二叠系火山碎屑岩气藏天然气地球化学特征及气源分析——以四川盆地成都—简阳地区永探1井为例

2018年12月底,在四川盆地二叠系火山岩发育地区部署的风险探井永探1井测试获得22.5万m³/d的高产工业气流,实现了二叠系火山碎屑岩的重大勘探突破,展现了火山碎屑岩气藏的巨大勘探潜力。本文根据该钻井成果资料,应用分析化验数据,采用不同地区气-气对比方法,开展了成都—简阳地区天然气地球化学特征分析、源-储接触关系解剖及气源综合对比。在此基础上,对二叠系火山碎屑岩气藏天然气成因进行了鉴别,对天然气来源进行了判识。结果表明：永探1井火山岩气藏天然气均为典型的干气,干燥系数达0.997,CH₄质量分数高,平均为99.03%,C₂H₆质量分数低,平均为0.35%,C₃H₈几乎没有,不含H₂S;天然气甲烷、乙烷碳同位素值均较轻,甲烷碳同位素平均值为-32.17‰,乙烷碳同位素平均值为-34.27‰,且岩心及镜下可见大量残余沥青,天然气成因鉴别分析表明永探1井火山岩气藏天然气为原油二次裂解气;通过源-储接触关系解剖以及天然气甲烷、乙烷碳同位素对比分析,表明永探1井火山碎屑岩气藏天然气主要来源于德阳—安岳台内裂陷内发育的巨厚下寒武统筇竹寺组优质烃源岩,部分来源于中二叠统。     

Geology and geochemistry of the Bingdaban ophiolitic mélange in the boundary fault zone on the northern Central Tianshan Belt,and its tectonic implications

The properties and tectonic significance of the fault bound zone on the northern margin of the Central Tianshan belt are key issues to understand the tectonic framework and evolutionary history of the Tianshan Orogenic Belt. Based on the geological and geochemical studies in the Tianshan orogenic belt, it is suggested that the ophiolitic slices found in the Bingdaban area represent the remaining oceanic crust of the Early Paleozoic ocean between the Hazakstan and Zhungaer blocks. Mainly composed of basalts, gabbros and diabases, the ophiolites were overthrust onto the boundary fault between the Northern Tianshan and Central Tianshan belts. The major element geochemistry is characterized by high TiO₂ (1.50%–2.25%) and MgO (6.64%–9.35%), low K₂O (0.06%–0.41%) and P₂O₅ (0.1%–0.2%), and Na₂O>K₂O as well. Low ΣREE and depletion in LREE indicate that the original magma was derived from a depleted mantle source. Compared with a primitive mantle, the geochemistry of the basalts from the Bingdaban area is featureded by depletion in Th, U, Nb, La, Ce and Pr, and unfractionated in HFS elements. The ratios of Zr/Nb, Nb/La, Hf/Ta, Th/Yb and Hf/Th are similar to those of the typical N-MORB. It can be interpreted that the basalts in the Bingdaban area were derived from a depleted mantle source, and formed in a matured mid-oceanic ridge setting during the matured evolutionary stage of the Northern Tianshan ocean. In comparison with the basalts, the diabases from the Bingdaban area show higher contents of Al₂O₃, ΣREE and HFS elements as well as unfractionated incompatible elements except Cs, Rb and Ba, and about 10 times the values of the primitive mantle. Thus, the diabases are thought to be derived from a primitive mantle and similar to the typical E-MORB. The diabases also have slight Nb depletion accompanying no apparent Th enrichment compared with N-MORB. From studies of the regional geology and all above evidence, it can be suggested that the diabases from the Bingdaban area were formed in the mid-oceanic ridge of the Northern Tianshan ocean during the initial spreading stage. Supported by the Major State Research Program of PRC (Grant No. 2001CB409801), the National Natural Science Foundation of China (Grant Nos. 40472115 and 40234041) and the State Research Program of China Geological Survey (Grant No. 2001130000-22)     

Iron Reduction Along an Inundation Gradient in a Tidal Sedge (<Emphasis Type="Italic">Cyperus malaccensis</Emphasis>) Marsh: the Rates,Pathways, and Contributions to Anaerobic Organic Matter Mineralization

Incubation experiments were adopted to characterize the rates and pathways of iron reduction and the contributions to anaerobic organic matter mineralization in the upper 0–5 cm of sediments along a landscape-scale inundation gradient in tidal marsh sediments in the Min River Estuary, Southeast China. Similar sediment characteristics, single-species vegetation, varied biomass and bioturbation, distinct porewater pH, redox potential, and electrical conductivity values have resulted in a unique ecogeochemical zonation along the inundation gradient. Decreases in solid-phase Fe(III) and increases in nonsulfidic Fe(II) and iron sulfide were observed in a seaward direction. Porewater Fe²⁺ was only detected in the upland area. High rates of iron reduction were observed in incubation jars, with significant accumulations of nonsulfidic Fe(II), moderate accumulations of iron sulfides, and negligible accumulations of porewater Fe²⁺. Most of the iron reduction was microbially mediated rather than coupled to reduced sulfides. Microbial iron reduction accounted for 20–89 % of the anaerobic organic matter mineralization along the inundation gradient. The rate and dominance of microbial iron reduction generally decreased in a seaward direction. The contributions of microbial iron reduction to anaerobic organic matter mineralization depended on the concentrations of bioavailable Fe(III), the spatial distribution of which was significantly related to tidal inundation. Our results clearly showed that microbial iron reduction in the upper sediments along the gradient is highly dependent on spatial scales controlled primarily by tidal inundation.     

