A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.     

粉喷桩处理软基的变形及固结测试分析

以广珠准高速铁路软土路堤试验粉喷桩处理段的变形及孔压测试数据为基础 ,对用粉喷桩处理深厚软土地基的沉降、基底横向差异沉降、边桩变形、孔压分布规律及固结进行了分析     

歧口凹陷火成岩的地球化学特征、形成时代及构造意义

歧口凹陷侏罗系火成岩主要以中-酸性的流纹岩、粗面岩和粗面安山岩为主,白垩系主要为中-基性的粗面玄武岩和玄武质粗面安山岩,第三系火成岩以粗面玄武岩、碱性玄武岩及辉绿岩为主。同位素定年结果获得白垩系玄武岩的年龄为133±20 Ma,安山岩和粗安岩年龄分别为111.8±0.9 Ma和122.1±3.1 Ma,第三系辉绿岩年龄为16.57±0.23 Ma。地球化学特征显示,侏罗系火成岩相对低钛、高碱和钠、低铁镁,轻重稀土元素强烈分馏、微量元素相对富集LILE、贫化HFSE、亏损Nb和Ti、P,部分高Sr、低Yb,总体指示为挤压环境下加厚地壳物质的熔融产物,白垩系火成岩中等钛和碱的含量,高钠、铁和镁,稀土和微量元素显示其来自于伸展背景的富集地幔源,但受到陆壳物质的混染,第三系火成岩高钛含量、中等碱含量但变化大、高钠、富铁镁,轻重稀土元素分馏弱到中等、微量元素富集LILE和HFSE,同样来自板内伸展环境的富集地幔源的产物。表明歧口凹陷构造转换发生在晚侏罗世和早白垩世之间。     

Effects of a proline solution cover on the geochemical and mineralogical characteristics of high-sulfur coal gangue

Batch experiments were conducted to comparatively evaluate the inhibition effects and mechanisms of a low-concentration (1%) proline solution cover on the release of pollutants from high-sulfur coal gangue. High-sulfur coal gangue was continuously immersed in a proline solution and in deionized water (as a control treatment) for 540 days. The results showed that the coal gangue in the control treatment was oxidized and generated leachate with poor water qualities, i.e., the leachate exhibited lower pH values, higher redox potential values, higher pollutant concentrations (SO₄^2?, Fe, Mn, Cu, and Zn), and high levels of acidophilic sulfur-oxidizing bacteria. However, compared to the control treatment, the addition of the proline solution (1%) significantly improved the water quality of the leachate by significantly reducing the Eh values, the pollutant concentrations (SO₄^2?, Fe²⁺, Fe, Mn, Cu, and Zn), and the activity of acidophilic sulfur-oxidizing bacteria and by significantly increasing the pH value to neutral. The proline treatment significantly inhibited the oxidation of coal gangue and the release of pollutants, mainly by inhibiting the activity of acidophilic sulfur-oxidizing bacteria and by altering the heavy metal fractions and the mineralogical characteristics. Therefore, in engineering practice, workers should consider using an environmental friendly aqueous proline solution cover to achieve the in-situ control of pollutant releases from coal gangue dumps.     

安徽拂晓地区地物化特征及找矿意义

拂晓地区位于苏鲁超高压变质带安徽段的张八岭地区,地质构造条件与山东段的胶东金矿矿集区类似,具有较好的成矿地质条件和找矿前景。为探索拂晓地区金矿找矿前景,我们系统的开展地物化工作,以面积性的磁法、化探异常为依据,圈定隐伏岩体范围,提供多目标的直接找矿信息,减小找矿范围,预测出两个重点找矿远景区。在重点找矿远景区内,部署了两条可控源音频大地电磁和频谱激电剖面对重点区域的深部纵向结构特征进行探索。综合研究拂晓地区的地物化资料,提出以“弱磁异常-化探异常中心-中等强度的电性异常”为特征的物化探找矿标志;“煌斑岩脉-闪长质脉岩”为特征的地质直接找矿标志;“次级断裂带-不同岩体间的接触带区域”为重点找矿区域的地物化综合找矿方法,有效的增强了找矿能力。为安徽拂晓地区及其邻区的矿产勘查工作提供一定的指示。     

燕辽地区火山热液型铀－金－多金属矿床成矿特征

燕辽地区位于华北地台北缘东段，是我国著名的中生代火山热液型铀、金、多金属矿床成矿区。研究结果表明，其成矿作用受统一的晚中生代大陆裂陷火山岩浆活动控制；成矿时代集中在晚侏罗世及早白垩世；成矿介质为火山岩浆水、变质水和大气水混合的中温、中低温火山热液；成矿物质主要来自富集型的上地幔及下地壳。     

Ages of Lueliang Group and Its Metamorphism in Mt.Lueliang Region,Shanxi Province：Evidence form Single Grain Zircon U—Pb Dating

Presented in this paper are the newly obtained grain zircon U-Pb ages of volcanic rocks of the Lueliang Goup and associated Kuanping granitic migmatitic gneiss in Shanxi Province.The zircon U-Pb ages of bimodal volcanic rocks(basalt and rhyolite)of the Upper Lueliang Group indicate that the rocks erupted at about 2100 Ma.So the Lueliang Group was formed during the Early Proterozoic.In the area studied the second-stage metamorphism experienced by the Lueliang Group is the dominant one which took place at about 1806 Ma.i.e.,during the late Early Proterozoic.     

地下水源热泵系统热平衡预测三维数值模拟

为了准确模拟预测地下水源热泵系统运行期间的地下水渗流场与温度场的变化规律,避免未来地下水源热泵系统运行期间出现的冷热贯通现象与堆积问题,科学合理地设计地下水源热泵系统。以江苏南通益兴集团地下水源热泵示范工程为例,建立了地下水渗流与热量运移三维耦合数值模型,并结合地下水源热泵系统的设计运行方案,预测分析了未来地下水源热泵系统的热平衡发展趋势。结果表明,该工程按设计方案运行,整个区域地下水温度逐渐升高,出现热堆积问题。采用春秋季与冬季多加热生活用水增加制热负荷量的方法,可有效缓解热堆积问题。