ichnofabrics with present to rare trace fossils and preserved sedimentary structures. The type and intensity of the bioturbation is controlled by the amount of organic matter and the oxygenation at the sea floor that is determined by the action of bottom currents and the sea‐level fluctuations affecting the carbonate factory in carbonate platforms bordering the basins where the carbonate drifts form. The study of the bioturbation in core and outcrop provides palaeoenvironmental information about carbonate‐drift deposits that complement the classical sedimentological data.     

Tidal river sediments in the Washington,D.C. area. III. Biological effects associated with sediment contamination

Sediment toxicity and benthic macroinvertebrate community structure were measured as one component of a study cohceived to determine the distribution and effect of sediment contamination in tidal freshwater portions of the Potomac and Anacostia rivers in the Washington, D.C., area. Samples were collected at 15 sites. Analyses included a partial life cycle (28 d) whole sediment test using the amphipod Hyalella azteca (Talitridae) and an assessment of benthic community structure. Survival and growth (as estimated by amphipod length) were experimental endopoints for the toxicity test. Significant mortality was observed in 5 of 10 sites in the lower Anacostia River basin and at the main channel Potomac River site. Sublethal toxicity, as measured by inhibition of amphipod growth, was not observed. Toxicity test results were in general agreement with synoptically measured sediment contaminant concentrations. Porewater total ammonia (NH₃+NH₄ ⁺) appears to be responsible for the toxicity of sediments from the Potomac River, while correlation analysis and simultaneously extracted metals: acid volatile sulfide (SEM∶AVS) results suggest that the toxicity associated with Anacostia River sediments was due to organic compounds. Twenty-eight macroinvertebrate taxa were identified among all sites, with richness varying from 5 to 17 taxa per site. Groups of benthic assemblages identified by group-average cluster analysis exhibited variable agreement with sediment chemical and sediment toxicity results. Integration of toxicological, chemical, and ecological components suggests that adverse environmental effects manifest in the lower Anacostia River benthos result from chemical contamination of sediment.     

U-Pb dating of an early paleozoic bimodal magmatism in the french Massif Central and of its further metamorphic evolution

In the Marvejols area (Southern french Massif Central), the gneissic Marvejols supergroup is overthrust on the metasedimentary “Série du Lot”, deposited in part prior to 540 Ma. The allochtonous terranes are characterized by the occurrence of a leptyno-amphibolitic group, a complex association of mafic and felsic rocks of igneous and sedimentary derivation. A 480±10 Ma age has been obtained by U-Pb dating of zircons, for the crystallization of both mafic and felsic meta-igneous rocks. These rocks were emplaced during an important extensional tectonics. Relics of eclogites, pyrigarnites, coronite gabbros and HP-trondhjemites are clear evidence for a further HP-HT event dated at 415±6 Ma on zircons from a HP trondhjemite. Subsequently, the Marvejols supergroup underwent an amphibolite facies metamorphism with incipient mobilization dated at 345±10 Ma. Rifting and thinning of the continental crust in Cambro-Ordovician times appears to be a major geodynamic feature which could account for the thermal events often referred to the “Caledonian” orogeny. The Silurian (415 Ma) age of the HP episode is clearly older than the main Variscan tectonometamorphic event; it is in agreement with Rb-Sr dating of the Moldanubian granulites and with some radiometric data from Southern Brittany (France). These results point to a compressive phase, probably in a subduction context, in view of the high pressures reached (15–20 Kb), after the Cambro-Ordovician distensive phase. The main final tectono-metamorphic paroxysm (blocking of subduction process and continental collison ?) is not prior to the end of Devonian (340–350 Ma) and is related to the Variscan orogeny s.s     

An Overview of Dissolved and Suspended Matter Fluxes in the Loire River Basin: Natural and Anthropogenic Inputs