一种简单方便的防拷贝程序设计方法——识别计算机的C语言程序设计

本文主要讨论一种特殊的Ｃ语言程序设计方法，这种程序能有效地对自身的关键模块加密，并能在运行时完成动态解密。该方法主要利用了“硬盘分区表”和最初安装在硬盘中程序自身的位置等信息，采用伪随机数加密法来实现。因所设计的程序具有识别计算机的能力，能有效地防止非法复制，从而保护软件制作者的知识产权和经济利益     

上新世湖相纹泥及其环境信息与时间标尺记录

纹泥反映了湖相沉积物中特有的沉积韵律,是气候的季节变化和年际变化的产物。山西榆社张村地区上新世晚期的湖心相沉积中发育了极为完好的纹泥剖面。纹泥深浅相间形成清晰的纹理,分别代表夏秋和冬春。一深一浅组成一对,代表一年。纹泥层的单层厚度平均为0．12～0．25mm／条,薄者＜0．1mm／条,厚者可达0．3mm／条。暗色纹泥层的厚度大于浅色纹泥层。暗色纹泥的有机质含量丰富,木本植物孢粉占优势,同时CaO的含量低;浅色纹泥恰好相反。湖相纹泥具有建立高分辨率时间标尺和环境演化序列的特殊优越条件。     

TWO DIMENSIONAL FINITE ELEMENT-BOUNDARY ELEMENT COUPLING MODEL OF MAGNETOTELLURIC SOUNDING

This paper describes how to apply the boundary element method to solve 2-D magneto-telluric sounding problem and then couple the BEM with finite element method to deal with inhomogeneous geological structure and its relation to regional stress regime. The BEM is able to calculate precisely the derivative of field variables. Such a new approach can more flexibly than others set up the upper boundary condition of the air region. Two practical examples are given. One is the study of topographical effect on the MT fields using boundary element method. There is an inverse relationship between the change of apparent resistivity and the topographical variation. The other is a coupled model of a basin in Nei Monngol Autonomous Region. A lower resistivity zone must exist in the crust and should be thicker below the central portion of the basin. This seems to agree with the regional stress regime changed from extension in Mesozoic to compression in Cenozoic     

辐照绿柱石的色心与赋色机制

在不同辐照剂量的带电粒子作用下，四川无色绿柱石因赋色而呈现浅蓝色，蓝绿色，黄绿色，浅黄色及橙黄色，紫外可见吸收光谱（UV－VIS）和阴极发光光谱（CLS）研究表明，辐照绿柱石中存在两组与赋色密切相关的色心组合，其一为相对稳定的[Fe^3 ]OH和[Fe^3 4]心，其二则为不稳定的[H^0]i心和F^ 心，二者对可见光的能量分别具有不同程度的选择性吸收和发射，由此产生特征的吸收与发射光谱。低温退火处理（210℃），有助于消除辐照绿柱石中不稳定的色心，使相对稳定的[Fe^3 ]OH心黉度再度聚集，并形成新的缺陷（二次缺陷），进而提高稳定色心的主波长和饱和度。研究证实，二次缺陷形成的初始温度，可近似代表辐照绿柱石的最佳热固色温度点，经辐照与热固色作用而形成的黄色，橙黄色绿柱石的颜色相对稳定，并不因长期日照或低温受热（＜280℃）而褪色。     

立交桥曲线箱梁动力分析模型

提出了1种双脊骨空间有限元模型,用来模拟和分析立交桥曲线箱梁的固有振动特性和动力反应。将曲线箱梁分别看作是由空间梁或壳组成的空间结构,并分别采用分段空间直梁模型、壳元模型和实体元模型进行模拟,分析相同曲线箱梁的振动特性和地震时程反应,通过与双脊骨模型的计算结果的比较验证双脊骨模型的可靠性。初步研究了在相同曲率半径下不同跨度的曲线箱梁的固有振动特性,分析了双脊骨模型的脊骨间距、横向连接间距等参数对模型计算结果的影响。研究结果可为曲线梁桥抗震性能和地震反应分析提供参考。     

Bathymetric inversion of South China Sea from satellite altimetry data

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热带对流层低频振荡过程的能量学初步分析

本文利用线性化的能量方程和交叉谱方法分别研究了准两周振荡和准40天振荡的能量来源及其转换过程。发现:在热带对流层中,对于低频振荡过程来说,来自中高纬度的侧向强迫作用和水汽凝结的加热作用是非常重要的,为扰动的产生和维持提供了重要能源。而正、斜压不稳定作用对扰动发展的作用是极小的。并且指出,在东亚热带对流层上部,准两周振荡通过与平均气流的相互作用为基本气流提供许多能量,对于维持这里的高空东风急流有重要作用。准40天振荡向平流层输送能量,对平流层平均环流的演变可能有重要贡献。