Structure,transport and potential vorticity of the Gulf Stream at 68°W: Revisiting older data sets with new techniques

The stream-coordinates mean structure of the Gulf Stream at 68°W is derived using new methods for both defining stream coordinates and interpreting bottom pressure and inverted echo sounder travel times collected during the extensive Synoptic Ocean Prediction experiment. These new analyses provide pictures of the vertical structure of Gulf Stream flows that are demonstrably dynamically consistent with the density field at all depths, in contrast to previous work that relies on simple vertical interpolations to fill gaps between sparse current meter measurements. This new view of the Gulf Stream suggests a slightly higher total mean transport, with the increases coming from both baroclinic and barotropic components, and slightly stronger recirculation cells, particularly on the southern side. The recirculation of the Gulf Stream appears to have a weak baroclinic component, perhaps 10% of the total. A significant advantage of the methodology is the ability to obtain sensible vertical and horizontal gradients of currents and density so that the vertical and cross-stream structures of the components of the mean potential vorticity can be clearly imaged. One new feature from this calculation is that the along-stream gradient of the cross-stream velocity, a term that is often ignored in potential vorticity analyses, is non-negligible (though small) and is asymmetric about the current axis. Both the derived structure and implied dynamics of the circulation can be significantly altered by small changes to the method of calculating daily stream coordinates, e.g., by carefully filtering out observations in rings or not. Arrays of pressure-equipped inverted echo sounders provide the opportunity (at reasonable cost) for properly defining the stream coordinates of energetic jets such as the Gulf Stream.     

Dissolved sulfides in the oxic water column of San Francisco Bay,California

Trace contaminants enter major estuaries such as San Francisco Bay from a variety of point and nonpoint sources and may then be repartitioned between solid and aqueous phases or altered in chemical speciation. Chemical speciation affects the bioavailability of metals as well as organic ligands to planktonic and benthic organisms, and the partitioning of these solutes between phases. Our previous, work in south San Francisco Bay indicated that sulfide complexation with metals may be of particular importance because of the thermodynamic stability of these complexes. Although the water column of the bay is consistently well-oxygenated and typically unstratified with respect to dissolved oxygen, the kinetics of sulfide oxidation could exert at least transient controls on metal speciation. Our initial data on dissolved sulfides in the main channel of both the northern and southern components of the bay consistently indicate submicromolar concenrations (from <1 nM to 162 nM), as one would expect in an oxidizing environment. However, chemical speciation calculations over the range of observed sulfide concentrations indicate that these trace concentrations in the bay water column can markedly affect chemical speciation of ecologically significant trace metals such as cadmium, copper, and zinc.     

On the speciation of metals in the water column of a polluted estuary

The dissolved (<0.40 γm) fraction of water samples from Newark Bay, New Jersey was analysed for Zn, Cu and Pb content by differential pulse anodic stripping polarographic techniques. In the dissolved fraction, non-labile forms of Zn, Cu and Pb exist as shown by differential pulse anodic stripping voltammetry analysis on acidified samples and acidified-UV irradiated samples. The particulate fraction (>;0.40 μm) contains metals in the form of sulphides (Fe, Zn, Cu, Mn), oxides and oxyhydroxides (Si, Al, Fe, Cu, Ni, Sn), phosphate (Ca, Ce, La), clay minerals (Fe, Zn, Cu, Ti) and carbonaceous material (Fe, Cu, Zn) as demonstrated by X-ray microanalysis. The solid phases are likely present in colloidal form in the dissolved fraction of the water column as well. The forms of the metals in the water column are partially due to the resuspension of bottom sediments by dredging and natural processes, to sewage outfall and to natural geochemical processes.     