The spatial and temporal distributions of major elements were investigated in the surface waters and in associated suspended matter at two sites of the upper Loire basin (Orleans and Brehemont) between 1995 and 1998.According to geochemical and isotopic patterns, the dissolved load appears to result from a process of mixing rainwater inputs, weathering processes of carbonate and silicate bedrock, and agricultural and urban inputs. Natural inputs influence 60% of water chemical composition at both sites. Annual dissolved fluxes were estimated to be 1300 10³ t/y at Orleans and 1620 10³ t/y at Brehemont. Major elements are transported mainly in the dissolved fraction. After correcting for atmospheric and anthropogenic inputs, the silicate specific export rate was calculated to be 11 t/y/km² throughout the basin and the carbonate specific export rate to be from 47 t/y/km² at Orleans to 23 t/y/km² at Brehemont.The suspended load appears to result from at least two particle reservoirs: a silicate reservoir and a carbonate reservoir. The silicate reservoir has a detrital origin, mainly during periods of high flow, while the carbonate reservoir has a detrital origin during periods of high flow and an authigenic origin during periods of low flow. Of the total annual flow of suspended matter, this authigenic material represents 16% at Orleans, 25% at Brehemont and 37% in the fluvial part of the estuary. After correcting authigenic inputs, the specific export rate due to mechanical weathering was estimated to be 8 t/y/km² throughout the Loire basin.     

Paläoklimatische Information im Isotopengehalt14C-datierter Saharawässer: Kontinentaleffekt in D und18O

Zusammenfassung In den¹⁴C-Altern der Saharawässer spiegelt sich die wechselnde Abfolge von Feucht- und Trockenphasen während des späten Pleistozäns und Holozäns wider. Außerdem zeigt sich ein West-Ost-Gefälle in ihrem D- und¹⁸O-Gehalt, das als Kontinentaleffekt im Grundwasser gedeutet wird. Dieser Kontinentaleffekt setzt voraus, daß das nordafrikanische Klimageschehen vergangener Feuchtphasen von der Westdrift bestimmt wurde, die regenbringende atlantische Luftmassen weit ins Saharainnere getrieben hat. Ein einfaches mathematisches Modell, das den Kontinentaleffekt durch eine Rayleigh-Kondensation beschreibt, ergibt die beste Anpassung an die Meßwerte, wenn für die Sahara (ähnlich wie heute in Europa) ein West-Ost-Gefälle in den Paläo-Winterniederschlagsmengen von –30% pro 1000 km angenommen wird. Unter der Annahme ehemaliger Winterniederschläge (Sept.-März) von 600 mm (entspricht Lissabon heute) für das Gebiet an der nordafrikanischen Atlantikküste ergibt diese Modellrechnung z. B. 250 mm für die Paläo-Winterniederschläge im Gebiet des Murzuk-Beckens.

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The¹⁴C-age distribution of Saharian groundwaters shows the alternating sequence of humid and arid periods in the late Pleistocene and Holocene. The observed west-east decrease of the D- and¹⁸O-content of the Sahara waters is interpreted to be the Continental Effect in rain and groundwater. The paleoclimatic situation during ground-water formation therefore was controlled by the western drift carrying wet Atlantic air masses across the Sahara. The best fit of a simple Rayleigh condensation model of the continental effect to the experimental data is obtained with a west-east decrease of the Saharian paleo-winter precipitation of –30% per 1000 km (similar to the one in Europe today). With an annual winter precipitation rate (Sept.-March) of 600 mm (corresponding to the one of Lisboa today) for the Northafrican coastal area at the Atlantic Ocean a previous winter precipitation rate of 250 mm is obtained for the Murzuq Basin.