Studies on the Behaviour of Water-endangering Substances in Plants for the Biological Cleaning of Municipal Waste Waters. Part 1: Bromoxynil

The behaviour of the herbicide bromoxynil (3,5-dibromo-4-hydroxybenzonitrile), labelled with ⁸²Br, is investigated in an activated sludge plant on the laboratory scale with municipal wastewater. Only 5% of bromoxynil present in a concentration of 5 mg/l are degraded after preadaption of activated sludge for some weeks. The known hydrolysis products 3,5-dibromo-4-hydroxybenzamide and 3,5-dibromo-4-hydroxybenzoic acid were identified as degradation products. In addition, 1.9±0.9% of the quantity of ⁸²Br appeared in the solution as Br^? by debromination. Moreover, a pronounced adsorption of the active substance on activated sludge occurs. Its activity amounts to about 130% of the initial activity of the solution.     

Short-term variability of suspended sediment and phytoplankton in Tampa Bay,Florida: Observations from a coastal oceanographic tower and ocean color satellites

We examined short-term phytoplankton and sediment dynamics in Tampa Bay with data collected between 8 December 2004 and 17 January 2005 from optical, oceanographic, and meteorological sensors mounted on a coastal oceanographic tower and from satellite remote sensing. Baseline phytoplankton (chlorophyll-a, Chl) and sediment concentrations (particle backscattering coefficient at 532 nm, bbp(532)) were of the order of 3.7 mg m⁻³ and 0.07 m⁻¹, respectively, during the study period. Both showed large fluctuations dominated by semidiurnal and diurnal frequencies associated with tidal forcing. Three strong wind events (hourly averaged wind speed >8.0 m s⁻¹) generated critical bottom shear stress of >0.2 Pa and suspended bottom sediments that were clearly observed in concurrent MODIS satellite imagery. In addition, strong tidal current or swells could also suspend sediments in the lower Bay. Sediments remained suspended in the water column for 2–3 days after the wind events. Moderate Chl increases were observed after sediment resuspension with a lag time of ˜1–2 days, probably due to release of bottom nutrients and optimal light conditions associated with sediment resuspension and settling. Two large increases in Chl with one Chl > 12.0 mg m⁻³ over ˜2 days, were observed at neap tides. For the study site and period, because of the high temporal variability in phytoplankton and sediment concentrations, a monthly snapshot can be different by −50% to 200% from the monthly “mean” chlorophyll and sediment conditions. The combination of high-frequency observations from automated sensors and synoptic satellite imagery, when available, is an excellent complement to limited field surveys to study and monitor water quality parameters in estuarine environments.     

Editorial

Editorial Introduction

Editorial     

Synoptic volumetric variations and flushing of the Tampa Bay estuary

Two types of analyses are used to investigate the synoptic wind-driven flushing of Tampa Bay in response to the El Niño-Southern Oscillation (ENSO) cycle from 1950 to 2007. Hourly sea level elevations from the St. Petersburg tide gauge, and wind speed and direction from three different sites around Tampa Bay are used for the study. The zonal (u) and meridional (v) wind components are rotated clockwise by 40° to obtain axial and co-axial components according to the layout of the bay. First, we use the subtidal observed water level as a proxy for mean tidal height to estimate the rate of volumetric bay outflow. Second, we use wavelet analysis to bandpass sea level and wind data in the time–frequency domain to isolate the synoptic sea level and surface wind variance. For both analyses the long-term monthly climatology is removed and we focus on the volumetric and wavelet variance anomalies. The overall correlation between the Oceanic Niño Index and volumetric analysis is small due to the seasonal dependence of the ENSO response. The mean monthly climatology between the synoptic wavelet variance of elevation and axial winds are in close agreement. During the winter, El Niño (La Niña) increases (decreases) the synoptic variability, but decreases (increases) it during the summer. The difference in winter El Niño/La Niña wavelet variances is about 20 % of the climatological value, meaning that ENSO can swing the synoptic flushing of the bay by 0.22 bay volumes per month. These changes in circulation associated with synoptic variability have the potential to impact mixing and transport within the bay.