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Résumé Une succession de périodes humides et arides à la fin du Pléistocène et à l'Holocène se réflète dans la distribution des âges¹⁴C d'eaux souterraines du Sahara. Les teneurs en D et¹⁸O diminuent d'Ouest en Est, ce qui est interprété comme un effet continental dans l'eau souterraine. Celui-ci signifie que la climatologie des phases pluviales passées, dans l'Afrique du Nord, était déterminée par des vents d'Ouest qui apportaient des masses d'air atlantique humide à l'intérieur du Sahara. Un modèle mathématique simple décrivant l'effet continental par une condensation du type Rayleigh, reproduit avec la meilleure conformité les valeurs expérimentales, pour autant qu'on admette que les pluies hivernales au Sahara diminuaient anciennement d'Ouest en Est de 30% par 1000 km (comme à présent en Europe). En supposant qu'autrefois la quantité de pluie hivernale, de septembre à mars à la côte atlantique de l'Afrique du Nord était de 600 mm (comme aujourd'hui à Lisbonne), on obtient à l'aide de ce modèle une précipitation hivernale ancienne de 250 mm dans le bassin du Mourzouk.

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, ¹⁴C, . , ¹⁸O, , . , , , , . , Rayleigh, — , — — 30 % 1000 . , - , . . , 600 , — —, 250 .

     

Sulfide and platinum mineralization in the Merensky Reef: evidence from hydrous silicates and fluid inclusions

The base metal sulfides of the Merensky Reef are associated with hydrous silicates and intense deuteric hydrous alteration of cumulus and postcumulus silicates. Biotite and phlogopite crystallized in the vicinity of sulfides from a volatile-enriched highly fractionated intercumulus melt. Amphibole, chlorite, and talc are later alteration phases of cumulus pyroxene and intercumulus plagioclase. Biotite is often accompanied by zircon, rutile, and quartz. Accessory quartz hosts a complex suite of H₂O-NaCl-(CaCl₂)-CO₂-CH₄ fluid inclusions which have thus far not been described from the Merensky Reef. The earliest fluid inclusion compositions are NaCl-(H₂O) with less than 10 vol.% water; CO₂ coexisting with a halite daughter crystal and brine; and polyphase inclusions with up to six daughter and accidental phases and high contents of divalent cations. The maximum trapping temperature is around 730° C at 4 to 5 kb pressure. Later inclusion generations are H₂O-NaCl, CO₂-H₂O, and pure CO₂ and CH₄. The presence of Cl-rich fluids during the intercumulus stage of the crystallizing Merensky Reef is directly related to the mode of sulfide precipitation. Prior to sulfide unmixing in a hydrous magma sulfur is likely to be present as H₂S. Sulfur saturation causes reaction of H₂S with oxides of the silicate melt to form a sulfide melt plus water. During reaction the magma is enriched in water until a separate fluid unmixes. It carries all compounds with high fluid/melt partition coefficients, as well as metals capable of forming OH- and Cl-complexes. Precious metals are assumed to have fractionated into the Cl-rich fluid as Cl-complexes rather than being dissolved in the sulfide melt. During the cooling evolution of the fluid the precious elements precipitate around the periphery of sulfide melt droplets. The model proposed explains the distribution pattern of platinum-group minerals in the Merensky Reef better than any orthomagmatic mineralization concept offered so far.     

Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.     

Can a Training Image Be a Substitute for a Random Field Model?

In most multiple-point simulation algorithms, all statistical features are provided by one or several training images (TI) that serve as a substitute for a random field model. However, because in practice the TI is always of finite size, the stochastic nature of multiple-point simulation is questionable. This issue is addressed by considering the case of a sequential simulation algorithm applied to a binary TI that is a genuine realization of an underlying random field. At each step, the algorithm uses templates containing the current target point as well as all previously simulated points. The simulation is validated by checking that all statistical features of the random field (supported by the simulation domain) are retrieved as an average over a large number of outcomes. The results are as follows. It is demonstrated that multiple-point simulation performs well whenever the TI is a complete (infinitely large) realization of a stationary, ergodic random field. As soon as the TI is restricted to a limited domain, the statistical features cannot be obtained exactly, but integral range techniques make it possible to predict how much the TI should be extended to approximate them up to a prespecified precision. Moreover, one can take advantage of extending the TI to reduce the number of disruptions in the execution of the algorithm, which arise when no conditioning template can be found in the TI.